Experimental Melting of Carbonated Peridotite at 6-10 GPa

Partial melting of magnesite-bearing peridotites was studiedat 6–10 GPa and 1300–1700°C. Experiments wereperformed in a multianvil apparatus using natural mineral mixesas starting material placed into olivine containers and sealedin Pt capsules. Partial melts originated within the peridotitelayer, migrated outside the olivine container and formed poolsof quenched melts along the wall of the Pt capsule. This allowedthe analysis of even small melt fractions. Iron loss was nota problem, because the platinum near the olivine container becamesaturated in Fe as a result of the reaction Fe₂SiO₄^Ol = Fe^Fe–Ptalloy + FeSiO₃^Opx + O₂. This reaction led to a gradual increasein oxygen fugacity within the capsules as expressed, for example,in high Fe³⁺ in garnet. Carbonatitic to kimberlite-like meltswere obtained that coexist with olivine + orthopyroxene + garnet± clinopyroxene ± magnesite depending on P–Tconditions. Kinetic experiments and a comparison of the chemistryof phases occasionally grown within the melt pools with thosein the residual peridotite allowed us to conclude that the meltshad approached equilibrium with peridotite. Melts in equilibriumwith a magnesite-bearing garnet lherzolite are rich in CaO (20–25wt %) at all pressures and show rather low MgO and SiO₂ contents(20 and 10 wt %, respectively). Melts in equilibrium with amagnesite-bearing garnet harzburgite are richer in SiO₂ andMgO. The contents of these oxides increase with temperature,whereas the CaO content becomes lower. Melts from magnesite-freeexperiments are richer in SiO₂, but remain silicocarbonatitic.Partitioning of trace elements between melt and garnet was studiedin several experiments at 6 and 10 GPa. The melts are very richin incompatible elements, including large ion lithophile elements(LILE), Nb, Ta and light rare earth elements. Relative to theresidual peridotite, the melts show no significant depletionin high field strength elements over LILE. We conclude fromthe major and trace element characteristics of our experimentalmelts that primitive kimberlites cannot be a direct productof single-stage melting of an asthenospheric mantle. They rathermust be derived from a previously depleted and re-enriched mantleperidotite. KEY WORDS: multianvil; carbonatite melt; peridotite; kimberlite; element partitioning     

The effect of the Fernando de Noronha plume on the mantle lithosphere in north-eastern Brazil

New xenolith occurrences in the Cenozoic alkali basalts of north-eastern Brazil have been studied in order to constrain the possible imprint on the continental mantle lithosphere of its passage over the Fernando de Noronha plume and the regional mantle processes. Texturally, the lherzolite and harzburgite xenoliths define three groups: group 1, porphyroclastic; group 2, protogranular; group 3, transitional between groups 1 and 2. Equilibrium temperatures are highest for group 1 and lowest for group 2. Clinopyroxenes from group 1 peridotites have Primitive Mantle (PM)-normalised REE patterns varying from L-MREE-enriched convex-upward, typical of phases in equilibrium with alkaline melts, to LREE-enriched, spoon-shaped, to LREE-enriched, steadily fractionated in a wehrlite. Group 2 clinopyroxenes show patterns slightly depleted in LREE to nearly flat. The M-HREE are at 3–5 ×PM concentration level, as typical in fertile lithospheric lherzolites. Most of group 3 clinopyroxenes show LREE-depleted patterns similar to the group 2 ones, but in two samples the clinopyroxenes are characterised by LREE-enriched, spoon-shaped profiles. Sr and Nd isotopes of the group 1 clinopyroxenes form an array between DM and EMI-like components, both of them are also present in the host basalts. Melts estimated to be in equilibrium with the group 1 clinopyroxenes having L-MREE-enriched, convex-upward patterns are similar to the Cenozoic alkaline magmas. The groups 2 and 3 clinopyroxenes define two distinct compositional fields at higher ¹⁴³Nd/¹⁴⁴Nd values, correlated with their LREE composition. The isotopes of the groups 2 and 3 LREE-depleted clinopyroxenes form an array from DM towards the isotopic composition of Mesozoic tholeiitic basalts from north-eastern Brazil. Melts in equilibrium with these clinopyroxenes are similar to these basalts, thus suggesting that such xenoliths record geochemical imprint from older melt-related processes.

The LREE-enriched spoon-shaped group 3 clinopyroxenes are characterised by the highest ¹⁴³Nd/¹⁴⁴Nd values at any given ⁸⁷Sr/⁸⁶Sr composition. These results are interpreted in terms of a lithospheric mantle section which underwent thermo-chemical and mechanical erosion by infiltration of asthenospheric alkali basalts having EMI-like isotope characteristics during Cenozoic time. At that time, the lithospheric mantle consisted of fertile lherzolites and harzburgites recording the geochemical imprint of Mesozoic mantle processes. The onset of the interaction between lithospheric peridotites and alkaline melts was characterised by the porous flow percolation of small melt volumes that induced chromatographic enrichments in highly incompatible elements and the isotope signature of the spoon-shaped, group 3 clinopyroxenes. Group 1 peridotites represent the base of the lithospheric column eroded by the ascending alkaline melts, whereas the group 2 documents the shallower lithospheric section, with group 3 being the transition. The similarity of processes and isotope components in the protogranular xenoliths from Fernando de Noronha area and north-eastern Brazil supports the hypothesis that the lithosphere beneath Fernando de Noronha is a detached portion of the continental one. Furthermore, the similarity in terms of textural and geochemical features documented by the mantle samples coming from the two different regions seems to confirm the interference of the two regions with the same plume.     

800-yr-long records of annual air temperature and precipitation over southern Siberia inferred from Teletskoye Lake sediments

A unique 800-yr-long record of annual temperatures and precipitation over the south of western Siberia has been reconstructed from the bottom sediments of Teletskoye Lake, Altai Mountains using an X-ray fluorescence scanner (XRF) providing 0.1-mm resolution timeseries of elemental composition and X-ray density (XRD). Br content appears to be broadly correlative with mean annual temperature variations because of changes in catchment vegetation productivity. Sr/Rb ratio reflects the proportion of the unweathered terrestrial fraction. XRD appears to reflect water yield regime and sediment flux. Sedimentation is rather continuous because annual clastic supply and deposited mass are the same. The artificial neural networks method was applied to convert annual sedimentary time-series of XRD, Br content, and Sr/Rb ratio to annual records of temperature and precipitation using a transfer function. Comparison of these reconstructed Siberian records with the annual record of air temperature for the Northern Hemisphere shows similar trends in climatic variability over the past 800 yr. Estimated harmonic oscillations of temperature and precipitation values for both historical and reconstructed periods reveal subdecadal cyclicity.     

The thermo-tectonic history of the Song-Kul plateau, Kyrgyz Tien Shan: Constraints by apatite and titanite thermochronometry and zircon U/Pb dating

The Song-Kul Basin sits on a plateau at the Northern and Middle Kyrgyz Tien Shan junction. It is a lacustrine basin, occupied by Lake Song-Kul and predominantly developed on igneous basement. This basement was targeted for a multi-method chronological study to identify the different magmatic episodes responsible for basement formation and to constrain the timing of the development of its present-day morphology. Zircon U/Pb dating by LA-ICP-MS revealed four different magmatic episodes: a Late Cambrian (~ 500 Ma) island arc system, a Late Ordovician (~ 450 Ma) subduction related intrusion, an Early Permian (~ 290 Ma) collisional stage, and a Middle to Late Permian (~ 260 Ma) post-collisional magmatic pulse. Middle to Late Triassic (~ 200–230 Ma) titanite fission-track ages and Late Triassic – Early Jurassic (~ 180–210 Ma) apatite fission-track ages and thermal history modeling indicate the Song-Kul basement was already emplaced in the shallow crust at that time. An exhumed fossil apatite fission-track partial annealing zone is recognized in the bordering Song-Kul mountain ranges. The area experienced only minor post-Early Mesozoic denudation. The igneous basement was slowly brought to apatite (U–Th)/He retention temperatures in the Late Cretaceous–Palaeogene. Miocene to present reactivation of the Tien Shan does not manifestly affect this part of the orogen.     

Identification of hydrogeochemical processes in a volcano-sedimentary aquifer of Ciénega de Chapala in Michoacán,Mexico

The present study characterized the hydrogeochemical processes of the aquifer of Ciénega de Chapala in Michoacán, Mexico. The dominant water families contained bicarbonate magnesium and sodium. In the region, water infiltrates into a fractured volcanic environment exposed in the surrounding mountains and is transmitted to the volcano-sedimentary units of the ciénega, where silicate alteration and ion exchange processes occur in the clays of the subsoil. The Gibb diagrams confirm that the main evolutionary processes in the aquifer are rock-water interactions in the local flow and evaporation in the intermediate and regional flows. The molar ratios of HCO₃/Na and Ca/Na are congruent with the type of volcano-sedimentary environment present in the area. Ternary mixing processes associated with three end members were also identified and were related to the flow systems in the area. The local flow contributes 77% of water to the system, and the intermediate and regional flows contribute 16% and 7%, respectively.     

Middle to Late Pleistocene lake‐level fluctuations of Lake El'gygytgyn,far‐east Russian Arctic

Lake El'gygytgyn, located in central Chukotka, Russian Arctic, was the subject of an international drilling project that resulted in the recovery of the longest continuous palaeoclimatic and palaeoenvironmental record for the terrestrial Arctic covering the last 3.6 million years. Here, we present the reconstruction of the lake‐level fluctuations of Lake El'gygytgyn since Marine Isotope Stage (MIS) 7 based on lithological and palynological as well as chronological studies of shallow‐water sediment cores and subaerial lake terraces. Reconstructed lake levels show an abrupt rise during glacial–interglacial terminations (MIS 6/5 and MIS 2/1) and during the MIS 4/3 stadial–interstadial transition. The most prominent lowstands occurred during glacial periods associated with a permanent lake‐ice cover (namely MIS 6, MIS 4 and MIS 2). Major triggering mechanisms of the lake‐level fluctuations at Lake El'gygytgyn are predominantly changes in air temperature and precipitation. Regional summer temperatures control the volume of meltwater supply as well as the duration of the lake‐ice cover (permanent or seasonal). The duration of the lake‐ice cover, in turn, enables or hampers near‐shore sediment transport, thus leading to long‐term lake‐level oscillations on glacial–interglacial time scales by blocking or opening the lake outflow, respectively. During periods of seasonal ice cover the lake level was additionally influenced by changes in precipitation. The discovered mechanism of climatologically driven level fluctuations of Lake El'gygytgyn are probably valid for large hydrologically open lakes in the Arctic in general, thus helping to understand arctic palaeohydrology and providing missing information for climate modelling.     

Vegetation and climate history in the Laptev Sea region (Arctic Siberia) during Late Quaternary inferred from pollen records

Paleoenvironmental records from a number of permafrost sections and lacustrine cores from the Laptev Sea region dated by several methods (¹⁴C-AMS, TL, IRSL, OSL and ²³⁰Th/U) were analyzed for pollen and palynomorphs. The records reveal the environmental history for the last ca 200 kyr. For interglacial pollen spectra, quantitative temperature values were estimated using the best modern analogue method. Sparse grass-sedge vegetation indicating arctic desert environmental conditions existed prior to 200 kyr ago. Dense, wet grass-sedge tundra habitats dominated during an interstadial ca 200–190 kyr ago, reflecting warmer and wetter summers than before. Sparser vegetation communities point to much more severe stadial conditions ca 190–130 kyr ago. Open grass and Artemisia communities with shrub stands (Alnus fruticosa, Salix, Betula nana) in more protected and moister places characterized the beginning of the Last Interglacial indicate climate conditions similar to present. Shrub tundra (Alnus fruticosa and Betula nana) dominated during the middle Eemian climatic optimum, when summer temperatures were 4–5 °C higher than today. Early-Weichselian sparse grass-sedge dominated vegetation indicates climate conditions colder and dryer than in the previous interval. Middle Weichselian Interstadial records indicate moister and warmer climate conditions, for example, in the interval 40–32 kyr BP Salix was present within dense, grass-sedge dominated vegetation. Sedge-grass-Artemisia-communities indicate that climate became cooler and drier after 30 kyr BP, and cold, dry conditions characterized the Late Weichselian, ca 26–16 kyr BP, when grass-dominated communities with Caryophyllaceae, Asteraceae, Cichoriaceae, Selaginella rupestris were present. From 16 to 12 kyr BP, grass-sedge communities with Caryophyllaceae, Asteraceae, and Cichoriaceae indicate climate was significantly warmer and moister than during the previous interval. The presence of Salix and Betula reflect temperatures about 4 °C higher than present at about 12–11 kyr BP, during the Allerød interval, but shrubs were absent in the Younger Dryas interval, pointing to a deterioration of climate conditions. Alnus fruticosa, Betula nana, Poaceae, and Cyperaceae dominate early Holocene spectra. Reconstructed absolute temperature values were substantially warmer than present (up to 12 °C). Shrubs gradually disappeared from coastal areas after 7.6 kyr BP when vegetation cover became similar to modern. A comparison of proxy-based paleoenvironmental reconstructions with the simulations performed by an Earth system model of intermediate complexity (CLIMBER-2) show good accordance between the regional paleodata and model simulations, especially for the warmer intervals.