Arsenic contamination of groundwater: Mitigation strategies and policies

Contamination of groundwater by arsenic from natural geochemical sources is at present a most serious challenge in the planning of large-scale use of groundwater for drinking and other purposes. Recent improvements in detection limits of analytical instruments are allowing the correlation of health impacts such as cancer with large concentrations of arsenic in groundwater. However, there are at present no known large-scale technological solutions for the millions of people—mostly rural—who are potentially affected in developing countries. An overall framework of combating natural resource degradation is combined with case studies from Chile, Mexico, Bangladesh and elsewhere to arrive at a set of strategic recommendations for the global, national and local dimensions of the arsenic crisis. The main recommendations include: the need for flexibility in the elaboration of any arsenic mitigation strategy, the improvement and large-scale use of low-cost and participatory groundwater quality testing techniques, the need to maintain consistent use of key lessons learned worldwide in water supply and sanitation and to integrate arsenic as just one other factor in providing a sustainable water supply, and the following of distinct but communicable tracks between arsenic-related developments and enhanced, long-term, sustainable water supplies.

Structuring factors and recent changes in subtidal macrozoobenthic communities of a coastal lagoon, Arcachon Bay (France)

Sediment stability in the shallow Venice Lagoon was investigated by means of numerical modelling. Results from a hydrodynamic model allowed for the determination of the wave climate and bottom effective parameters so that simulations with a Lagrangian model for suspended particulate matter could be performed. A spring–neap cycle in summer 1998 was chosen as integration period since data for calibration and verification were collected within the European project F-ECTS between summer 1998 and spring 1999. Deposition on shallow mud flats as well as short term erosion during a strong wind event were reproduced and mass balances for two areas computed. A relation of patterns of SPM in the water and in the sediment was found and can be ascribed to the displacement of material during storm events from shallow areas to the bottom of very small channels. Assuming about 10 to 14 storm events during the year comparable to the Bora event during the integration time, estimates for long-term trends of sediment loss on shallow flats by Day et al. [Day, J.W., Rybczyk, J., Scarton, F., Rismondo, A., Are, D., Cecconi, G., 1999. Soil accretionary dynamics, sea-level rise and the survival of wetlands in Venice Lagoon: a field and modelling approach. Estuarine, Coastal and Shelf Science 49, 607–628] are met by the simulation results. Evidently, long-term sediment evolution of the lagoon is therefore not dominated by the average (residual) processes that occur in the lagoon, but by the few peak events that happen randomly over the year.     

Geological interpretation of combined SEABEAM,GLORIA and seismic data from Porto and Vigo Seamounts,Iberian continental margin

Long-range sidescan sonar (GLORIA) data over Porto and Vigo Seamounts collected in 1978 has been re-interpreted in the light of SEABEAM bathymetric surveys conducted in 1982. The application of quantitative bathymetric information enables the interpreter to allow for artefacts inherent in the GLORIA data and to separate topography-related primary backscattering variations on the sonographs from more subtle changes that result from textural, slope and outcrop effects. The distinctions are made easier when slant-range corrected GLORIA data are available.Use of the combined survey data to precisely locate seismic profiling tracks and to identify likely areas of outcrop has allowed refined geological maps of the seamounts to be drawn and regional fault trends detected. The overall outline of the seamounts appears strongly fault-controlled.Porto and Vigo Seamounts are made up of the same geological formations and have had a similar structural history since their uplift as continental fault blocks in the Late Cretaceous to Middle Eocene period. Ravines that dissect the presumably lithified scarps bounding the seamounts may be relict features but still appear to control sediment input to gulley and channel systems in the surrounding topography. Sedimentary ridges associated with the seamounts represent anomalously thick sequences of post-Eocene material and probably result from interaction of downslope sedimentary processes and contour-following boundary currents.Contribution No. 274 from the Groupe d'Etude de la Marge Continentale (ERA 605).     

Seasonal variations in dimethylsulfoniopropionate and dimethylsulfide concentrations in relation to the plankton community in the St. Lawrence Estuary

Weekly variations in total dimethylsulfoniopropionate (DMSPt) and dimethylsulfide (DMS) were investigated in relation to the phytoplankton assemblage from spring to fall 1994 at a coastal fixed station in the St. Lawrence Estuary. DMSPt and DMS concentrations showed a strong seasonality and were tightly coupled in time. Maximum concentrations of DMSPt and DMS were observed in July and August, during a period of warm water and low nutrient concentrations. Seasonal maxima of 365.4 nmol l⁻¹ for DMSPt and 14.2 nmol l⁻¹ for DMS in early August coincided with the presence of many phytoplankton species, such as Alexandrium tamarense, Dinophysis acuminata, Gymnodinium sp., Heterocapsa rotundata, Protoperidinium ovatum, Scrippsiella trochoidea, Chrysochromulina sp. (6 μm), Cryptomonas sp. (6 μm), a group of microflagellates smaller than 5 μm (mf < 5), many tintinnids, and Mesodinium rubrum. The abundance of mf < 5 followed the general trend of DMS concentrations. The temporal occurrence of high P. ovatum abundance and DMSPt concentrations suggests that this heterotrophic dinoflagellate can either synthesize DMSP or acquire it from DMSP-rich prey. The calculated sea-to-air DMS flux reached a maximum of 8.36 μmol ⁻² d⁻¹ on August 1. The estimated annual emission from the St. Lawrence Estuary is 77.2 tons of biogenic sulfur to the atmosphere.     

长江三角洲泥质潮坪沉积间断的定量分析

现场观测获得了长江口开敞型泥质潮坪不同时间尺度的沉积速率及层偶保存率。每天观测结果表明，单个层偶的保存率约为46．6％。随着观测时间间隔的增大保存率迅速减小,大小潮周期内层偶保存率降为9．2％，季节性观测层偶保存率为3．7％。现代长江三角洲建造一个完整的潮坪沉积层序约需96a。百年尺度潮坪层序层偶的保存率仅为0．74％，99．26％的潮汐周期由于侵蚀或无沉积而没有纹层保存下来，形成间断。因此，沉积间断占潮坪层序的比例应为99．26％。沉积速率和沉积时间之间存在对数线性负相关，拟合直线的斜率为－0．39，由此推导出潮坪层序的完整性计算公式为C＝（t^*/t)^ 0.39。虽然对泥质潮坪沉积中沉积间断的估计有很大的不确定性，但它是从现代沉积过程观测中得到的，可以帮助我们更深入地认识古代潮坪沉积的特征及其成因，并突出沉积间断在潮坪沉积层序中的重要性。     

Continental Lithospheric Contribution to Alkaline Magmatism: Isotopic (Nd, Sr, Pb) and Geochemical (REE) Evidence from Serra de Monchique and Mount Ormonde Complexes

Isotopic results (Sr, Nd, Pb), as well as concentrations ofmajor and trace elements (REE) are reported for whole-rock samplesand mineral separates from the onland alkaline complex of Serrade Monchique (South Portugal) and the offshore alkali basaltvolcanic suite of Mount Ormonde (Gorringe Bank). These two geneticallyrelated alkaline complexes were emplaced at the east Atlanticcontinent–ocean boundary during the Upper Cretaceous,i.e. 66–72 m.y. ago. Taken together, Serra de Monchiqueand Mount Ormonde may be seen as one of the few examples ofwithin-plate magmatism that straddles the continent–oceanboundary. Major and trace element compositions fail to revealany significant differences between onland and offshore complexes.This is particularly true regarding less differentiated samples(mg-number 0.40) which show the same progressive and continuousenrichment of their trace element patterns, with no specificanomaly (e.g. negative Nb anomaly) being present in samplesfrom the onland complex. Initial Pb and Sr isotopic compositionsalso do not allow any distinction to be made between Serra deMonchique and Mount Ormonde samples. Initial Pb isotope ratiosare moderately high (19.1 < ²⁰⁶Pb/²⁰⁴Pb < 19.8; ²⁰⁷Pb/²⁰⁴Pb= 15.6) in both cases. Moreover, once the effects of Sr contaminationby seawater are taken into account and the most contaminatedsamples discarded using data from fresh clinopyroxene separatesand results of leaching experiments, the initial Sr isotopiccompositions of Mount Ormonde samples are found to be unradiogenic(⁸⁷Sr/⁸⁶Sr = 0.7031±1) and identical to those obtainedat Serra de Monchique (⁸⁷Sr/⁸⁶Sr = 0.7032±1). In contrast,a systematic mean difference of 2 _Nd units is observed betweenSerra de Monchique [_Nd(T) = +4.8] and Mount Ormonde [_Nd(T) =+6.6] whole-rock samples. Surprisingly, a variation is alsoobserved at Mount Ormonde between the whole-rock samples andone of the two analysed clinopyroxene separates. Whereas MountOrmonde whole-rock samples invariably yielded _Nd(T) = +6.6 (meanvalue), a value of +0.5 is obtained for one clinopyroxene separate,whereas another gives +6.0. The above geochemical and isotopicresults make it possible to assign respective roles to the asthenosphere,lithosphere and crust in the petrogenesis of Serra de Monchiqueand Mount Ormonde complexes. We propose that both complexesshare a common mantle source whose isotopic characteristicsare very similar to the source of oceanic island basalts. Continentalmantle lithosphere, already characterized isotopically by studiesof peridotite massifs within the Iberian peninsula, acts asa contaminant which is evident onland on the whole-rock scale,and also present offshore as discrete clinopyroxene xenocrysts.The continental crust appears to play no role in the petrogenesisof the Serra de Monchique alkaline rocks. KEY WORDS: alkaline complexes; continental lithosphere; isotope geochemistry; passive continental margin; within-plate volcanics     

Oxygen isotopic constraints on the origin of magnesian chondrules and on the gaseous reservoirs in the early Solar System

We report in situ ion microprobe analyses of the oxygen isotopic composition of the major silicate phases (olivine, low-Ca pyroxene, silica, and mesostasis) of 37 magnesian porphyritic (type I) chondrules from CV (Vigarano USNM 477-2, Vigarano UH5, Mokoia, and Efremovka) and CR (EET 92042, EET 92147, EET 87770, El Djouf 001, MAC 87320, and GRA 95229) carbonaceous chondrites. In spite of significant variations of the modal proportions of major mineral phases in CR and CV chondrules, the same isotopic characteristics are observed: (i) olivines are isotopically homogeneous at the ‰ level within a chondrule although they may vary significantly from one chondrule to another, (ii) low-Ca pyroxenes are also isotopically homogeneous but systematically ¹⁶O-depleted relative to olivines of the same chondrule, and (iii) all chondrule minerals analyzed show ¹⁶O-enrichments relative to the terrestrial mass fractionation line, enrichments that decrease from olivine (±spinel) to low-Ca pyroxene and to silica and mesostasis. The observation that, in most of the type I chondrules studied, the coexisting olivine and pyroxene crystals and glassy mesostasis have different oxygen isotopic compositions implies that the olivine and pyroxene grains are not co-magmatic and that the glassy mesostasis is not the parent liquid of the olivine. The δ¹⁸O and δ¹⁷O values of pyroxene and olivine appear to be strongly correlated for all the studied CR and CV chondrules according to:

     

Competition in a Precambrian world: palaeoecology of Ediacaran fronds

Leaf‐shaped Ediacaran fronds are among the most widespread and readily recognized members of the terminal Neoproterozoic Ediacara Biota. Ediacaran fronds gathered nutrients from the water column through filter feeding or direct nutrient absorption, resulting in the onset of modern‐style ecological competition complete with denizens occupying distinct tiers in the water column. It is believed that the frond shape most likely represents a common need to elevate a feeding apparatus higher in the water‐column to feed from the upper (> 20 cm) tiers. Therefore, the frond shape represents a shared ecology, not ancestry.     

Coincidence or not? Interconnected gas/fluid migration and ocean–atmosphere oscillations in the Levant Basin

A growing number of studies on shallow marine gas/fluid systems from across the globe indicate their abundance throughout geological epochs. However, these episodic events have not been fully integrated into the fundamental concepts of continental margin development, which are thought to be dictated by three elements: tectonics, sedimentation and eustasy. The current study focuses on the passive sector of the Levant Basin on the eastern Mediterranean continental margin where these elements are well constrained, in order to isolate the contribution of gas/fluid systems. Single-channel, multichannel and 3D seismic reflection data are interpreted in terms of variance, chaos, envelope and sweetness attributes. Correlation with the Romi-1 borehole and sequence boundaries constrains interpretation of seismic stratigraphy. Results show a variety of fluid- or gas-related features such as seafloor and subsurface pockmarks, volumes of acoustic blanking, bright spots, conic pinnacle mounds, gas chimneys and high sweetness zones that represent possible secondary reservoirs. It is suggested that gas/fluid migrate upwards along lithological conduits such as falling-stage systems tracts and sequence boundaries during both highstands and lowstands. In all, 13 mid-late Pleistocene sequence boundaries are accompanied by independent evidence of 13 eustatic sea-level drops. Whether this connection is coincidental or not requires further research. These findings fill gaps between previously reported sporadic appearances throughout the Levant Basin and margin and throughout geological time from the Messinian until the present day, and create a unified framework for understanding the system as a whole. Repetitive appearance of these features suggests that their role in the morphodynamics of continental margins is more important than previously thought and thus may constitute one of the key elements of continental margin development.