花岗质熔体的结构特征与其产铀潜力

本文从花岗质熔体结构特征的角度,探讨了熔体成分与其产铀潜力之间的关系。分析了熔体中的K,Na对铀富集的控制作用,八面体、四面体空隙和晶体场效应,O/Si比值对铀活动性的影响。讨论了决定熔体粘度的一些因素,提出了熔体相对粘度值的计算方法,结合实例介绍了熔体相对粘度值的意义及地质应用。总结了有利于产铀的熔体结构特征标志。     

基于土壤理化性质估计土壤水分特征曲线Van Genuchten模型参数

在东北黑土区采集了不同侵蚀强度黑土土样,测定其土壤水分、机械组成、有机质和容重等指标,利用Rosetta模型估计了Van Genuchten模型的参数,并将估算土壤水分与实测土壤水分对比,评价了选择不同土壤理化性质指标的模拟精度,及该方法对东北黑土的适宜性。结果表明：选择4个或6个土壤性质指标,尺度参数（α）和形状参数（n）的差异较大,采用6指标时,α增大,n减小。修正VG模型参数m与n的关系后,模型拟合精度明显提高,其中6指标的计算结果好于4指标,但拟合值偏大,需进一步较正。Rosetta模型适用于砂粒含量小于46%,粘粒含量大于28%的东北黑土。     

Tracking a Severe Pollution Event in Beijing in December 2016 with the GRAPES–CUACE Adjoint Model

We traced the adjoint sensitivity of a severe pollution event in December 2016 in Beijing using the adjoint model of the GRAPES–CUACE (Global/Regional Assimilation and Prediction System coupled with the China Meteorological Administration Unified Atmospheric Chemistry Environmental Forecasting System). The key emission sources and periods affecting this severe pollution event are analyzed. For comaprison, we define 2000 Beijing Time 3 December 2016 as the objective time when PM_2.5 reached the maximum concentration in Beijing. It is found that the local hourly sensitivity coefficient amounts to a peak of 9.31 μg m^–3 just 1 h before the objective time, suggesting that PM_2.5 concentration responds rapidly to local emissions. The accumulated sensitivity coefficient in Beijing is large during the 20-h period prior to the objective time, showing that local emissions are the most important in this period. The accumulated contribution rates of emissions from Beijing, Tianjin, Hebei, and Shanxi are 34.2%, 3.0%, 49.4%, and 13.4%, respectively, in the 72-h period before the objective time. The evolution of hourly sensitivity coefficient shows that the main contribution from the Tianjin source occurs 1–26 h before the objective time and its peak hourly contribution is 0.59 μg m^–3 at 4 h before the objective time. The main contributions of the Hebei and Shanxi emission sources occur 1–54 and 14–53 h, respectively, before the objective time and their hourly sensitivity coefficients both show periodic fluctuations. The Hebei source shows three sensitivity coefficient peaks of 3.45, 4.27, and 0.71 μg m^–3 at 4, 16, and 38 h before the objective time, respectively. The sensitivity coefficient of the Shanxi source peaks twice, with values of 1.41 and 0.64 μg m^–3 at 24 and 45 h before the objective time, respectively. Overall, the adjoint model is effective in tracking the crucial sources and key periods of emissions for the severe pollution event.     

Changes in Extreme Maximum Temperature Events and Population Exposure in China under Global Warming Scenarios of 1.5 and 2.0°C: Analysis Using the Regional Climate Model COSMO-CLM

We used daily maximum temperature data (1986–2100) from the COSMO-CLM (COnsortium for Small-scale MOdeling in CLimate Mode) regional climate model and the population statistics for China in 2010 to determine the frequency, intensity, coverage, and population exposure of extreme maximum temperature events (EMTEs) with the intensity–area–duration method. Between 1986 and 2005 (reference period), the frequency, intensity, and coverage of EMTEs are 1330–1680 times yr^–1, 31.4–33.3°C, and 1.76–3.88 million km², respectively. The center of the most severe EMTEs is located in central China and 179.5–392.8 million people are exposed to EMTEs annually. Relative to 1986–2005, the frequency, intensity, and coverage of EMTEs increase by 1.13–6.84, 0.32–1.50, and 15.98%–30.68%, respectively, under 1.5°C warming; under 2.0°C warming, the increases are 1.73–12.48, 0.64–2.76, and 31.96%–50.00%, respectively. It is possible that both the intensity and coverage of future EMTEs could exceed the most severe EMTEs currently observed. Two new centers of EMTEs are projected to develop under 1.5°C warming, one in North China and the other in Southwest China. Under 2.0°C warming, a fourth EMTE center is projected to develop in Northwest China. Under 1.5 and 2.0°C warming, population exposure is projected to increase by 23.2%–39.2% and 26.6%–48%, respectively. From a regional perspective, population exposure is expected to increase most rapidly in Southwest China. A greater proportion of the population in North, Northeast, and Northwest China will be exposed to EMTEs under 2.0°C warming. The results show that a warming world will lead to increases in the intensity, frequency, and coverage of EMTEs. Warming of 2.0°C will lead to both more severe EMTEs and the exposure of more people to EMTEs. Given the probability of the increased occurrence of more severe EMTEs than in the past, it is vitally important to China that the global temperature increase is limited within 1.5°C.     

Strength of undisturbed and reconstituted frozen soil at temperatures close to 0 ℃

The strength of warm frozen soils in permafrost is fundamentally significant to estimate and predict the ground settlements from construction activities. A study was therefore initiated to assess the strength and its behaviors of undisturbed and reconstituted frozen soils at temperatures close to 0 ℃. A series of triaxial compression tests(TCT) were performed by using a developed testing apparatus and a matching specimen-preparation method. The confinement was applied from air pressure, the temperature in the specimen was maintained using two-end refrigeration, and multi-stage loading on a single specimen was adopted to determine the strength. The test results showed that the strength, both for the undisturbed and reconstituted frozen-soil specimens, was significantly dependent on the temperatures and independent of the applied confining pressures. Additionally, the strength of undisturbed frozen soils was about 1.6 times more than that for reconstituted frozen soils. These observations were closely associated with the structures existing between pore-ice and gravels with large diameters.     

东北地区气候变化CMIP5模式预估

利用CMIP5的多模式集合资料,从时间变化和空间分布两方面分析了不同情景下(RCP2.6、RCP4.5、RCP8.5)中国东北地区未来100年的气候变化。结果显示:3种排放情景下,21世纪东北地区气温和降水呈显著增长趋势,中期和末期增幅较明显,冬季增幅高于其他季节,RCP8.5情景下气温增暖最为显著,RCP4.5次之,RCP2.6最小,随着年代的推移,气温和降水年较差逐渐减小;空间分布显示:3种排放情景下各个时期的增温分布形式基本一致,由南向北逐渐增大,辽宁南部增温幅度最小,最显著地区位于黑龙江大兴安岭;不同情景下气温变化率的分布形势略有不同,但均呈显著增温趋势;3种排放情景下降水距平百分率均为增加趋势,呈由东向西逐渐增大的经向分布特征;不同情景下的降水变化率分布形势相似,呈南大北小特征,辽宁地区增长最为明显,黑龙江西部地区增长相对较小。     

Changes in temporal concentration property of summer precipitation in China during 1961–2010 based on a new index

Based on the property of entropy, a new index Q was defined to measure the temporal concentration property of summertime daily rainfall in China, based on daily precipitation data collected at 553 observation stations in China during 1961–2010. Furthermore, changes in the temporal concentration property of summer precipitation in China were investigated. The results indicate that the regions with larger Q values were located in most parts of Northwest China and the north of the Yellow River, where daily precipitation tended to become temporally concentrated during the study period. On the contrary, smaller Q values were found in eastern Tibetan Plateau, southeastern Northwest China, and most parts of Southwest and South China. The most obvious increasing trend of Q index was found in South China and most parts of Southwest China, where precipitation showed a temporal concentration trend. However, a decreasing trend of Q index was found in Northwest China, the Tibetan Plateau, and the north of the Huaihe River. Variations of the Q index and the summer rainfall total during 1961–2010 in China both exhibited an increasing trend, implying larger temporal variability in rainfall attributes. It is illustrated that the summer precipitation in general became more temporally concentrated with more intense rainfall events and wetter days.     

Study on anisotropy of Longmaxi shale using hydraulic fracturing experiment

Hydraulic fracturing reservoir reconstruction technology is crucial in the development of shale gas exploitation techniques.Large quantities of high-pressure fluids injected into shale reservoirs significantly alter compressional(P)and shear(S)wave velocities,rock mechanical parameters,and anisotropic characteristics.In this study,differentiated hydraulic fracturing petrophysical experiments were carried out on Longmaxi Formation shale under pseudo-triaxial stress loading conditions.The effects of stress loading methods,and water-rock physical and chemical reactions on P-and S-wave velocities and rock mechanical parameters were compared.The experimental results showed that isotropic stress loading may increase the P-and Swave velocities and Young’s modulus of dry shale kldnsample.Furthermore,it may lead to a weakening of the corresponding anisotropy.In contrast,differential stress loading was able to improve the anisotropy of Young’s modulus and accelerate the decrease in the compressive strength of shale in the vertical bedding direction.The water-rock physical and chemical reactions prompted by hydraulic fracturing was found to"soften"shale samples and reduce Young’s modulus.The influence of this"soften"effect on the compressional and shear wave velocities of shale was negligible,whilst there was a significant decrease in the anisotropy characteristics of Thomsen parameters,Young’s modulus,and Poisson’s ratio.The negative linear relationship between the Poisson’s ratios of the shale samples was also observed to lose sensitivity to stress loading,as a result of the"soften"effect of fracturing fluid on shale.The results of this study provide a reliable reference point and data support for future research on the mechanical properties of Longmaxi shale rocks.     

S‐Doped Magnetic Mesoporous Carbon for Efficient Adsorption of Methyl Orange from Aqueous Solution

A simple and rapid soft‐templating coupled with one‐pot solvent thermal method is developed to synthesize S‐doped magnetic mesoporous carbon (S‐doped MMC). In this method, phenolic resin is used as a carbon precursor and Pluronic copolymer P123 is used as a template and 2,5‐dimercapto‐1,3,4‐thiadiazole is used as sulfur source. Prepared S‐doped MMC processes a high specific surface area, the Fe₃O₄ particles are well embedded in the mesoporous carbon walls that exhibit a strong magnetic response, and the hydrated iron nitrate loading amount of 0.808 g is the best. Batch adsorption experiments are carried out at different pH, initial concentration, temperature, and contact time on the adsorption of methyl orange (MO) by S‐doped MMC. The kinetic data of the adsorption process are better fitted with pseudo‐second‐order model than the pseudo‐first‐order model. Langmuir model is more suitable for the equilibrium data than Freundlich model. The thermodynamic parameters including ΔG⁰, ΔH⁰, and ΔS⁰ indicate that the adsorption is a feasible, spontaneous, and endothermic process. Finally, it is found that the coexistence of PO₄^3?, NO₃^?, SO₄^2?, Cl^?, and CO₃^2? does not influence the adsorption process. These results illustrate S‐doped MMC can be an efficient adsorbent for the removal of MO from wastewater.     

基于机器学习的时间反转散射体检测方法

地下小尺度散射体的检测和识别对于提高地震勘探的分辨率具有重要意义,目前业界普遍采用绕射波分离及成像方法检测地下散射体,而绕射波成像的质量主要取决于绕射波和反射波波场分离的程度.本文将被动源震源定位问题中常用的时间反转原理引入到地下散射体检测中,首先通过分析被动源和主动源模型反传波场的聚焦状态,验证了时间反转原理应用于地下散射体检测中的可行性;并引入机器学习中的朴素贝叶斯分类算法,给出适用于时间反转散射体检测的分类算法框架,计算模型中每个点成为散射体的概率,最终检测出地下散射体最有可能存在的位置.散射体模型和Sigsbee2a模型的试算结果证实了本文方法在不需对反射波和绕射波分离的情况下,即可实现对地下散射体的检测和定位,同时由于考虑了多次散射的影响,检测结果能准确反映地下散射体的位置.