Ionosphere Disturbances Preceding Earthquakes according to the Data of Ground Based Station of the Vertical Ionospheric Sounding Wakkanai

The paper analyzes the data of manual ionograms processing of hourly measurements of the critical frequency foF2 of the F2 ionospheric layer at the Wakkanai ionospheric vertical sounding station (Japan) in a geomagnetically quiet environment before a series of earthquakes with magnitude M > 6.0, for which the station entered the earthquake preparation zone, in order to detect possible Ionospheric Disturbances Preceding Earthquakes (IDPE), and to determine their quantitative characteristics. Detected IDPE, in the opinion of the authors, can be related to the processes of preparation of the corresponding earthquakes, i.e., to be Ionospheric Precursors of Earthquakes (IPE).     

<Emphasis Type="Italic">M</Emphasis><Subscript>W</Subscript>9 Tohoku earthquake in 2011 in Japan: precursors uncovered by natural time analysis

This paper reviews the precursory phenomena of the 2011 M _W9 Tohoku earthquake in Japan that emerge solely when we analyze the seismicity data in a new time domain termed natural time. If we do not consider this analysis, important precursory changes cannot be identified and hence are missed. Natural time analysis has the privilege that enables the introduction of an order parameter of seismicity. In this frame, we find that the fluctuations of this parameter exhibit an unprecedented characteristic change, i.e., an evident minimum, approximately two months before Tohoku earthquake, which strikingly is almost simultaneous with unique anomalous geomagnetic field variations recorded mainly on the z component. This is consistent with our finding that such a characteristic change in seismicity appears when a seismic electric signal (SES) activity of the VAN method (from the initials of Varotsos, Alexopoulos, Nomicos) initiates, and provides a direct confirmation of the physical interconnection between SES and seismicity.     

Microbial release of potassium from K-bearing minerals by thermophilic fungus Aspergillus fumigatus

A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles.     

Rapid photo-oxidation of Mn(II) mediated by humic substances

The oxidation of Mn(II) by O₂ to Mn(III) or Mn(IV) is thermodynamically favored under the pH and pO₂ conditions present in most near surface waters, but the kinetics of this reaction are extremely slow. This work investigated whether reactive oxygen species, produced through illumination of humic substances, could oxidize Mn at an environmentally relavent rate. The simulated sunlight illumination of a solution containing 200 μM Mn(II) and 5 mg/L Aldrich humic acid buffered at pH 8.1 produced ∼19 μM of oxidized Mn (MnO_x where x is between one and two) after 45 minutes. The major oxidants reponsible for this reaction appear to be photoproduced superoxide radical anion, O₂⁻, and singlet molecular oxygen, ¹O₂. The dependencies of MnO_x formation on Mn(II), humic acid, and H⁺ concentration were characterized. A kinetic model based largely on published rate constants was established and fit to the experimental data. As expected, analysis of the model indicates that the key reaction rate controlling MnO_x production is the rate of decomposition of a MnO₂⁺ complex formed from the reaction of Mn(II) with O₂⁻. This rate is strongly dependent on the Mn(II) complexing ligands in solution. The MnO_x production in the seawater sample taken from Bodega Bay, USA and spiked with 200 μM Mn(II) was well reproduced by the model. Extrapolations from the model imply that Mn photo-oxidation should be a significant reaction in typical surface seawaters. Calculated rates, 5.8 to 55 pM h⁻¹, are comparable to reported rates of biological Mn oxidation, 0.07 to 89 pM h⁻¹. Four fresh water samples that were spiked with 200 μM Mn(II) also showed significant MnO_x production. Based on these results, it appears that Mn photo-oxidation could constitute a significant, and apparently unrecognized geochemical pathway in natural waters.     

Source identification of PM2.5 particles measured in Gwangju, Korea

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.     

Global high resolution versus Limited Area Model climate change projections over Europe: quantifying confidence level from PRUDENCE results

Four high resolution atmospheric general circulation models (GCMs) have been integrated with the standard forcings of the PRUDENCE experiment: IPCC-SRES A2 radiative forcing and Hadley Centre sea surface temperature and sea-ice extent. The response over Europe, calculated as the difference between the 2071–2100 and the 1961–1990 means is compared with the same diagnostic obtained with nine Regional Climate Models (RCM) all driven by the Hadley Centre atmospheric GCM. The seasonal mean response for 2m temperature and precipitation is investigated. For temperature, GCMs and RCMs behave similarly, except that GCMs exhibit a larger spread. However, during summer, the spread of the RCMs—in particular in terms of precipitation—is larger than that of the GCMs. This indicates that the European summer climate is strongly controlled by parameterized physics and/or high-resolution processes. The temperature response is larger than the systematic error. The situation is different for precipitation. The model bias is twice as large as the climate response. The confidence in PRUDENCE results comes from the fact that the models have a similar response to the IPCC-SRES A2 forcing, whereas their systematic errors are more spread. In addition, GCM precipitation response is slightly but significantly different from that of the RCMs.     

Spatially explicit measures of production of young alewives in Lake Michigan: Linkage between essential fish habitat and recruitment

The identification and protection of essential habitats for early life stages of fishes are necessary to sustain fish stocks. Essential fish habitat for early life stages may be defined as areas where fish densities, growth, survival, or production rates are relatively high. To identify critical habitats for young-of-year (YOY) alewives (Alosa pseud oharengus) in Lake Michigan, we integrated bioenergetics models with GIS (Geographic Information Systems) to generate spatially explicit estimates of potential population production (an index of habitat quality). These estimates were based upon YOY alewife bioenergetic growth rate potential and their salmonine predators’ consumptive demand. We compared estimates of potential population production to YOY alewife yield (an index of habitat importance). Our analysis suggested that during 1994–1995, YOY alewife habitat quality and yield varied widely throughout Lake Michigan. Spatial patterns of alewife yield were not significantly correlated to habitat quality. Various mechanisms (e.g., predator migrations, lake circulation patterns, alternative strategies) may preclude YOY alewives from concentrating in areas of high habitat quality in Lake Michigan.     

UPPER PALAEOZOIC FORMATIONS AND FAUNAS OF YAOLING,CHENHSIEN,S.HUNAN.

STRATIGRAPHY Yao Ling (瑤林) lies 40 li southeast from Chen Hsien city (郴縣), about Long. 112°30′E., Lat. 25°40′N., and is halfway between Chen Hsien city and the well known wolfram mining district, Yao Kang Sien (瑤崗仙). On the     

A PRELIMINARY STUDY ON THE CHEMICAL AND MINERALOGICAL COMPOSITION OF LOESS.

In general, geologically speaking, it has been noted that if the formation of coal took place during the Permo-Carboniferous period, its volatile matter will al ways be less than 30％ when analized, and the contrary is usually the case for coal created during the Tertiary and Jurassic, these having more than 40％.