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 Picritic units of the Miocene shield volcanics on Gran Canaria, Canary Islands, contain olivine and clinopyroxene phenocrysts with abundant primary melt, crystal and fluid inclusions. Composition and crystallization conditions of primary magmas in equilibrium with olivine Fo90-92 were inferred from high-temperature microthermometric quench experiments, low-temperature microthermometry of fluid inclusions and simulation of the reverse path of olivine fractional crystallization based on major element composition of melt inclusions. Primary magmas parental for the Miocene shield basalts range from transitional to alkaline picrites (14.7–19.3 wt% MgO, 43.2–45.7 wt% SiO2). Crystallization of these primary magmas is believed to have occurred over the temperature range 1490–1150° C at pressures ≈5 kbar producing olivine of Fo80.6-90.2, high-Ti chrome spinel [Mg/ (Mg+Fe2+)=0.32–0.56, Cr/(Cr+Al)=0.50–0.78, 2.52–8.58 wt% TiO2], and clinopyroxene [Mg/(Mg+Fe)=0.79–0.88, Wo44.1-45.3, En43.9-48.0, Fs6.8-11.0] which appeared on the liquidus together with olivine≈Fo86. Redox conditions evolved from intermediate between the QFM and WM buffers to late-stage conditions of NNO+1 to NNO+2. The primary magmas crystallized in the presence of an essentially pure CO2 fluid. The primary magmas originated at pressures >30 kbar and temperatures of 1500–1600° C, assuming equilibrium with mantle peridotite. This implies melting of the mantle source at a depth of ≈100 km within the garnet stability field followed by migration of melts into magma reservoirs located at the boundary between the upper mantle and lower crust. The temperatures and pressures of primary magma generation suggest that the Canarian plume originated in the lower mantle at depth ≈900 km that supports the plume concept of origin of the Canary Islands. Received: 23 October 1995/Accepted: 21 February 1996  相似文献   
76.
Major elements, S, F, Cl concentrations and relative proportions of S6+ to total S were analyzed with electron microprobe in sideromelane glass shards from Pleistocene volcaniclastic sediments drilled during ODP Leg 157. Glasses are moderately to strongly evolved and represent a spectrum from alkali basalt, basanite and nephelinite through hawaiite, mugearite and tephrite to phonolitic tephrite. Measured S6+/ΣS (0.03–0.98) and calculated Fe2+/Fe3+ (2.5–5.8) ratios in the melt yield preeruptive redox conditions ranging from NNO−1.4 to NNO+2.1. The morphology of the glass shards, variations of S and Cl concentrations (0.010–0.127 wt% S, 0.018–0.129 wt% Cl), calculated preeruptive temperatures (1030–1200 °C) and oxygen fugacities suggest that glasses deposited even within the same ash layers have diverse origin and may have resulted from both submarine and subaerial eruptions. Most vesicle-free glasses are characterized by high concentrations of S and represent undegassed or slightly degassed submarine lavas, whereas vesiculated glasses with low concentrations of S and Cl are strongly degassed and can be ascribed to the eruptions in shallow water or on land. Sideromelane glass shards at Sites 953 are thought to have resulted from submarine eruptions northeast of Gran Canaria, glasses at Site 954 represent mostly volcaniclastic material of shallow water submarine and subaerial eruptions on Gran Canaria and Tenerife, and glasses deposited at Site 956 resulted from submarine or explosive eruptions on Tenerife. Received: 8 April 1997 / Accepted: 27 October 1997  相似文献   
77.
Gabbroic and ultramafic xenoliths and olivine and clinopyroxene phenocrysts in basaltic rocks from Gran Canaria, La Palma, El Hierro, Lanzarote and La Gomera (Canary Islands) contain abundant CO2-dominated fluid inclusions. Inclusion densities are strikingly similar on a regional scale. Histogram maxima correspond to one or more of the following pressures: (1) minimum 0.55 to 1.0 GPa (within the upper mantle); (2) between 0.2 and 0.4 GPa (the Moho or the lower crust); (3) at about 0.1 GPa (upper crust). Fluid inclusions in several rocks show a bimodal density distribution, the lower-density maximum comprising both texturally early and late inclusions. This is taken as evidence for an incomplete resetting of inclusion densities, and simultaneous formation of young inclusions, at well-defined magma stagnation levels. For Gran Canaria, pressure estimates for early inclusions in harzburgite and dunite xenoliths and olivine phenocrysts in the host basanites overlap at 0.9 to 1.0 GPa, indicating that such magma reservoir depths coincide with levels of xenolith entrainment into the magmas. Magma chamber pressures within the mantle, inferred to represent levels of mantle xenolith entrainment, are 0.65–0.95 GPa for El Hierro, 0.60–0.68 GPa for La Palma, and 0.55–0.75 GPa for Lanzarote. The highest-density fluid inclusions in many Canary Island mantle xenoliths have probably survived in-situ near-isobaric heating at the depth of xenolith entrainment. Inclusion data from all islands indicate ponding of basaltic magmas at Moho or lower crustal depths, and possibly at an additional higher level, strongly suggestive of two main crustal accumulation levels beneath each island. We emphasize that repeated magmatic underplating of primitive magmas, and therefore intrusive accretion, are important growth mechanisms for the Canary Islands, and by analogy, for other ocean islands. Comparable fluid inclusion data from primitive rocks in other tectonic settings, including Iceland, Etna and continental rift systems (Hungary, South Norway), indicate that magma accumulation close to Moho depths shortly before eruption is not, however, restricted to oceanic intraplate volcanoes. Lower crustal ponding and crystallization prior to eruption may be the rule rather than the exception, independent of the tectonic setting. Received: 30 May 1997 / Accepted: 6 February 1998  相似文献   
78.
We studied the volcanic contribution to the global sediment budget in the Pacific Ocean basin. It is the world's oldest (174 m.y.) and largest (≈49% of Earth's surface area) ocean basin and has had a high and continuous tephra influx from intraplate and convergent margin volcanoes through time. Computerized shipboard data from 65 legs of the Deep Sea Drilling Project (DSDP) and the Ocean Drilling Program (ODP) were screened for the presence of volcaniclastic components. Tephra-bearing and tephra-free core sections (standard 1.5- and 0.30-m core catcher sections) were separated, regardless of the mass fraction of tephra present. The percentage of tephra-bearing core sections ("tephra frequency") per site and time span ("age unit") was calculated. The age units were the Quaternary, the subepochs of the Tertiary, and the stages of the Cretaceous. A total of 424 drill sites yielded 1433 usable stratigraphic units. Fifty percent are younger than 13 m.y., corresponding to only approximately 10% of the total interval studied (124.5 m.y.). The percentage of tephra-bearing age units is high throughout (83±6%) and correlates linearly with the total number of age units (R 2 =0.998; n=17). The average tephra frequency (30–50%) fluctuates, because the abundance of age units of different tephra frequency classes (0, 1–33, 34–67, 68–100% tephra frequency) varies with time. This indicates that the Cenozoic increase in tephra production results from increase in volcanicity and not spatial extension of volcanic source areas. The Cenozoic sediments that were recovered are dominated by distal tephra from explosive arc volcanism. Pulses of arc volcanism occurred in the Pliocene–Quaternary (since ≈5 m.y.) and mid-Miocene (≈12–15 m.y.). However, the record of explosive arc volcanism in Paleogene and Cretaceous sediments was either not drilled or has been destroyed by subduction. Except for the Cretaceous (≈70–110 m.y.) volcanic pulse, intraplate volcanism is poorly represented in the tephra record because the drill sites are outside the proximal range (>500–1000 km) of the sources. Thus, the tephra record drilled contains significant gaps that bias the estimate of tephra volume towards the less voluminous distal deposits. Most of the volcaniclastic volume accumulated by mass wasting as volcaniclastic aprons surrounding ocean island volcanoes. Volcaniclastic production rates range from 10,000 to 41,800 km3/m.y. for large intraplate volcanoes and approximately 10–13 km3/km arc length per million years for oceanic island arcs. Extrapolation over the lifetime of major Pacific arcs and hotspot chains, combined with a volume estimate of the distal tephra component, indicates a minimum of 9.3×106 km3 of tephra, corresponding to 23 vol.% of the existing Pacific oceanic sediments. At least two thirds of the tephra volume was deposited in the proximal range and at least half of it is derived from intraplate sources. The large proportion of tephra, its composition, and its localized accumulation causes significant spatial and temporal variation in Pacific oceanic sediments that should have a perceptible impact on the elemental fluxes between ocean, crust, and mantle.  相似文献   
79.
U-series disequilibria analyses have been combined with chemical and petrographic analyses in order to assess both the timescales and processes involved in the formation of the chemically zoned Fogo A trachytes. Least squares major element modelling demonstrates that the mafic trachytes could have evolved from a parental alkali basalt via trachybasalt with 70% fractionation of augite (35–36%), plagioclase (23%), magnetite (16%), kaersutite (15%), olivine (8%) and apatite (2–3%). Derivation of the mafic trachytes from a basanite parent is inconsistent with calculated fractionation paths. Major and trace element variations in 25 pumice samples collected from throughout the stratigraphic extent of the Fogo A deposit show that the trachytes represent the inverted, extrusive equivalent of a strongly chemically zoned magma chamber. The zonation is attributed to 70–75% Rayleigh fractional crystallization of the observed phenocryst phases. Wallrock assimilation and magma mixing did not contribute significantly to the observed chemical trends. The maximum age of the Fogo A trachytic magma based on radioactive disequilibria between 230Th and 238U is 300000 years. However, a calculated model age suggests that the time of evolution of the Fogo A trachytes from a parent alkali basalt is only 90000 years. Constant element variations and Th-isotopic ratios in Fogo C, Fogo A and 1563 A.D. trachytes suggest that a single long-lived trachytic magma chamber has been the source of at least the past 15.2 Ka of trachytic volcanism from Agua de Pao. After each eruption an evolved cupola reformed and became zoned prior to the next eruption. The maximum time necessary to form the zonation is 4600 years, the time between the Fogo A and 1563 A.D. eruptions. Low (226Ra)/(230Th)i ratios in the Fogo A and 1563 A.D. trachytes suggest that alkali feldspar fractionation continued up to the time of the respective eruptions.  相似文献   
80.
Valley-fill ignimbrites of the Middle Laacher See Tephra (MLST) in the proximal depositional fan south of Laacher See volcano are laterally continuous with fine-grained overbank-facies deposits, 0.5–1.5 m thick, covering higher elevations and interfluves between the paleovalleys. The overbank deposits consist of up to 12 ash layers, each 4–10 cm thick, which show internal structures typical of ash-flow transport, such as poor sorting, reverse size-grading of pumice, local normal grading of coarse ash-sized lithics above a fine-grained basal layer, cross-stratification behind obstacles, and erosional unconformities. Thickness, median grain-size, and number of individual layers decrease systematically with distance from the vent. Overbank ash layers thicken at the valley slopes and form discrete valley-fill ignimbrite flow units in the paleochannels with median grain size increasing from 63 m to 350 m. Toward the center of paleochannels, however, the well-defined overbank facies is obscured by mutual erosion of individual flow units. Overlapping data fields in ternary grain-size variation diagrams indicate the overbank facies to have evolved from ash flows chiefly through depletion of lapilli and coarse ash. Overbank-facies ash layers do not represent dust layers resulting from elutriation clouds of ash flows (co-ignimbrite ash) or surge deposits developed on higher ground due to low concentration of solids. They are similar in some parameters to Taupo-type ignimbrite veneer deposits, but are interpreted differently. The thin, fine-grained, Laacher See ash layers are thought to have been deposited from diluted portions of the flow proceeding directly from the eruption column while the main pyroclastic flows were confined to the paleovalleys radiating away from the eruptive center. The wide distribution of the thin ash layers is attributed to the balance of deposition from various flow parts and turbulent entraining and heating of ambient air that sustained sufficient mobility of the diluted flows to spread across hills and level ground.  相似文献   
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