Coral skeleton P/Ca proxy for seawater phosphate: Multi-colony calibration with a contemporaneous seawater phosphate record

A geochemical proxy for surface ocean nutrient concentrations recorded in coral skeleton could provide new insight into the connections between sub-seasonal to centennial scale nutrient dynamics, ocean physics, and primary production in the past. Previous work showed that coralline P/Ca, a novel seawater phosphate proxy, varies synchronously with annual upwelling-driven cycles in surface water phosphate concentration. However, paired contemporaneous seawater phosphate time-series data, needed for rigorous calibration of the new proxy, were lacking. Here we present further development of the P/Ca proxy in Porites lutea and Montastrea sp. corals, showing that skeletal P/Ca in colonies from geographically distinct oceanic nutrient regimes is a linear function of seawater phosphate (PO_4 SW) concentration. Further, high-resolution P/Ca records in multiple colonies of Pavona gigantea and Porites lobata corals grown at the same upwelling location in the Gulf of Panamá were strongly correlated to a contemporaneous time-series record of surface water PO_4 SW at this site (r² = 0.7-0.9). This study supports application of the following multi-colony calibration equations to down-core records from comparable upwelling sites, resulting in ±0.2 and ±0.1 μmol/kg uncertainties in PO_4 SW reconstructions from P. lobata and P. gigantea, respectively.

     

New experimental constraints on the composition and structure of tholins

Powdered samples of carbon-nitrogen-hydrogen “tholins” that mimic Titan's atmosphere aerosols were produced under levitation conditions in the laboratory with a dusty plasma (PAMPRE experiment) using different initial N₂:CH₄ gas mixtures and studied using UV Raman and infrared spectroscopy, X-ray diffraction and high resolution transmission electron microscopy (HRTEM). Comparison between the tholins produced in the PAMPRE experiments and samples prepared by other techniques reveal that they form a fairly homogeneous family of hydrogenated carbon nitride materials. Wall effects during the PAMPRE deposition experiments and other were found to have little effect on the chemical structure of tholins. The first-order UV Raman bands of the disordered carbonaceous materials point to a large contribution of sp² clusters present compared with olefinic CN or CC groupings, whereas features at 690 and 980 cm⁻¹ suggest C₃N₃ rings are present as a species inserted in the macromolecular network. Diffraction techniques do not indicate the presence of large polyaromatic species in any of the tholins studied, whatever their nitrogen concentration, in disagreement with certain previous observations. This precludes the idea that the nature and degree of absorption in the visible range is controlled by the size of polyaromatic species, as has been observed in series of carbon-based materials obtained via thermal processing. Infrared spectroscopy analysis of the tholins has confirmed earlier identifications of chemical groups present including primary amines, nitriles, and alkyl moieties such as CH₂/CH₃, but has ruled out CH₂/CH₃ branches appearing on secondary or tertiary amines. Similar analyses were also performed on a polymeric (HCN)_x material, which was found to present several similarities with the tholins, hence suggesting similar polymerization processes.     

Mammal remains at Rantis Cave,Israel, and Middle–Late Pleistocene human subsistence and ecology in the Southern Levant

Rantis Cave is a recently discovered filled cave in central Israel, displaying a rich faunal accumulation of micromammals, ungulates and carnivores. U–Th dating assigns the beginning of accumulation to ca. 140 ka. The accumulation is culturally assigned to the late half of the Middle Paleolithic (MP) period. Single‐grain optically stimulated luminescence measurements attest to a complex sedimentological history. We present the cross‐disciplinary results of taphonomic and geomorphological analyses, which point to the cave serving as a natural pitfall trap for the large fauna, with little human or carnivore activity. The fauna is dominated by Dama among the ungulates and by Microtus among the micromammals. These data in conjunction with ungulate tooth mesowear analysis suggest a xeric Mediterranean environment on the eastern margin of the southern Levantine foothills. The relative taxonomic abundance of ungulate taxa shows some differences from anthropogenic MP sites, possibly reflecting the prey choice patterns of MP hunters. Overall, the natural accumulation scenario for Rantis Cave provides a rare paleoenvironmental and paleoeconomic reference to the rich anthropogenic MP faunas of the Southern Levant, enabling the reconstruction of a rich and diverse environmental setting for this important human dispersal route. Copyright © 2011 John Wiley & Sons, Ltd.     

Problems with binary pattern measures for flood model evaluation

As the calibration and evaluation of flood inundation models are a prerequisite for their successful application, there is a clear need to ensure that the performance measures that quantify how well models match the available observations are fit for purpose. This paper evaluates the binary pattern performance measures that are frequently used to compare flood inundation models with observations of flood extent. This evaluation considers whether these measures are able to calibrate and evaluate model predictions in a credible and consistent way, i.e. identifying the underlying model behaviour for a number of different purposes such as comparing models of floods of different magnitudes or on different catchments. Through theoretical examples, it is shown that the binary pattern measures are not consistent for floods of different sizes, such that for the same vertical error in water level, a model of a flood of large magnitude appears to perform better than a model of a smaller magnitude flood. Further, the commonly used Critical Success Index (usually referred to as F^{<2 >}) is biased in favour of overprediction of the flood extent, and is also biased towards correctly predicting areas of the domain with smaller topographic gradients. Consequently, it is recommended that future studies consider carefully the implications of reporting conclusions using these performance measures. Additionally, future research should consider whether a more robust and consistent analysis could be achieved by using elevation comparison methods instead. Copyright © 2013 John Wiley & Sons, Ltd.     

Thermal stresses in borehole heat exchangers

The backfilling materials of borehole heat exchangers (BHE), particularly the grout material, must provide a suitable thermal contact and ensure durability to the induced thermal stresses because of the heat loading. In this paper, the thermal stresses that occurred in BHEs because of heat injection or extraction is investigated with an analytical solution of a hollow cylinder model that is adapted for time‐dependent heat loading, the geometry of a BHE, and the thermo‐mechanical properties of surrounding ground conditions. Firstly, the hollow cylinder model is solved with the considered boundary conditions in 2D plane stress. Secondly, the temperature differences at the inner and outer circles of the cylinder are evaluated with the heat line source models for continuous and discontinuous loading to observe the impact of the heat loading schedule. The developed analytical solution for thermal stress investigation is validated with numerical models. It is demonstrated that the analytical solutions agree well with numerical results for two types of BHE configurations (co‐axial and single U‐shaped pipes). Furthermore, the calculated maximum stresses are compared with the tensile strength of grout materials obtained from Brazilian tests. It is predicted that the thermal contraction of the grout, partially constrained by the surrounding rock, generates tensile stresses that may lead to cracking in the BHE. According to the results, the stiffness of rock has a primary role on the developed tensile stresses, and the relationship between the thermal conductivity of the ground and of the grout induces a proportional impact on the magnitude of thermal stresses. Copyright © 2015 John Wiley & Sons, Ltd.     

The Upper Bajocian-Lower Bathonian boundary section in the outskirts of Saratov: Molluscan characteristics and biostratigraphy

The analysis of all available data on the structure of the Bajocian-Bathonian boundary section in the outskirts of Saratov (Sokur quarry) and the taxonomic composition of its ammonites, belemnites, and bivalves revealed a continuous succession of the Pseudocosmoceras michalskii (Upper Bajocian), Oraniceras besnosovi, and Arcticoceras ishmae (Lower Bathonian) zones. In connection with the critique by Meledina et al. (2009), correlation of Bajocian and Bathonian boundary strata of the Central Russia and Northern Siberia is discussed. The inconsistency of Siberian bivalve and belemnite assemblages with Central Russian ammonite zones is explained by heterochronous invasions of different molluscan groups.     

Wave characteristic and morphologic effects on the onshore hydrodynamic response of tsunamis

While the destruction caused by a tsunami can vary significantly owing to near- and onshore controls, we have only a limited quantitative understanding of how different local parameters influence the onshore response of tsunamis. Here, a numerical model based on the non-linear shallow water equations is first shown to agree well with analytical expressions developed for periodic long waves inundating over planar slopes. More than 13,000 simulations are then conducted to examine the effects variations in the wave characteristics, bed slopes, and bottom roughness have on maximum tsunami run-up and water velocity at the still water shoreline. While deviations from periodic waves and planar slopes affect the onshore dynamics, the details of these effects depend on a combination of factors. In general, the effects differ for breaking and non-breaking waves, and are related to the relative shift of the waves along the breaking–non-breaking wave continuum. Variations that shift waves toward increased breaking, such as steeper wave fronts, tend to increase the onshore impact of non-breaking waves, but decrease the impact of already breaking waves. The onshore impact of a tsunami composed of multiple waves can be different from that of a single wave tsunami, with the largest difference occurring on long, shallow onshore topographies. These results demonstrate that the onshore response of a tsunami is complex, and that using analytical expressions derived from simplified conditions may not always be appropriate.     

The use of natural and archeological analogues for understanding the long-term behavior of nuclear glasses

The knowledge of the long-term behavior of nuclear waste in anticipation of ultimate disposal in a deep geological formation is of prime importance in a waste management strategy. If phenomenological models have been developed to predict the long-term behavior of these materials, validating these models remains a challenge, when considering the time scale of radioactive decay of radionuclides of environmental concern, typically 10⁴–10⁵ yrs. Here we show how natural or archaeological analogues provide critical constraints not only on the phenomenology of glass alteration and the mechanisms involved, but also on the ability of experimental short-term data to predict long-term alteration in complex environments.