冰后期以来长江水下三角洲层序地层特征及沉积环境演化*

长江水下三角洲层序地层学研究有助于全面了解长江三角洲地层特征和沉积环境演化模式。通过对长江水下三角洲下切河谷区YD0901和YD0903孔岩心的详细沉积物粒度、特征元素比值(Cl/Ti和Zr/Rb)、沉积相对比分析,恢复了冰后期以来长江水下三角洲层序地层格架。研究区冰后期以来自下而上依次出现河流相、潮汐河流相、河口湾相、浅海相和三角洲相的沉积相序。末次冰期海平面下降,古长江形成下切河谷,古河间地发育硬黏土层,构成五级Ⅰ型层序界面。之后海平面回升,分别于15 cal ka BP和8.0 cal ka BP形成最大海退和最大海侵界面,水下三角洲区域最大海侵发生时间略滞后于平原区,约为7.5 cal ka BP。据此3个层序界面将冰后期地层划分为低位体系域、海侵体系域和高位体系域。钻孔岩心记录揭示了14.8 cal ka BP海侵到达研究区;14.8~13 cal ka BP期间,受MWP-1A冰融水事件影响海平面快速上升,海岸线向陆推进速率可达71.9,km/ka;海退期间各钻孔沉积速率较低,直至2 cal ka BP开始,沉积速率明显增加。     

A sedimentary record of the rise and fall of the metal industry in Bergslagen,south central Sweden

Detailed stratigraphic analyses of sediments deposited in Lake Botjärnen, a small boreal forest lake in the shield terrain of central Sweden, clearly reflect progressively increasing human impact on terrestrial and aquatic ecosystems following settlement and establishment of an iron industry in the 17th century. Rising frequencies of pollen and spores from light-demanding plants provide evidence of extensive forest clearance for charcoal and timber production, which peaked in the early 20th century. An associated increase in catchment erosion is reflected by changing carbon and nitrogen elemental content and carbon–isotope composition of sediment organic matter and by increased magnetic susceptibility of the sediments. Records of air-borne pollutants (lead, zinc and sulphur) can be correlated to the development of local and regional mining and metal industry as inferred from historical accounts. Rapid recession of the iron industry led to re-forestation and recovery of the aquatic nutrient status to pre-industrial conditions over the past 100 years. The chronology of the sediment succession, which is based on ²¹⁰Pb and ¹³⁷Cs radionuclide data in combination with radiocarbon dating, is confirmed by historical lead pollution trends established for the region.     

胶东金银矿石英主微量元素化学成分特征及意义

石英是自然界分布很广的矿物,是金矿中重要的载金矿物之一,在金矿的各个成矿阶段均有出现。目前对胶东各类型金银矿中石英的化学成分标型研究还较薄弱。该文对胶东各类型金银矿中成矿期石英的化学成分进行了详细研究,结果表明,各金银矿中石英中K/Na,Al,Na-K-Al和(Na+K)-Al参数均有显著区别,可用于区分胶东各类型金银矿,以上区别和各金银矿不同的成矿环境密切相关。以上结论对胶东各金银矿的成因和找矿具有借鉴意义。     

黔中开阳磷矿沉积区震旦纪陡山沱期定量岩相古地理重建*

磷矿的沉积和成矿与成磷期的古地理环境密切相关。本文首次将“单因素分析多因素综合作图法”运用于开阳地区震旦纪陡山沱期沉积型磷矿床的成矿分析和找矿预测上。通过选取陡山沱组及其各岩性段的地层厚度及磷矿层品位作为单因素,确定开阳地区古地理格局;结合地层岩性组合、沉积特征等多因素综合分析,恢复开阳地区成矿期沉积环境,编制陡山沱早期、中期和晚期岩相古地理图。根据定量岩相古地理重建结果,认为开阳地区陡山沱期整体处于南靠黔中古陆、地势南高北低、局部地形复杂的滨岸海滩沉积环境,其中临滨带为最有利成矿带,局部地形变化也会造成矿层厚度、品位的差异;矿层受到的水流冲蚀、暴露、淋滤及再沉积作用是导致矿石品位显著提升的关键因素。通过定量岩相古地理学精确还原成矿期古地理环境、解析多期次沉积成矿过程,对于确定磷矿控矿因素、构建找矿预测模型和预测矿体空间位置具有重要意义。     

基于多元回归分析的铬污染地下水风险评价方法

土-水分配系数（K_d）是表征重金属污染物在土壤包气带中迁移能力的重要参数,受污染物质量浓度、pH值、有机质质量分数、铁铝氧化物质量分数等多种因素影响。本文通过实验研究了分配系数与各种影响因素之间的关系,基于多元回归分析方法得到了分配系数与影响因素的关系方程;并以分配系数、泄漏量、土壤孔隙度、初始含水率为风险因子建立了地下水污染风险评价方法。以某工厂铬废液的泄露为案例,采用构建的方法进行地下水污染风险评价。结果表明：该处地下水被污染的风险等级为中等。地下水污染风险评价方法的建立为重金属污染地下水的监测管理提供了一种有效方法。     

全新世黄土记录的古气候演化及磁化率和粒度参数灵敏性探讨

黄土是公认的三大古气候记录载体之一,全新世黄土由于位于顶层极易受到人类活动的影响,故研究程度不高.最近在甘肃会宁白草塬发现一个沉积连续、分辨率高、且保存完整的全新世黄土剖面,该剖面忠实地记录了全新世古气候演化,能够很好地与三宝洞和葫芦洞石笋氧同位素记录全新世古气候进行对比:二者共同记录了约12.5 ～11.5ka之间的Younger Dryas冷干事件;约10.5 ～5.2ka全新世适宜期,但是适宜期中气候变化具有不稳定性;5.2ka至今,气候较全新世适宜期慢慢变干变冷,二者相互印证了东亚季风区全新世古气候演化的一般过程;而驱动二者演化主要因素是太阳辐射量的变化.位于黄土高原西北边缘的会宁白草塬剖面中的磁化率和粒度两参数相比较:粒度较磁化率波动更频繁,记录古气候变化更灵敏.     

Lake ecosystem dynamics and links to climate change inferred from a stable isotope and organic palaeorecord from a mountain lake in southwestern China (ca. 22.6–10.5 cal ka BP)

A detailed understanding of long-term climatic and environmental change in southwestern China is hampered by a lack of long-term regional palaeorecords. Organic analysis (%TOC, %TN, C/N ratios and δ¹³C values) of a sediment sequence from Lake Shudu, Yunnan Province (ca. 22.6–10.5 cal ka BP) indicates generally low aquatic palaeoproductivity rates over millennial timescales in response to cold, dry climatic conditions. However, the record is punctuated by two marked phases of increased aquatic productivity from ca. 17.7 to 17.1 cal ka BP and from ca. 11.9 to 10.5 cal ka BP. We hypothesise that these shifts reflect a marked, stepwise lacustrine response to Asian summer monsoon strengthening during the last deglaciation.     

Variation in n-alkane δD values from terrestrial plants at high latitude: Implications for paleoclimate reconstruction

The molecular hydrogen isotope composition (δD) of leaf waxes from terrestrial plants is increasingly used to infer hydrological characteristics of ancient high latitude climates. Analysis of the hydrogen isotope composition of n-alkanes (δD_n-alkane) from a global dataset of individual plants growing at low and middle latitudes indicates that plant ecological life form is an important factor in determining the hydrogen isotope fractionation. However, environmental and biological controls of high latitudinal leaf wax δD values are poorly understood because of a lack of δD records from modern flora in these regions. We previously noticed smaller apparent hydrogen isotope fractionations between n-alkanes and environmental water (ε_alk-water) in deciduous trees growing at high latitudes (>59°N; Liu, W.-G., Yang, H., 2008. Multiple controls for the variability of hydrogen isotopic compositions in higher plant n-alkanes from modern ecosystems. Global Change Biology 14, 2166-2177.) To further examine these issues, we measured δD_n-alkane from a variety of plants that inhabit high latitude environments and added critically needed leaf wax δD data from grass and herbs to the existing global δD_n-alkane database. Inclusion of these new data with the existing global dataset (n = 408) confirms plant ecological life form as an important control for leaf wax δD variation for terrestrial plants living at high latitudes. Our results suggest that, while precipitation δD is captured in these high latitude plants, physiological characters such as leaf area, venation pattern and hydraulic system, that enhance transpiration rate during summer growth, may impart δD_n-alkane differences among plants with different ecological life forms.     

Re–Os molybdenite ages and zircon Hf isotopes of the Gangjiang porphyry Cu–Mo deposit in the Tibetan Orogen

The Miocene porphyry Cu–(Mo) deposits in the Gangdese orogenic belt in southern Tibet were formed in a post-subduction collisional setting. They are closely related to the Miocene adakite-like porphyries which were probably derived from a thickened basaltic lower crust. Furthermore, mantle components have been considered to have played a crucial role in formation of these porphyry deposits (Hou et al. Ore Geol Rev 36: 25–51, 2009; Miner Deposita doi:10.1007/s00126-012-0415-6, 2012). In this study, we present zircon Hf isotopes and molybdenite Re–Os ages on the newly discovered Gangjiang porphyry Cu–Mo deposit in southern Tibet to constrain the magma source of the intrusions and the timing of mineralization. The Gangjiang porphyry Cu–Mo deposit is located in the Nimu ore field in the central Gangdese porphyry deposits belt, southern Tibet. The copper and molybdenum mineralization occur mainly as disseminations and veins in the overlapped part of the potassic and phyllic alteration zones, and are predominantly hosted in the quartz monzonite stock and in contact with the rhyodacite porphyry stock. SIMS zircon U–Pb dating of the pre-mineral quartz monzonite stock and late intra-mineral rhyodacite porphyry yielded ages of 14.73?±?0.13 Ma (2σ) and 12.01?±?0.29 Ma (2σ), respectively. These results indicate that the magmatism could have lasted as long as about 2.7 Ma for the Gangjiang deposit. The newly obtained Re–Os model ages vary from 12.51?±?0.19 Ma (2σ) to 12.85?±?0.18 Ma (2σ) for four molybdenite samples. These Re–Os ages are roughly coincident with the rhyodacite porphyry U–Pb zircon age, and indicate a relatively short-lived episode of ore deposition (ca. 0.3 Ma). In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS indicate that the ε _Hf(t) values of zircons from a quartz monzonite sample vary from +2.25 to +4.57 with an average of +3.33, while zircons from a rhyodacite porphyry sample vary from +5.53 to +7.81 with an average of +6.64. The Hf data indicate that mantle components could be partly involved in the deposit formation, and that mantle contributions might have increased over time from ca. 14.7 to 12.0 Ma. Combined with previous works, it is proposed that the Gangjiang deposit could have resulted from the convective thinning of the lithospheric root, and the input of upper mantle components into the magma could have played a key role in the formation of the porphyry deposits in the Miocene Gangdese porphyry copper belt in the Tibetan Orogen.     

加强自然科学基金资助方向引导,推动陆地表层研究深化

着重阐述了近10年来,为推动陆地表层研究深入发展,国家自然科学基金在重点发展领域、重大研究计划、重大项目、申请代码及学科分类体系细化等层面对资助方向的引导作用。