Hydrogeochemistry of Urban Floodplain Aquifer Under the Influence of Contaminated River Seepage in Delhi (India)

Hydrogeochemical and hydrodynamic surface/groundwater interactions were investigated at the urban floodplain aquifer in Delhi, India. The heavily polluted Yamuna River is in hydraulic contact to the groundwater and river seepage results in a contamination plume. A conceptual redox zonation was developed based on the occurrence or absence of terminal electron acceptors. The redox zonation shows an inverted zonation from sulphate-reducing conditions close to the river over manganese- and iron-reducing conditions to a mixed oxic/suboxic zone. This study shows that the occurrence of problematic substances such as ammonium and arsenic in the groundwater is a consequence of the high load of untreated sewage in the river in combination with losing river conditions. Sequential extraction of aquifer material was performed to obtain information on geochemical availability of arsenic associated with different mineral phases and binding forms. Geogenic and anthropogenic arsenic sources contribute to overall arsenic concentration, and arsenic is found to be attributed mainly to amorphous iron oxide and sulphidic phases in the sediment. The contamination plume at the urban floodplain aquifer makes the groundwater unfit for drinking water purposes.     

Map Comparison or Traditional Mass-balance Measurements: Which Method is Better?

A number of Norwegian glaciers were selected in the 1960s for long-term mass-balance measurements, to produce necessary hydrological information for hydropower exploitation. Special large-scale glacier maps were produced for field work and data processing, and some glaciers have been mapped more than once. Thus, comparison of glacier maps can be used to calculate changes in glacier volume for some of the glaciers, provided they are of sufficient accuracy.
Conventional mass-balance measurements were carried out on all the selected glaciers. A cumulative calculation of net balances for a series of years is used to indicate the change in a glacier's volume during that period. However, various errors originate in the field, some of which are systematic, particularly on glaciers with large winter accumulation.
The present study indicates that certain errors are difficult to define and determine, For the maritime glacier Ålfotbreen, a cumulative mass-balance calculation gives a positive total balance (+3.4 m water equivalent in the period 1968–88), whereas the map comparison indicates a total negative balance (−5.8 m water equivalent). This indicates a discrepancy between the methods, which must be accounted for.
Determination of errors in mass-balance measurements is difficult. Sinking of stakes in the accumulation area and the use of sounding sticks (steel probes) in heavy snowlayers cause problems.     

Depositional patterns of Pennsylvanian sediments in Sullivan County, West-Central Indiana, U.S.A.

Individual Pennsylvanian clastic sediment intervals above the Seelyville Coal were examined on electric logs from Sullivan County, Indiana, U.S.A. for vertical sequence, interval thickness, and sand content. This information was used to evaluate local variability of this area of the Illinois Basin depositional system.Each clastic interval is composed of a lateral association of vertical sequences of sediments, bounded above and below by a thin association of coal, limestone, black shale, and/or underclay. An “average” constructive clastic unit is characterized by the following thickness parameters: mean , standard deviation (s) = 3.4 m, minimum = 6.1 m, and

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sand content, as measured by electric log resistivity, is 37%.Clastic sediment intervals characterized as “deep water” sediments tend to be clayrich, have the greatest lateral continuity, are composed of 50% to 90% coarsening upward sequences, are comprised of less than 16% fining upward sequences, and are composed of less than 10% of sequences of facies which are transitional between coarsening and fining upward. Sandstone channels are linear to coarsely dendritic and probably postdate lower portions of the coarsening upward sequences. One example of longshore shoaling between the Springfield and Houchin Creek coals was discovered. This is the youngest stratigraphic evidence of longshore currents in Illinois Basin clastic sediments. This milieu probably represents a distal delta position.Shallow-water sediments are sand-rich, complex, and gradational. They tend to be interfingered and to display poor lateral continuity. Coarsening upward sequences comprise less than 20% of the data sites. Fining upward fluvial sequences are represented by well-developed dendritic map patterns and constitute 20–30% of the sites. Transitional sequences between coarsening and fining upward log profiles are represented by both interfingered and gradational sequences and constitute 20–55% of the sites.Each constructive vertical sequence represents only a portion of the overall progradational deltatic environment.Destructive linear erosional channels are oriented downdip into the basin. The first occurrence in Indiana of the Trivoli Sandstone channel facies, located between the Ditney and West Franklin horizons, was delineated. Destructive channel sands are found commonly between the Houchin Creek and Colchester coals.Clastic subintervals locally began to develop when compacted unit thickness exceeded 18 m.Average regional wedging contributes 0.13 m/km to local sediment interval thickness variability. The average compacted clastic interval thickness has a local range of 19 m owing to local depositional environments. This variation is related closely to the overall clastic ratio of end-member sequences which are situated in close proximity. The average clastic unit varies in thickness of ± 1.4 m owing to the influence of compaction of the underlying Pennsylvanian sediment filling the Mississippian unconformity valleys. Compactional effects between clastic units become negligible as composite interval thickness exceeds 30 m.     

Helgoland Roads,North Sea: 45 Years of Change

The Helgoland Roads time series is one of the richest temporal marine data sets available. Running since 1962, it documents changes for phytoplankton, salinity, Secchi disc depths and macronutrients. Uniquely, the data have been carefully quality controlled and linked to relevant meta-data, and the pelagic time series is further augmented by zooplankton, intertidal macroalgae, macro-zoobenthos and bacterioplankton data. Data analyses have shown changes in hydrography and biota around Helgoland. In the late 1970s, water inflows from the south-west to the German Bight increased with a corresponding increase in flushing rates. Salinity and annual mean temperature have also increased since 1962 and the latter by an average of 1.67°C. This has influenced seasonal phytoplankton growth causing significant shifts in diatom densities and the numbers of large diatoms (e. g. Coscinodiscus wailesii). Changes in zooplankton diversity have included the appearance of the ctenophore Mnemiopsis leidyi. The macroalgal community also showed an increase in green algal and a decrease in brown algal species after 1959. Over 30 benthic macrofaunal species have been newly recorded at Helgoland over the last 20 years, with a distinct shift towards southern species. These detailed data provide the basis for long-term analyses of changes on many trophic levels at Helgoland Roads.     

Primary and secondary bifurcation in baroclinic instability

In modelling atmospheric flows the baroclinic instability of the flow in a differentially heated rotating annulus plays a central role. This paper deals with an experimental study using LDV and flow visualization techniques. Usually the temperature difference,T, was kept fixed while the angular velocity,, was varied. On crossing the stability boundary, the primary bifurcation, the basic flow gives way to a baroclinic wave flow. For a given annulus geometry the wave number,m, of the first wave pattern was found to be uniquely defined byT. The measured critical values of, _crit, agree reasonably well with those obtained by other authors. On increasing above _crit the wave number changed, this process showing hysteresis. The situation might indicate secondary bifurcation phenomena. Flow visualization using aluminium particles shows surface flow details.This paper is dedicated to Prof. Dr. K. Gersten on the occasion of his 60th birthday     

Regional characterisation of hydraulic properties of rock using air-lift data

 Hydrogeologic studies are commonly data-intense. In particular, estimations of hydraulic properties of hard rock often require large amounts of data. In many countries, large quantities of hydrogeologic data have been collected and archived over the years. Therefore, the use of existing data may provide a cost-efficient alternative to collecting new data in early stages of hydrogeologic studies, although the available data may be considered imprecise. Initially, however, the potential usefulness, i.e., the expected accuracy, of the available data in each specific case must be carefully examined. This study investigates the possibilities of obtaining estimates of transmissivity from hard-rock air-lift data in Sweden within an order of magnitude of results obtained from high-quality injection-test data. The expected accuracy of the results was examined analytically and by means of statistical methods. The results were also evaluated by comparison with injection-test data. The results indicate that air-lift data produce estimates of transmissivity within an order of magnitude compared to injection-test data in the studied examples. The study also shows that partial penetration and hydrofracturing may only affect the estimations approximately half an order of magnitude. Thus, existing data may provide a cost-efficient alternative to collection of new data in early stages of hydrogeologic studies. Received, January 1998 Revised, November 1998, December 1998 Accepted, December 1998     

CO2 equivalences for short-lived climate forcers

With advancing climate change there is a growing need to include short-lived climate forcings in cost-efficient mitigation strategies to achieve international climate policy targets. Tools are required to compare the climate impact of perturbations with distinctively different atmospheric lifetimes and atmospheric properties. We present a generic approach for relating the climate effect of short-lived climate forcers (SLCF) to that of CO₂ emissions. We distinguish between three alternative types of metric-based factors that can be used to derive CO₂ equivalences for SLCF: based on forcing, activity and fossil fuel consumption. We derive numerical values for a wide range of parameter assumptions and apply the resulting generalised approach to the practical example of aviation-induced cloudiness. The evaluation of CO₂ equivalences for SLCF tends to be more sensitive to SLCF specific physical uncertainties and the normative choice of a discount rate than to the choice of a physical or economic metric approach. The ability of physical metrics to approximate economic-based metrics alters with changing atmospheric concentration levels and trends. Under reference conditions, physical CO₂ equivalences for SLCF provide sufficient proxies for economic ones. The latter, however, allow detailed insight into structural uncertainties. They provide CO₂ equivalences for SLCF in short term strategies in the face of failing climate policies, and a temporal evolution of CO₂ equivalences over time that is noticeably better in line with cost-efficient climate stabilisation.