东天山双龙铜矿石英闪长岩锆石U-Pb定年、Hf同位素分析及对构造环境的制约

通过对新疆东天山雅满苏岛弧带双龙铜矿成岩地质特征、岩石地球化学特征及Hf同位素分析,认为赋矿岩体为一套形成于后碰撞环境下的准铝质高钾钙碱性岩石系列的石英闪长岩,LA-ICP-MS锆石U-Pb同位素年龄为(300.9±1.2)Ma。岩石地球化学显示,赋矿岩石具富集大离子亲石元素(LILE)K,Rb等及高场强元素(HFSE)Th,U,Zr和Hf,贫Nb,Ta,Ti,Sr,P特征,可能形成于后碰撞构造环境。石英闪长岩锆石176Hf/177Hf变化范围0.282949~0.283002,平均值0.282979,εHf(t)值为12.32~14.40,平均13.40,tDM2(Hf)为375~482Ma,平均429Ma,表明岩浆物源可能来自志留纪新生地壳的部分熔融。     

Geological and geochemical characteristics of the Baogudi Carlin-type gold district (Southwest Guizhou,China) and their geological implications

The newly discovered Baogudi gold district is located in the southwestern Guizhou Province, China, where there are numerous Carlin-type gold deposits. To better understand the geological and geochemical characteristics of the Baogudi gold district, we carried out petrographic observations, elemental analyses, and fluid inclusion and isotopic composition studies. We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou. Three mineralization stages, namely, the sedimentation diagenesis, hydrothermal (main-ore and late-ore substages), and supergene stages, were identified based on field and petrographic observations. The main-ore and late-ore stages correspond to Au and Sb mineralization, respectively, which are similar to typical Carlin-type mineralization. The mass transfer associated with alteration and mineralization shows that a significant amount of Au, As, Sb, Hg, Tl, Mo, and S were added to mineralized rocks during the main-ore stage. Remarkably, arsenic, Sb, and S were added to the mineralized rocks during the late-ore stage. Element migration indicates that the sulfidation process was responsible for ore formation. Four types of fluid inclusions were identified in ore-related quartz and fluorite. The main-ore stage fluids are characterized by an H₂O–NaCl–CO₂–CH₄ ± N₂ system, with medium to low temperatures (180–260 °C) and low salinity (0–9.08% NaCl equivalent). The late-ore stage fluids featured H₂O–NaCl ± CO₂ ± CH₄, with low temperature (120–200 °C) and low salinity (0–7.48% NaCl equivalent). The temperature, salinity, and CO₂ and CH₄ concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage. The calculated δ¹³C, δD, and δ¹⁸O values of the ore-forming fluids range from − 14.3 to − 7.0‰, −76 to −55.7‰, and 4.5–15.0‰, respectively. Late-ore-stage stibnite had δ³⁴S values ranging from − 0.6 to 1.9‰. These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids, with minor contributions from strata. Collectively, the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou. It is likely that the Baogudi gold district, together with other Carlin-type gold deposits in southwestern Guizhou, was formed in response to a single widespread metallogenic event.

     

商末气候变化对于稻作农业的影响——基于济南大辛庄、刘家庄遗址商代植物遗存观察

气候变化影响着农作物的生长。文章通过对比济南大辛庄遗址中、晚商时期的植物遗存和济南刘家庄遗址商末周初的植物遗存,发现两个遗址主要农作物均包括粟(Setaria italica (L.)Beauv.)、黍(Panicum miliaceum L.)、大豆(Glycine max(L.)Merr.)和小麦(Ttiticum aestivum L.),大辛庄遗址水稻(Oryza sativa L.)绝对数量较多,但刘家庄遗址未发现水稻。综合本地区其他遗址的植物考古研究结果,可以发现山东地区岳石文化时期、商代水稻仍是主要粮食作物之一,但到商末周初水稻数量急剧减少。同时,邻近的中原地区和关中地区,多处商周时期遗址水稻种植也普遍出现萎缩。多项地质记录表明,商末(3000 a B.P.前后)东亚夏季风快速减弱,降水量显著下降。山东地区受东亚季风影响,这一时期降水量减少,难以保证稻作农业所需的持续充足的水源,从而影响到水稻产量和种植规模。因此,商末气候变化很可能是刘家庄遗址商末周初水稻缺失以及山东地区商末周初水稻数量骤降的主要原因之一,也同时影响到整个黄河中下游这一时期的稻作农业。     

临夏黄土记录的26万年来季风快速变化

黄土高原西部高分辨率黄土序列开展的多代用指标研究,有助于揭示轨道-亚轨道尺度上东亚冬、夏季风的变化特征及动力机制。但针对同一地质记录提取冬、夏季风多代用指标进行对比和敏感性分析的工作尚不多见,因此制约了对季风快速变化特征和机理的理解。本文利用甘肃临夏85 m黄土岩芯开展高分辨率的粒度、磁化率和元素扫描分析,发现在轨道尺度上粒度和Zr/Rb比值显示的大幅冰期-间冰期波动与深海氧同位素记录有很好的对应关系,表明东亚冬季风的波动响应于北半球高纬冰量的变化。但在千年尺度上,粒度能更敏感地响应冬季风的快速变化;Rb/Sr比值和磁化率均能很好记录轨道尺度上的东亚夏季风波动,但在亚轨道尺度上Rb/Sr的敏感性明显高于磁化率。粒度、Zr/Rb和Rb/Sr所指示的东亚季风快速变化表现出较强的岁差信号,与石笋和北纬65°夏季太阳辐射有较好的对应关系,表明东亚季风变化也受到岁差直接驱动的夏季太阳辐射变的控制。在最后两个冰期-间冰期旋回中(即末期冰期旋回和倒数第二次冰期旋回)Rb/Sr及Zr/Rb比值和粒度记录分别可以辨别出与石笋相同数量级的变暖事件,但粒度记录的暖事件明显要多于Rb/Sr及Zr/Rb比值,且这些暖事件并不能一一对应。粒度及元素比值记录显著变冷的千年尺度的Heinrich(H)事件与石笋记录的夏季风明显减弱的事件有很好的对应关系,但其发生频率明显高于海洋记录。这些指标记录的千年尺度上波动信号的不一致性主要归因指标对不同气候要素敏感性的差异。未来需要进一步开展高分辨率多代用指标敏感性分析,选取对季风快速变化的敏感指标,有助于我们理解季风快速变化的特征(如周期和幅度等)和分析季风快速变化的时空差异性。     

Research on Initial Modeling Method for TTI Anisotropic Parameters Based on Local Tomography

The initial modeling method based on TTI anisotropy can provide an initial model for the fine modeling of tomographic inversion, and the quality of the initial model directly affects the efficiency and accuracy of tomographic inversion. It is necessary to study the accurate initial modeling method of TTI anisotropy. Based on the conventional flow of the initial modeling method of TTI anisotropic, in this paper the anisotropic parameter extraction formula was perfected, a local tomography method to optimize the flow of the initial modeling method of TTI anisotropy was introduced, and the accuracy of the initial model was further improved, which is more consistent with the actual geological conditions and conducive to the fine modeling of the later tomographic inversion. The processing results of model and filed data show that the initial modeling method of TTI anisotropy based on local tomography is effective and practical.     

黄骅坳陷新生界火成岩岩相与储集性能分析

通过取芯段火成岩岩芯观察、测井以及地震相分析,将黄骅坳陷新生界火山岩划分为爆发相、溢流相、火山通道相和火山沉积相4种,并根据储集空间特征进一步划分为10种亚相,将侵入岩划分为3个相带。在此基础上建立黄骅坳陷火成岩岩相模式,并分析不同岩相火成岩的储集性能。研究认为：研究区溢流相上下区亚相和爆发相储集物性优越,构造裂缝和原生气孔发育,气孔、溶蚀孔缝、构造缝为主要储集空间;侵入相和次火山岩相火成岩由于热液作用造成围岩发生变质,原岩结构构造发生变化,使原来孔渗条件极差的泥岩变质为具有一定储集性能的储集岩;主要储集空间为收缩裂隙和构造裂隙。     

长春地区白垩系地层地铁勘察参数的确定

白垩系砾岩及泥岩地层在长春地区普遍存在,但由于砾岩地层现场钻探难以取样进行室内土工试验,泥岩地层由于存在水稳性、膨胀性、崩解性等因素影响,砾岩和泥岩的承载力值、抗剪强度参数指标、渗透系数以及基床系数等参数多以经验数据评估方法为主,在合理准确确定相关参数的问题上存在较大分歧。通过对长春地区白垩系砾岩及泥岩进行原位平板载荷试验、浸水载荷试验以及现场原位剪切试验,获取砾岩、泥岩的承载力值、抗剪强度指标、渗透系数以及现场基床系数值等,为地铁建设工程地质问题分析及设计提供充足的地质依据。     

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.     

北京西山地区下苇甸剖面寒武系张夏组鲕粒硅化成因探讨

鲕粒作为碳酸盐岩中非常重要的指相颗粒,其研究主要集中在成因上面,而成岩作用研究较少。北京西山地区下苇甸剖面寒武系张夏组发育大套鲕粒灰岩,通过对该剖面野外实测、薄片观察、XRD测试等手段,结合有机碳、热解等地化参数,对鲕粒的硅化机制及其硅质来源做了系统的研究。结果表明,鲕粒溶蚀再沉淀或者新生变形作用造成鲕粒边缘有机质富集,有机质演化释放的有机酸是硅质沉淀的主要因素,硅质来源主要为陆源输入和黏土矿物的转化。由于有机质主要富集在鲕粒边缘,形成有机质膜,从而造成硅质的沉淀主要沿鲕粒边缘发生,形成鲕粒边缘特有的硅化套,这种结果也从侧面反映了微生物在原始鲕粒形成中发挥了重要作用。