Size-Resolved Aerosol Characterization for a Polluted Episode at the IfT Research Station Melpitz in Autumn 1997

Inorganic ions, organic carbon (OC), elemental carbon (EC) and a variety of organic single species in airborne particles have been determined at the research station of the Leibniz – Institut für Troposphärenforschung (IfT) in Melpitz (Germany) in autumn 1997.Samples of eight selected measurement events were divided in two groups in order to investigate differences in the chemical composition of particles originating from southwesterly (SW – developed EU countries) or from easterly directions (E – less developed eastern countries). Differences between these two groups were tested statistically by Student's t-test.Five stage cascade impactor samples show nitrate as most abundant in the accumulation mode in the SW group. EC and sulphate show the most abundant mass fractions in the E group. That can be considered as a consequence of domestic coal heating and coal-fired power plant emissions in the region of westerly Poland, northern Czech Republic and easterly Germany. Higher nitrate concentrations in the SW group can be explained by stronger NO _x emissions caused by the leeward plume of the conurbation of Leipzig, as well as by the still higher traffic density in western Germany.The methane sulphonic acid (MSA) mass fraction was higher for SW air masses in accumulation mode particles, probably indicating marine origin. Succinic acid also showed higher mass fractions for the SW group. This could be caused by primary emission in automobile exhaust gases and photochemical formation during transport from SW. Indeed, during SW sampling, solar radiation intensity was higher than during E sampling.The observed differences in the particle composition are an expression of the still existing technology gradient in Europe. Future campaigns could show the development to a joint economy with smaller differences in anthropogenic emissions.     

Development of a chemistry module for GCMs: first results of a multiannual integration

The comprehensive chemistry module CHEM has been developed for application in general circulation models (GCMs) describing tropospheric and stratospheric chemistry, including photochemical reactions and heterogeneous reactions on sulphate aerosols and polar stratospheric clouds. It has been coupled to the spectral atmospheric GCM ECHAM3. The model configuration used in the current study has been run in an –off-line mode, i.e. the calculated chemical species do not affect the radiative forcing of the dynamic fields. First results of a 15-year model integration indicate that the model ECHAM3/CHEM runs are numerically efficient and stable, i.e. that no model drift can be detected in dynamic and chemical parameters. The model reproduces the main features regarding ozone, in particular intra- and interannual variability. The ozone columns are somewhat higher than observed (approximately 10%), while the amplitude of the annual cycle is in agreement with observations. A comparison with HALOE data reveals, however, a serious model deficiency regarding lower-stratosphere dynamics at high latitudes. Contrary to what is concluded by observations, the lower stratosphere is characterized by slight upward motions in the polar regions, so that some of the mentioned good agreements must be considered as fortuitous. Nevertheless, ECHAM3/CHEM well describes the chemical processes leading to ozone reduction. It has been shown that the mean fraction of the northern hemisphere, which is covered by polar stratospheric clouds (PSCs) as well as the temporal appearance of PSCs in the model, is in fair agreement with observations. The model results show an activation of chlorine inside the polar vortex which is stronger in the southern than in the northern winter hemisphere, yielding an ozone hole over the Antarctic; this hole, however, is also caused to a substantial degree by the dynamics. Interhemispheric differences concerning reformation of chlorine reservoir species HCl and ClONO₂ in spring have also been well reproduced by the model.     

A Fully Depleted pn-Junction CCD for Infrared-, UV- and X- ray detection

This paper describes the performance of the Fully Depleted pn-junction CCD (pn-CCD) system, developed for ESA's XMM-satellite mission for soft x-ray imaging and spectroscopy in the single photon counting mode in the 100 eV to 10 keV photon range. The 58 mm x 60 mm large pn-CCD array, designed and fabricated at the Semiconductor Lab (Halbleiterlabor) of the Max-Planck-Institut, uses pn-junctions for registers and as backside structure. This concept naturally enables full depletion of the detector volume independent of the silicon wafer's resistivity and thickness, and as such make it an efficient detector for the x-ray region and the infrared. For high detection efficiency in the soft x-ray region and UV, an ultrathin pn-CCD backside deadlayer has been realized. Each pn-CCD-channel is equipped with its own on-chip JFET amplifier which, in combination with the CAMEX-amplifier and multiplexing chip, facilitates parallel readout and fast data rate: the cooled pn-CCD system can be read out at a data rate up to 3 MHz with an electronic noise floor of ENC < 5 e-.     

Nutrients limiting the algal growth potential (AGP) in the Po River plume and an adjacent area, Northwest Adriatic Sea: Enrichment bioassays with the test algaeNitzschia closterium andThalassiosira pseudonana

From April 1993 to March 1994, 135 samples were collected at two sites in the coastal Adriatic Sea, both near (14.5 km) and far (63 km) from the Po River delta. The nutrient(s) limiting algal growth potential (AGP) were estimated by bioassay usingNitzshia closterium (local isolate) andThalassiosira pseudonama (strain 3-H). Estimates were also made by comparing the nutrient molar ratios, ΣN:P and ΣN:Si (whereΣN=NO₃ ^?+NO₂ ^?+NH₄ ⁺+urea), to the Redfield Ratio (16∶1, 1∶1). According to the bioassay results, phosphorus was the sole nutrient limiting AGP in 2% of the samples and was the most limiting nutrient in 69% of the samples; nitrogen was sole limiting nutrient in 18% of the samples. In 11% of samples, nitrogen and phosphorus were equally co-limiting. Omission of phosphorus from spike enrichments allowed, on average, only a 1.6-fold increase in biomass over that in the unenriched controls. Similar omission of nitrogen allowed a 4-fold increase, while silicon, iron, and micronutrients resulted in 14-fold, 18-fold, and >20-fold increases, respectively. In most of the samples, ΣN:P was much greater than 16, indicating a marked phosphorus deficiency, while ΣN:Si values suggested that silicon was the third most limiting nutrient in 35% of samples. In water collected for from the Po delta, the yield ofN. closterium was not limited by any nutrients other than the three major ones: P, N and Si. In these same waters,T. pseudonana was also potentially limited by iron and, to a lesser extent, by vitamins. The role of iron varied. In samples collected near the Po delta, iron acted as the third most limiting nutrient forN. closterium in June and September; it appeared 29 times out of 78 on the list of potentially limiting nutrients forT. pseudonana, including 5 times as the most limiting. Altogether, comparison with published results suggests that the roles of iron and silicon in AGP limitation have increased during the past three decades, and could become even more important if eutrophication in the Adriatic Sea continues to increase.     

Boundary-layer modification in wintertime cold-air outbreaks from the Arctic sea ice

During the field experiment ARKTIS 1993 ten cases of boundary-layer modification in wintertime cold-air outbreaks from the Arctic sea ice in the Spitsbergen region were observed by aircraft over a distance ranging from about 50 km over the ice to about 300 km over the water. The modification depends decisively on the initial conditions over the ice, the boundary conditions at the bottom and top of the boundary layer and on the conditions of the large-scale flow. The modification of the bulk boundary-layer characteristics in relation to these conditions is presented.Besides the air-sea temperature contrast, the most important role for the boundary-layer modification is played by the stability on top of the boundary layer and by the divergence of the large-scale flow. According to the high variability of these conditions the observed boundary-layer modifications were very variable ranging from 100 to 300 m thick boundary layers with air temperatures between -32 and -22 °C over the ice to thicknesses between 900 and 2200 m and air temperatures between -15 and -5 °C after 300 km fetch over the open water. In most cases the large-scale flow was anticyclonic and divergent over the ice and changed to cyclonic and convergent over the water and an ice-sea breeze was superimposed on it.The sensible and latent heat fluxes are the dominant terms in the surface energy budget over the open water and ranged between 200 and 700 W m^-2 whereas the net longwave radiation is the dominating term over the ice with the heat fluxes only about 10 W m^-2.     

Geoscience for environmental planning in Lithuania

While consideration of natural environment factors increased in the late eighties, from the very beginning geoscience was outside the planning process. It was a consequence of the state of applied geology in Lithuania. During this time the development of certain industrial projects was stopped; urgent environment protection measures came into use; it was recognised that nonrational utilization depleted resources.     

Insight into variability of spring and flash flood events in Lithuania

In this research, variability of spring (from 1 March to 30 May) and flash (from 1 June to 30 November) floods in rivers of different regions was analysed. The territory of Lithuania is divided into three regions according to hydrological regime of the rivers: Western, Central, and Southeastern. The maximum river discharge data of spring and flash floods [a total of 31 water gauging stations (WGS)] were analysed. Comparison of the data of four periods (1922–2013, 1941–2013, 1961–2013, and 1991–2013) with the data of the reference period (1961–1990) was performed. Analysis included the longest discharge data set of the Nemunas River at Smalininkai WGS (1812–2013) as well. Mixed patterns of flood changes in Lithuanian rivers were detected. The analysis of flood discharges of the Nemunas River indicated that both spring and flash floods in Lithuania were getting smaller.     

Spatial–temporal analysis of the shoreline change rate using automatic computation and geospatial tools along the Tetouan coast in Morocco

Natural Hazards - Analyzing and understanding coastline variability and dynamics are important for scientists and policy-makers. This study investigates the long-term process of shoreline change...     

Meteorological singularities in the Czech Republic in the period 1961–2002

Summary Based on the mean daily values of air temperature, air pressure, and precipitation totals at 13 climatological stations within the territory of the Czech Republic in the period 1961–2002, a statistical analysis of “meteorological singularities” (i.e., calendar-dependent deviations from the mean annual variation for selected meteorological elements) was performed. At the 13 stations analysed, a total of 45 meteorological singularities (37 singularities in air temperature, 35 in air pressure, and 30 in precipitation) were found. The singularities detected correlate well with cases traditionally recognised in the Czech Republic as well as with the results of analyses performed for Germany. Despite the considerable variability of singularities in time and space, most of them are found across the entire territory of the Czech Republic and can be observed for the most part in all three elements processed. The majority of the singularities detected may be explained on the basis of circulation mechanisms, by relating them to a significantly higher occurrence of certain groups of synoptic situations characterised by anomalous temperature or precipitation effects. Cases of “competition” between singularities, when different singularities may occur on the same calendar day, were found.     

ENSO influence on Europe during the last centuries

El Niño/Southern Oscillation (ENSO) affects climate not only in the Pacific region and the tropics, but also in the North Atlantic-European area. Studies based on twentieth-century data have found that El Niño events tend to be accompanied in late winter by a negative North Atlantic Oscillation index, low temperatures in northeastern Europe and a change in precipitation patterns. However, many questions are open, for example, concerning the stationarity of this relation. Here we study the relation between ENSO and European climate during the past 500 years based on statistically reconstructed ENSO indices, early instrumental station series, and reconstructed fields of surface air temperature, sea-level pressure, precipitation, and 500 hPa geopotential height. After removing years following tropical volcanic eruptions (which systematically mask the ENSO signal), we find a consistent and statistically significant ENSO signal in late winter and spring. The responses to El Niño and La Niña are close to symmetric. In agreement with studies using twentieth-century data only, the ENSO signal in precipitation is different in fall than in late winter. Moving correlation analyses confirm a stationary relationship between ENSO and late winter climate in Europe during the past 300 years. However, the ENSO signal is modulated significantly by the North Pacific climate. A multi-field cluster analysis for strong ENSO events during the past 300 years yields a dominant pair of clusters that is symmetric and represents the ‘classical’ ENSO effects on Europe.