Diatom stratigraphy in five offshore sediment cores from the northwestern Baltic proper implying large scale circulation changes during the last 8500 years

Five Holocene sediment cores from the northwestern Baltic proper were analysed for lithology, siliceous microfossil assemblages and geochemical parameters. The data indicate that surface water salinity and redox conditions below the halocline have changed drastically at least four times since the Baltic Sea changed from a fresh water lake (the Ancylus Lake) to a semi-enclosed brackish water sea (the Litorina Sea) c. 8500 yrs BP. These variations appear to be mainly effects of changes in water depth at the thresholds of inlet areas. Based on these changes, and earlier studies of the shoreline displacement in the inlet areas, we propose a tentative model for changes of large scale water circulation in the Baltic Sea during the last c. 8500 yrs.At the transition from fresh to brackish water 8500 ¹⁴C yrs BP, upwelling of nutrient rich bottom water started to occur, causing a slight increase in primary production. Diatom assemblages in sediments indicate a slow rise in surface water salinity during this period.At 7000-6500 ¹⁴C yrs BP, surface water salinity and primary production simultaneously increased, as anoxic bottom conditions were established at depth below the halocline. We suggest that high primary production was caused by increased input of oceanic water, leading to increased upwelling of nutrient rich bottom water. At the anoxic bottoms laminated sediments formed until 5000-4500 ¹⁴C yrs BP. This period (c. 7000-4500 ¹⁴C BP) was contemporaneous with the post-glacial transgression maximum in Öresund, and we suggest it represents the most saline phase of the Baltic Sea post-glacial history.Due to a regression in Öresund starting 4500 ¹⁴C yrs BP, upwelling decreased and the halocline was lowered, resulting in decreased primary productivity and hence oxic deep water conditions. The diatom assemblages of the sediments indicate a lowering of salinity at the beginning of this period.We suggest that the second period of anoxic bottom conditions c. 2000-1500 ¹⁴C yrs BP was caused by a change of dominating inflows from the Öresund to the Belt Sea. This resulted in decreased salinity of the inflowing water which did not penetrate to the deepest parts of the basin as frequently as before. The diatom record indicates both a second lowering of salinity and a change in the large scale water circulation at the beginning of this period.     

Frontogenesis and cross frontal circulation in a strong summertime cold front

Summary The characteristics of a strong European summertime cold front are investigated using the wealth of synoptic observations, which were analysed by the dynamical initialization scheme of an operational meso-scale model. The study was also extended to forecasted fields.Cross-sections perpendicular to the front, covering a dormain of more than 2000 km in the horizontal and 10 km in the vertical direction, bring out the basic parameters (as potential temperature and the components of the geostrophic and ageostrophic wind vectors), the ageostrophic crossfrontal circulation and all cross-frontal frontogenesis terms.None of the many frontogenesis terms plays a dominant role, there is a concerted action of geostrophic and ageostrophic deformation and shear, of tilting and diabatic sources in producing a rather complex structure of total frontogenesis. The cross-sectional fields of all presented terms strongly underline the fact, that a front is not a line of discontinuity but a rather wide three-dimensional field phenomenon.With 12 Figures     

Detection of organic biomarkers in crude oils using ToF-SIMS

In this study, we show that time of flight-secondary ion mass spectrometry (ToF-SIMS) can be used to detect organic biomarkers, such as hopanes and steranes, in non-fractionated crude oils, without extraction and chemical preparation. Hopanes and steranes may provide valuable information on the history of life on early Earth, particularly if they are present in fluid inclusions in ancient rocks. Due to the presence of different generations of inclusions in even very small rock samples, it would be advantageous to find a method capable of detecting biomarkers in single oil rich fluid inclusions. The capability of ToF-SIMS for detailed chemical analysis of very small sample amounts makes it a potential technique for such analysis, and in this work this possibility is explored. The presence of hopanes and steranes in four different crude oils of different ages and stages of biodegradation was investigated using ToF-SIMS and GC–MS. By combining analyses of biomarker standards, crude oils and chromatographic oil fractions, specific peaks for the different biomarkers were identified in the ToF-SIMS spectra. The presence of these peaks in the spectra from the crude oil samples could be attributed to the biomarkers based on exact mass determination and by comparison with the spectra from the biomarker containing and biomarker lacking fractions, respectively. In addition, the results show that a significant biomarker signal may be obtained from a 10 μm² oil sample, demonstrating the potential of ToF-SIMS for analysis of single oil bearing fluid inclusions, which in turn may contribute to a better understanding of the early history of life on Earth.     

The “Donauplatin”: source rock analysis and origin of a distal fluvial Au-PGE placer in Central Europe

The mineral assemblage and the sedimentological characteristics of the “Donauplatin” (Danubian fluvial placer containing platinum-group elements (PGE) and gold (Au)) are described for the first time in connection with upstream reference placer deposits near the potential source area in tributaries of the River Danube/Donau. Granulometric and morphometric data have been obtained using the CCD-based CAMSIZER technique. The platinum-group minerals (PGM; iridium, osmium, unknown iridium-osmium-sulfide, ruthenium-osmium-iridium alloys, platinum-iron alloys, iridium-bearing platinum, sperrylite) have been derived from ultramafic magmatic rocks, probably belonging to the ophiolitic series in the Tepla Barrandian unit of the Bohemian Massif. The Au-Pd-Cu compounds in the placer originated from dynamo-metamorphogenic processes in a sulfur-deficient environment at the SW edge of the Bavarian Basement. Gold in the “Donauplatin” has been reworked from a “secondary” or intermediate repository of lateritic gold (Boddington-type). Its primary source is supposed to be of orogenic origin. Provenance analyses of the associated non-heavy minerals point to high-pressure metamorphic rocks, igneous rocks (monazite) and high-temperature metamorphic rocks (750° to 850°C, zircon morphology). Garnet compositions indicate that meta(ultra)basic igneous rocks, calc-silicate rocks and skarns prevailed over paragneisses in the provenance area. Extraterrestrial processes creating the well-known Ries impact crater in the environs of Nördlingen during the Miocene have a minor share in the PGE budget by delivering molybdenum-ruthenium-osmium-iridium alloys and iridium solid-solution series (s.s.s.) minerals. Judging by the heavy mineral suites, Saxothuringian source rocks of the NE Bavarian Basement connected with the Donau River via the Naab River drainage system have not contributed to the element budget of the “Donauplatin” under study. Stream sediments which have been derived from this provenance area are characterized by low-temperature (LT) crystalline rocks and a considerable proportion of pegmatitic and metabauxitic material lacking in the Holocene sediments of the “Donauplatin”.     

Succession and seasonal onset of colonization in subtidal hard‐bottom communities off northern Chile

Although there is extensive information concerning the colonization sequences of benthic communities, little is known about the successional development of subtidal hard‐bottom habitats in highly productive coastal upwelling areas. In these systems, succession is predicted to be fast due to high growth rate of the later dominant colonizers. Using artificial hard substrata a field experiment was conducted in a rocky subtidal area off Northern Chile (Humboldt Current System) and monitored at 3‐month intervals to test the following hypotheses: (i) epibenthic succession may proceed through consecutive replacement of species, (ii) there is a fast convergence rate towards natural communities, and (iii) different seasonal starting points for the colonization will produce different community structure over a 1‐year period of exposure. Panels were installed on a vertical wall at 17 m water depth. Three replicate panels were sampled every 3 months over a period of 27 months. As a reference, six haphazardly selected plots from the surrounding natural community were surveyed at each sampling date. To evaluate how seasonally varying substratum availability affects community development, further panels were exposed for a 12‐month period, starting in four different seasons (n = 3 replicates per season). Community succession was slow and occurred through progressive changes, between early encrusting red corallines, middle Balanus flosculus and late Lagenicella variabilis. After 27 months, the community composition, but not its structure, was similar between experimental and reference communities on surrounding rocky bottoms. Seasonality had no effects and after 1 year of exposure the experimental communities converged towards a common structure. This study indicates that succession of subtidal epibenthic communities follows a slow and predictable pattern with a dominant late colonial species. In addition, aseasonal variability might be more relevant during colonization and succession in this upwelling ecosystem.     

Using the anchoring device of a comet lander to determine surface mechanical properties

Owing to the low surface gravity of the Rosetta target comet 46P/Wirtanen, a means of anchoring the Rosetta Lander to the cometary surface will be necessary. This task can be accomplished by firing an anchor into the cometary soil immediately after touchdown to prevent a rebound of the spacecraft from the surface or subsequent ejection by other forces, and to allow for mechanical activities (drilling, etc.) at the landing site.

The rationale for anchoring is examined, based on estimates of the main forces likely to act on the spacecraft after landing. We report on the development of an anchoring device using a pyrotechnic gas generator as a power source and an instrumented anchor.

In addition to the anchoring function, which is the primary purpose of this system, the integration of acceleration and temperature sensors into the tip offers the possibility to determine some important material properties of the cometary surface layer. The accelerometer is designed to measure the deceleration history of the projectile and is thus expected to give information on how the material properties (in particular strength) change within the penetrated layer(s), while the temperature sensor will measure temperature variations at the depth at which the anchor finally comes to rest. As the mechanical properties of the material are not known, it is difficult to predict the final depth of the anchor with any great certainty, but it may well be greater than that reached by any other of the lander's instruments.

The instrumented anchor will be part of the MUPUS experiment, selected to form part of the Rosetta Lander payload. We report on results of laboratory simulations of anchor penetration performed at the Institut für Weltraumforschung, Graz, and compare these with models of projectile penetration. The value of the results expected from the penetrometry experiment in the context of an improved understanding of cometary processes is discussed.     

Allocation of effort in artisanal fisheries: The importance of migration and temporary fishing camps

In order to avoid conflicts when spatially explicit rules are implemented, it is critical to understand the spatial distribution of fishing effort, the migration patterns of fishermen and the use of temporary fishing camps. The migration of fishermen is a process shaped by historical patterns of resource availability, in addition to economic and political factors. We present an example in which a temporary fishing camp used for extraction of benthic resources (Loco: Concholepas concholepas) changed into a permanent one during the study period. Throughout the study period fishing effort (trips) was closely related to the productivity of the different fishing grounds, with more trips directed to the most productive areas. The conversion from a temporary to a permanent fishing camp did not improve the efficiency of the loco fishery, but did allow better access to alternative resources (surf clams) on nearby fishing grounds. The succession from simple shelters to a permanent ‘caleta’ is a common situation along the Chilean coast, motivated originally by resource availability and more recently by the creation of the TURF system. In particular the TURF system converts temporary (resource driven) movements of fishermen into rigid stationary caletas, which creates a number of problems. Temporary fishing camps are common when fishing grounds are far from the base port, but they require specific administrative tools in order to achieve sustainable fisheries management.     

Photometry of the minima of TX Herculis

Three epochs of primary and four epochs of secondary minima of TX Her were determined from photoelectric observations made between 1968 and 1973. The individual observations in three colours are given in Tables I-III.     

A preferred orientation of extragalactic double radio sources

The distribution of the main axes of double radio sources is used to test isotropy of that part of the universe which is accessible to radio investigations. Data for 274 double and/or extended sources have been taken from the literature to compute the fit to several simple models of global orientation by means of a ²-test. The best fit has been found on a 3%-significance level for the preferred orientation along a right-handed helix with pitch angle 82° in the direction =95°, =–38° (165°,b=20°). This preferential alignment of radio sources is assumed to be caused by a largescale magnetic field.