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51.
Geochemistry and mineralogy of shallow alluvial aquifers in Daudkandi upazila in the Meghna flood plain, Bangladesh 总被引:1,自引:0,他引:1
M. Aziz Hasan Mattias von Br?mssen Prosun Bhattacharya Kazi Matin Ahmed Arif Mohiuddin Sikder Gunnar Jacks Ondra Sracek 《Environmental Geology》2009,57(3):499-511
The shallow alluvial aquifers of the delta plains and flood plains of Bangladesh, comprises about 70% of total land area are
mostly affected by elevated concentrations of arsenic (As) in groundwater exposing a population of more than 35 million to
As toxicity. Geochemical studies of shallow alluvial aquifer in the Meghna flood plain show that the uppermost yellowish grey
sediment is low in As (1.03 mg/kg) compared to the lower dark grey to black sediment (5.24 mg/kg) rich in mica and organic
matter. Sequential extraction data show that solid phase As bound to poorly crystalline and amorphous metal (Fe, Mn, Al)-oxyhydroxides
is dominant in the grey to dark grey sediment and reaches its maximum level (3.05 mg/kg) in the mica rich layers. Amount of
As bound to sulphides and organic matter also peaks in the dark grey to black sediment. Vertical distributions of major elements
determined by X-ray fluorescence (XRF) show that iron (Fe2O3), aluminum (Al2O3) and manganese (MnO) follow the general trend of distribution of As in the sediments. Concentrations of As, Mn, Fe, HCO3
−, SO4
2− and NO3
− in groundwater reflect the redox status of the aquifer and are consistent with solid phase geochemistry. Mineralogical analysis
by X-ray diffraction (XRD) and scanning electron microscopy (SEM) fitted with energy dispersive X-ray spectrometer (EDS) revealed
dominance of crystalline iron oxides and hydroxides like magnetite, hematite and goethite in the oxidised yellowish grey sediment.
Amorphous Fe-oxyhydroxides identified as grain coating in the mica and organic matter rich sediment suggests weathering of
biotite is playing a critical role as the source of Fe(III)-oxyhydroxides which in turn act as sink for As. Presence of authigenic
pyrite in the dark grey sediment indicates active reduction in the aquifer. 相似文献
52.
Inga Golbeck Xin Li Frank Janssen Thorger Brüning Jacob W. Nielsen Vibeke Huess Johan Söderkvist Bjarne Büchmann Simo-Matti Siiriä Olga Vähä-Piikkiö Bruce Hackett Nils M. Kristensen Harald Engedahl Ed Blockley Alistair Sellar Priidik Lagemaa Jose Ozer Sebastien Legrand Patrik Ljungemyr Lars Axell 《Ocean Dynamics》2015,65(12):1603-1631
53.
54.
Preparing a seismic hazard model for Switzerland: the view from PEGASOS Expert Group 3 (EG1c) 总被引:1,自引:0,他引:1
The seismic hazard model used in the PEGASOS project for assessing earth-quake hazard at four NPP sites was a composite of four sub-models, each produced by a team of three experts. In this paper, one of these models is described in detail by the authors. A criticism sometimes levelled at probabilistic seismic hazard studies is that the process by which seismic source zones are arrived at is obscure, subjective and inconsistent. Here, we attempt to recount the stages by which the model evolved, and the decisions made along the way. In particular, a macro-to-micro approach was used, in which three main stages can be described. The first was the characterisation of the overall kinematic model, the “big picture” of regional seismogenesis. Secondly, this was refined to a more detailed seismotectonic model. Lastly, this was used as the basis of individual sources, for which parameters can be assessed. Some basic questions had also to be answered about aspects of the approach to modelling to be used: for instance, is spatial smoothing an appropriate tool to apply? Should individual fault sources be modelled in an intraplate environment? Also, the extent to which alternative modelling decisions should be expressed in a logic tree structure has to be considered. 相似文献
55.
R. Brázdil L. Řezníčková H. Valášek M. Havlíček P. Dobrovolný E. Soukalová 《水文科学杂志》2013,58(3):468-485
Abstract Floods from the middle part of the River Morava (eastern Czech Republic) are considered over the course of the past three centuries, the study being based on data derived from documentary evidence (1691–1880), measured peak water stages, Hk (1881–1920) and peak discharges, Qk (1916–2009), evaluated with respect to their N-year return period (HN and QN ). Changes in land use and water management (water reservoirs, channel modifications) are discussed, as are factors influencing runoff conditions in the Morava catchment. Decadal synthesis of flood series identifies the highest flood activity in the decades of 1911–1920 and 1961–1970 (11 floods each), 1831–1840, 1891–1900, 1901–1910 and 1931–1940 (10 floods each). Uncertainty in this series is related to some incompleteness of documentary data in the pre-1881 period. Very low flood frequency occurred in the 1990s–2000s, although the most disastrous floods were recorded in this particular period (July 1997 at Q 100 and March/April 2006 at Q 20–Q 50). Changes in flood frequency correspond partly to long-term changes in temperature and precipitation patterns. Citation Brázdil, R., ?ezní?ková, L., Valá?ek, H., Havlí?ek, M., Dobrovolný, P., Soukalová, E., ?ehánek, T. & Skokanová, H. (2011) Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors. Hydrol. Sci. J. 56(3), 468–485. 相似文献
56.
T. Gnauk K. Müller E. Brüggemann W. Birmili K. Weinhold D. van Pinxteren G. Löschau G. Spindler H. Herrmann 《Journal of Atmospheric Chemistry》2011,68(3):199-231
The fractions of local traffic (LT), urban background (UBG) and regional background (RBG) of the particle pollution at a traffic-influenced
kerbside in Dresden, Germany, were determined by measurements of size-segregated mass concentration, chemical composition
and particle size distributions in a network of five measurement stations partly existing and partly set up for this study.
Besides the kerbside station, one urban background site and three rural sites were included in the study. Using data from
these different sites, the LT, UBG, and RBG contributions were calculated, following the approach of Lenschow et al. (2001). At the kerbside site, 19% of the total number concentration (DpSt = 10–600 nm) could be attributed to the RBG, 15% to the UBG, and 66% to the LT immediately nearby. Particle mass concentrations
up to Dpaer = 420 nm RBG amounts to 68%, UBG to 21%, and LT only to 11%. Highest mass concentrations were observed at all stations in
autumn and winter during easterly inflow directions. The local traffic fraction of PM10 mass at the kerbside station was found to be 30% for westerly inflow, but only 7% for southeasterly inflow due to the dominating
transport fraction from up to 80% of the particle mass at this inflow direction. Size-resolved investigation showed the main
fractions in both the particle size ranges of Dpaer = 0.42 to 1.2 and 0.14 to 0.42 μm at all stations. The main components sulphate, ammonium and total carbon showed higher
concentrations at south-eastern/eastern inflow in autumn at all stations, while nitrate at the kerbside and urban background
site was higher during westerly inflow in winter. The chemical composition at the regional background site at westerly inflow
(12% nitrate, 8% sulphate, 11% total carbon) was significantly different from that at easterly inflow (3% nitrate, 15% sulphate,
22% total carbon). The prevailing part of the ionic mass was always found in the fine particle range of Dpaer = 0.14 to 1.2 μm at all stations. For all inflow directions highest total carbon concentrations were observed at the kerbside
station, especially in the ultra-fine size range of Dpaer = 0.05 to 0.14 μm with up to 30% of the whole carbon. PAH concentrations were always higher at south-eastern/eastern inflow
especially during wintertime. Trace metal components and silicon were found mainly in the coarse mode fraction at the kerbside
resulting from abrasion or resuspension. 相似文献
57.
Artificial light at night: implications for early life stages development in four temperate freshwater fish species 总被引:1,自引:0,他引:1
Anika Brüning Franz Hölker Christian Wolter 《Aquatic Sciences - Research Across Boundaries》2011,73(1):143-152
Flora and fauna have both evolved under a natural cycle of light and dark. But especially in urban areas, the night is now
increasingly disturbed by artificial light. Many traits and behaviours in fish are triggered by a circadian clock, for example
hatching and swim bladder inflation, which predominantly take place at dusk or night. As lighting becomes brighter and extends
farther into rural areas, the distinction between day and night becomes increasingly blurred. Therefore, the loss of diurnal
trigger by artificial light at night was hypothesized having deleterious effects on these traits and impact fish reproduction.
To assess these effects, eggs of four native freshwater fishes, Eurasian perch Perca fluviatilis, roach Rutilus rutilus, bleak Alburnus alburnus and chub Leuciscus cephalus, were incubated under two different light conditions: a photoperiod of 14 h light:10 h darkness (LD) and continuous illumination
(LL). The time to hatch and swim bladder inflation was recorded. The species showed inconsistent reactions to the light treatments.
In roach and bleak, the time to 50% hatch was longer in LL, whereas continuous lighting had an accelerating effect in chub.
Incubation in LL elongated the hatching period in perch and roach and, in perch, the onset of darkness seemed to trigger hatching.
The swim bladder inflation was significantly promoted by continuous light in chub and bleak but was not affected in roach.
In conclusion, nocturnal artificial illumination could have an effect on hatching and initial swim bladder filling by masking
the day–night-change and thereby diminish the trigger effect. However, the reactions were species specific and the increase
in variation indicated a lack of diurnal triggering, whilst a general deleterious effect of artificial light at night has
not been identified on early life stages. 相似文献
58.
Chunming Shi Valérie Masson-Delmotte Camille Risi Thomas Eglin Michel Stievenard Monique Pierre Xiaochun Wang Jing Gao François-Marie Bréon Qi-Bin Zhang Valérie Daux 《Earth and Planetary Science Letters》2011,301(1-2):307-316
We explore the potential of tree-ring cellulose δ18O and δ13C records for reconstructing climate variability in the southeast Tibetan Plateau. Our sampling strategy was designed to investigate intra and inter-tree variability, and the effects of the age of tree on δ18O variation. We show that intra-tree δ13C and δ18O variability is negligible, and inter-tree coherence is sufficient to build robust tree-ring δ18O or δ13C chronologies based on only four trees. There is no evidence of an age effect regarding δ18O, in contrast with tree-ring width. In our warm and moist sampling site, young tree δ13C is not clearly correlated with monthly mean meteorological data. Tree-ring δ18O appears significantly anti-correlated with summer precipitation amount, regional cloud cover, and relative humidity. Simulations conducted with the ORCHIDEE land surface model confirm the observed contribution of relative humidity to tree cellulose δ18O, and explain the weak correlation of δ13C with climate by the non-linear integration linked with photosynthesis. Altogether, the tree-ring cellulose δ18O is shown to be a promising proxy to reconstruct regional summer moisture variability prior to the instrumental period. 相似文献
59.
J. Krause G. E. Brügmann E. V. Pushkarev 《Contributions to Mineralogy and Petrology》2011,161(2):255-273
Uralian-Alaskan-type mafic–ultramafic complexes are recognized as a distinct class of intrusions regarding lithologic assemblage,
mineral chemistry and petrogenetic setting. In the present study, we discuss new data on the distribution of major elements
in minerals of the spinel group in rocks from Uralian-Alaskan-type complexes in the Ural Mountains, Russia. Cr-rich spinel
(Cr2O3 = 20–53 wt%) in dunite with interstitial clinopyroxene and in wehrlite cumulates indicate that it reacted with interstitial
liquid resulting in the progressive substitution of Al2O2 and Cr2O3 by Fe2O3 and TiO2. A distinct change in the spinel chemistry in dunite (Cr2O3 = 47–53 wt%), towards Al2O3- and Cr2O3-poor but Fe2O3-rich compositions monitors the onset of clinopyroxene fractionation in wehrlite (Cr2O3 = 15–35 wt%, Al2O3 = 1–8 wt%, Fe2O3 = 25–55 wt%). In more fractionated mafic rocks, the calculated initial composition of exsolved spinel traces the sustained
crystallization of clinopyroxene by decreasing Cr2O3 and increasing FeO, Fe2O3 and fO2. Finally, the initiation of feldspar crystallization buffers the Al2O3 content in most of the spinels in mafic rocks at very low Cr2O3 contents (<5 wt%). The fractionation path all along and the reaction with interstitial liquid are accompanied by increasing
Fe2O3 contents in the spinel. This likely is caused by a significant increase in the oxygen fugacity, which suggests closed system
fractionation processes. Spinel with Cr2O3 < 27 wt% is exsolved into a Fe2O3-rich and an Al2O3-rich phase forming a variety of textures. Remarkably, exsolved spinel in different lithologies from complexes 200 km apart
follows one distinct solvus line defining a temperature of ca. 600°C. This indicates that the parental magmas were emplaced
and eventually cooled at similar levels in the lithosphere, likely near the crust–mantle boundary. Eventually, these 600°C
hot bodies were rapidly transported into colder regions of the upper crust during a regional tectonic event, probably during
the major active phase of the Main Uralian Fault. 相似文献
60.
Rainfall-induced landslide event of May 2010 in the eastern part of the Czech Republic 总被引:3,自引:2,他引:1
Tom��? P��nek Rudolf Br��zdil Jan Klime? Veronika Smolkov�� Jan Hradecky Pavel Zahradn��?ek 《Landslides》2011,8(4):507-516
More than 150 landslides originated in the eastern part of the Czech Republic (region of the Flysch Outer Western Carpathians—hereinafter,
OWC) due to soil saturation caused by antecedent precipitation and long lasting and intensive rainfalls on 16–18 May 2010
(>300 mm as measured by some stations). As a consequence, a multitude of small failures originated 88% of which was smaller
than 104 m2. Most landslides are characterised as shallow (<10 m) or middle–deep (10–30 m) incipient (rather short travel) landslides,
debris slides and soil slips spatially clustered to a geological domain underlain by rather weak thin-bedded flysch and unconsolidated
Quaternary deposits. An exception to this is represented by a kilometre-long rockslide (∼2–3 mil m3) affecting tectonically weakened and weathered claystone/mudstone-dominated flysch on the southern slope of Mt. Girová (the
Beskydy Mountains). The rockslide is one of the largest long runout landslides in the territory of the Czech Republic activated
over the past few decades as it reaches the dimensions of the largest documented Holocene long runout landslides in the Czech
part of the OWC. A majority of the May 2010 landslide events developed inside older (Holocene or historic) landslide terrains,
which points to their spatial persistency and recurrent nature. In spite of the fact that the May 2010 landslide event was
not as destructive as some previous landslide activisation in the OWC region (e.g. July 1997 event), it left many slope failures
at the initial stage of their potential future reactivation. 相似文献