Note on deep-focus earthquakes,pressure changes,and pole motion

Summary The hypothesis has been advanced that major portions of the annual pole motion are caused by the seasonal transport of air masses. These pole motions in turn can act as trigger forces on earthquakes. This is tested by observations of northern hemisphere pressures, pole motion, and occurrence of deep focus earthquakes during the interval 1922 to 1935.

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Zusammenfassung Man hat die Annahme gemacht, dass die jährliche Polhöhenschwankung grossenteils durch die jahreszeitlichen Luftmassenbewegungen, verursacht wird. Diese Polhöhenschwankungen können ihrerseits die auslösende Ursache für Erdbeben sein. Die Hypothese wird an Hand der Beobachtungen der Luftdruckschwankungen auf der Nordhalbkugel, der Polbewegung und der Frequenz der Tiefherdbeben während der Jahre 1922 bis 1935 auf die Probe gestellt.

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Contribution written for the Number dedicated to Dr.G. Agamennone in occasion of his 90.th birthday.     

Trace analysis of quaternary aminoalcohols as degradation products from softeners in wastewater

The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved.     

Der Leitfähigkeitstest — Ein Testsystem zur Ermittlung der membrantoxischen Eigenschaften von Substanzen

The Conductivity Test — Determining the Membrane-toxic Properties of Substances A new biotest system is introduced which is specific in terms of the measured effect but not in terms of the applied organisms. The system is able to detect the effect of membrane-toxic compounds e.g. detergents, organic solvents, and radical formers. Released into the environment, these substances damage biological membranes and therefore cause ion leakage into a surrounding medium. Ion leakage is taken as a measure for membrane damage and is determined as an increase of the electrical conductivity in the medium (conductivity test). The results presented for the tensides benzalkonium chloride, LAS (linear alkylbenzenesulfonate), and APG (alkylpolyglycoside) demonstrate the capability of the conductivity test to distinguish between the differing toxicological potential of these membrane-toxic substances. In contrast to most of the conventional biotests, the endpoint of the conductivity test is independent of a specific organism. This independence is demonstrated by the results obtained with benzalkonium chloride treatment of Elodea canadensis, Lemna minor, and Salvinia natans. The conductivity test represents a versatile, easy to handle biotest system for the assessment of ecotoxicological effects caused by membrane-toxic substances.     

Use of traveltime skips in refraction analysis to delineate velocity inversion1

First arrival refraction data does not normally provide any indication of the velocity inversion problem. However, under certain favourable circumstances, when the low-velocity layer (LVL) is considerably thicker than the overlying higher-velocity layer (HVL), the velocity inversion can be seen in the form of a traveltime skip. Model Studies show that in such cases the length of the HVL traveltime branch can be used to determine the thickness of the HVL and the magnitude of the traveltime skip in order to determine the thickness of the LVL. This is also applicable in the case of field data.     

Seasonal soil water storage changes beneath central Amazonian rainforest and pasture

Evaporation and infiltration were compared for tropical rainforest and pasture, near to Manaus, Brazil from October 1990 to February 1992 using measurements of soil water storage over a depth of 2 m. The soil is a clayey oxisol of low water available capacity. In both of the dry seasons studied, the maximum change in soil water storage in the forest was 154 mm and in the pasture it was 131 and 112 mm. Similar behaviour of the soil water reservoir below forest and pasture in the wet season implied that differences in evaporation and drainage were small. In the dry season, soil water storage behaviour in the upper metre of the soil was similar but there were marked differences in the second metre. The pasture took up little water from below 1.5 m but the forest appeared to utilise all of the available water in the 2 m profile in both seasons.

The water balance of the 2 m profile showed that the pasture evaporation rate was equal to that of the forest until storage had decreased 80 mm from the maximum. There was then a decline in pasture evaporation rate to 1.2 mm day⁻¹ as the storage decreased by a further 50 mm. In contrast, the forest uptake rate remained above 3.5 mm day⁻¹ until storage had decreased 140 mm from the maximum (within 15 mm of the extraction limit), before declining abruptly to less than 1.5 mm day⁻¹. There was strong evidence that the forest was able to abstract water from depths greater than 3.6 m.

Spatial variability of soil water storage was significantly greater beneath the pasture than beneath the forest, particularly following rainfall events in the dry season. This was largely the result of redistribution of rainfall as local surface runoff. There was no evidence of redistribution or runoff in the forest.     

Entropy estimation of hydrological extremes

The method of Relative Entropy with Fractile constraints (REF method) is explained and applied to model extreme compound hydrological phenomena, such as extreme sea levels under storm conditions. Also presented is a simple method of Tail Entropy Approximation (TEA), which amounts to a correction of traditional statistical estimates for extreme observations.Distribution assumptions are necessary but downplayed in the REF method, relegating the prior distribution to the role of an extrapolation function. The estimates are objective in an information-theoretical sense. They also satisfy a strict requirement of self-consistency that is generally not satisfied by standard statistical methods: invariance under monotonic transformations of the random variable.Historical records of storm surge levels in the Netherlands and annual maximum tidal heights for Sheerness, UK, are used as examples. Comparison is made with distributions obtained using other methods.It is concluded that the tail entropy approximation provides simple, objective estimates of extremes in the tail beyond the range of observations.     

Geology, magmatic affinity and geotectonic environment of some Caledonian ophiolites in Norway

Ophiolites within the Norwegian Caledonides were generated during at least two distinct periods, i.e. Tremadocian-Arenigian and Ashgillian. The older generation show a long-lived magmatic development (ca 500-470 Ma) with rocks that range from MORB, IAT, boninites, calc-alkaline to alkaline basalt in geochemical affinity. This development is compatible with generation in a subduction-influenced environment, and a plausible modern equivalent may be the ensimatic arc-basin evolution in the western Pacific.The metabasalts of the younger (Ashgill, 443±3 Ma) ophiolite occurrence are characterized by a dominance of N- to E-MORB compositions with subduction zone influence. The volvanics of the complex are intercalated with, and overlain by, continentally-derived sediments. Calc-alkaline as well as alkaline lavas and volcanic-lastics apparantly define late magmatic products. Associated with the youngest ophiolite is a sedimentary melange with olistoliths of mature island arc-derived volcanics, as well as clasts with MORB-IAT affinity, chert and sandstone, the latter probably derived from an accretionary prism. An Andaman Sea model appears most applicable to the youngest ophiolite/associated sediments assemblage.Contemporaneously with the renewed, Ashgillian spreading episode, widespread deposition of clastic sequences of Ashgillian age took place unconformably on the Lower Ordovician ophiolite complexes in fault controlled basins.     

Gravity map of Kalabsha area, northwest of Aswan Lake, and its structural significance

A detailed gravity survey was carried out in one of the seismo-active areas at the northwestern region of the High Dam Lake (Kalabsha area) to study its subsurface structure. In order to understand the seismicity of the area, the establishment of a geodynamic model from geological and geodetic data is of great importance. After a series of adjustments and corrections of the measured gravity data, free-air and Bouguer anomaly maps were constructed for the Kalabsha area, and several interpretation techniques were applied to analyse these anomalies. The results of the analysis indicate that the Kalabsha area is affected by several faults trending mainly E-W and N-S. The active area located west of Gebel Marawa is bounded by a set of faults striking NE-SW, N-S and E-W. The throws of these faults range from 160 to 370 m.The minimum depth to the basement complex is about 200 m and its maximum depth is around 600 m. The thickness of the sedimentary column (Nubia sandstone) in the Kalabsha area decreases due west and increases toward the southern and eastern parts of the area. The results explain the tectonic framework of the area well.