Refined relationship between the position of the fundamental OH stretching and the first overtones for clays

The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W_2OH) and the wavenumbers of the OH-stretching fundamentals (W_OH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W_2OH/2 - W_OH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm^–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.     

Detection of blends in the vicinity of Zeeman lines

High resolution spectrograms taken in polarized light have revealed the presence of significant blending within the profiles of some important Zeeman multiplets of a large umbra. Wavelength and equivalent width of each depictable blend have been derived from the corrected spectrograms and some preliminary identifications have been made.     

Hydromorphology of a part of Azamgarh and Ghazipur districts,Uttar Pradesh

Hydrogeological studies in the Quaternary alluvial plain of a part of Azamgarh and Ghazipur districts, using air photos on scale 1:60,000 indicate the presence of five hydromorphic units namely, Alluvial upland, older alluvial plain of Mangat-Besu, older flood plain of Ganga—Gomti, youngest terrace of Ganga—Gomti and present flood plain of Ganga-Gomti. From the groundwater point of view older flood plain of Ganga—Gomti is the most promising hydromorphic unit. Abandoned channel of river Ganga offers favourable site for deep groundwater exploration with high potentiality. Chemical quality of shallow and deep aquifers is suitable for irrigation and other purposes.     

The Composition of Garnets from Pelitic Schists in relation to the Grade of Regional Metamorphism

Analyses of garnets are presented from a wide variety of metamorphicterrains, in relation to which there appears to be a regularpattern of substitution of (FeO+MgO) for (CaO+MnO), the valuesof these components reflecting the metamorphic grade of thepelitic schists. This provides a method for indicating variationsin grade in metamorphic terrains and for comparing the variationsin different areas. In areas of repeated metamorphism this wouldappear to have a particular value in establishing the gradeof the various episodes of metamorphism. It is also demonstratedthat by the determination of selected physical propertics (unitcell edge a and refractive index) of garnets in the peliticschists, and evaluating the significance of their variations,it is possible to work out the local changes of metamorphicgrade within a particular area.     

Effects of benzene and dimethylnaphthalene on homeostatic processes in two species of crabs

Long-term exposure of animals to sub-lethal doses of toxicants such as benzene (B) and dimethylnaphthalene (DMN) may result in subtle changes in their physiology and biochemistry. In crustaceans such changes include decreased rate of limb regeneration, extended time to molt and decreased growth increment at molt.^1,2 These processes depend upon an adequate supply of stored nutrients in the tissues and appropriate release of neuroendocrine substances from the central nervous system.^3,4 We are examining the effects of sub-lethal doses of B and DMN on osmotic and ionic regulation and on nutrient storage in the blue crab, Callinectes sapidus, and the green crab, Carcinus maenas. Disturbances in these physiological processes may reflect alterations in neuroendocrine functions brought about by the presence of toxicants. We find that exposure of C. maenas to B or DMN, followed by transfer to a dilute medium, results in impaired osmoregulatory capacity, while addition of these compounds to a dilute medium to which the animal is already acclimated does not affect their regulatory ability. Storage of carbohydrate in the midgut gland (hepatopancreas) is decreased by B or DMN, while the accessory storage tissues (gill, muscle) are not significantly affected.     

Long-term comparison of macrobenthos within the soft bottoms of the Bay of Banyuls-sur-mer (northwestern Mediterranean Sea)

The macrofauna present at seven of the stations within the Bay of Banyuls-sur-mer (northwestern Mediterranean) initially sampled by Guille during the late 1960s was reassessed in 1994, using the same gear and techniques as those used during the reference study. Results showed an increase both in the number of species and of individuals (all species pooled) per unit of surface area at nearly all stations. This trend was not significant for total biomass. The most important changes were linked to the increase of the polychaete Ditrupa arietina (both within the Spisula subtruncata and the Nephtys hombergii community) and the decrease of the polychaetes Scoloplos armiger and Notomastus latericeus within the Scoloplos armiger community. The possible causes underlying these changes are discussed. The most probable cause is considered to be a slight modification of sediment composition (decrease of fine material in the sediment) within the Spisula subtruncata, the Nephtys hombergii and the Scoloplos armiger communities. Temporal changes in (1) Rhone river input, (2) small coastal river inputs, and (3) frequency of easterly storms may all have contributed to such a decrease.     

Regeneration of sand waves after dredging

Sand waves are large bed waves on the seabed, being a few metres high and lying hundreds of metres apart. In some cases, these sand waves occur in navigation channels. If these sand waves reduce the water depth to an unacceptable level and hinder navigation, they need to be dredged. It has been observed in the Bisanseto Channel in Japan that the sand waves tend to regain their shape after dredging. In this paper, we address modelling of this regeneration of sand waves, aiming to predict this process. For this purpose, we combine a very simple, yet effective, amplitude-evolution model based on the Landau equation, with measurements in the Bisanseto Channel. The model parameters are tuned to the measured data using a genetic algorithm, a stochastic optimization routine. The results are good. The tuned model accurately reproduces the measured growth of the sand waves. The differences between the measured weave heights and the model results are smaller than the measurement noise. Furthermore, the resulting parameters are surprisingly consistent, given the large variations in the sediment characteristics, the water depth and the flow field. This approach was tested on its predictive capacity using a synthetic test case. The model was tuned based on constructed predredging data and the amplitude evolution as measured for over 2 years. After tuning, the predictions were accurate for about 10 years. Thus, it is shown that the approach could be a useful tool in the optimization of dredging strategies in case of dredging of sand waves.     

Deforestation and leaching of nitrogen as nitrates into underground water in intertropical zones: The example of Côte d'lvoire

High nitrate contents (up to 200 mgl) have been observed in wells drilled into fractured aquifers lying beneath layers of weathered and decayed rock in the humid tropics where annual rainfall is over 1000 mm and where there is no notable pollution. The source of the nitrates is linked mainly with localized deforestation by man.