Real system analyses/natural analogues

This paper gives an overview of the behaviour of U in two natural systems, the Forsmark site (a granitic system) in Sweden and the Ruprechtov site (a Tertiary sedimentary system) in the Czech Republic, which have been investigated in the frame of the FUNMIG project. It is not a full review paper on U geochemistry. It shows how different approaches and methods have been used to derive information on U solubility and speciation, on characteristics of key processes as well as on timescales of these processes and accordingly information on the long-term stability of U phases in the natural systems. The results are set in a wider context by relation to selected results from other sites.     

Heat generation versus depth of crystallization for Norwegian monzonitic rocks

Thorium, U and K analyses by γ-ray spectrometry of monzonitic intrusives from Lofoten-Vesterålen (ca. 1800 m.y.), Bjerkreim-Sogndal (ca. 1000 m.y.) and the Oslo region (ca. 275 m.y.) are used to calculate values of radioactive heat generation. A strong negative correlation between heat generation and depth of crystallization is demonstrated, indicating that the chemical zoning of the continental crust with respect to Th and U is of a rather regional and regular character, and was probably firmly established at least 1800 m.y. ago. The K contents, in contrast to Th and U, show an increase with depths of crystallization for these rocks. This may be explained by considerations of the pressure dependence of the partition coefficients for these elements between minerals and magma, and the importance of a fluid phase as a transport medium for the incompatible elements Th and U. A positive correlation between K content and age of intrusion is discussed on a tentative basis.     

Sub-surface precipitation of salts in supercritical seawater

Extremely low solubility of typical seawater salts within certain supercritical sections of their pressure–temperature composition space is a proven experimental fact. Its consequences are often referred to as either 'shock crystallization' or 'out-salting'. Our alternative model for the formation of salt deposits hypothesizes that high temperatures and pressures characteristic for the high heat-flow zones of tectonically active basins may bring submarine brines into the out-salting regions and result in the accumulation of geological-scale salt depositions.
To confirm the laboratory observations, molecular-scale simulations (molecular dynamics) have been employed to study structural changes in a model seawater system where temperature increased from ambient to near-critical and supercritical. Fluid properties and phase transition regions extracted from the simulations were then used as input parameters for a reservoir simulator program to model out-salting in a simple hydrothermal geological system. Both numerical simulations and laboratory experiments confirm that supercritical out-salting is a viable process of geological significance for the formation and accumulation of evaporites. We suggest two regions where hydrothermally associated salts may be depositing today: Atlantis II Deep, in the Red Sea, and Lake Asale, Ethiopia.     

Storsteinsfjellbreen: Variations in Mass Balance from the 1960s to the 1990s

When the Norwegian State Power Board decided to plan an extensive water power development in the mountainous areas southeast of Narvik in northern Norway, a large mapping project was started. Detailed maps were constructed at a scale of 1:10 000 from aerial photographs taken in 1960. Several hydrometric stations were installed, and three glaciers were selected for mass balance observations. Storsteinsfjellbreen was the largest of these, and a special glacier map with 10 m contours was printed in four colours, to be used in the field work. Mass balance studies were carried out initially during one 5-year period (1964–68), and also later during another 5-year period (1991–95).
Results from these periods are compared with similar data from the Swedish glacier Storglaciären, about 45 km to the southeast. For all the years except one (1968), the net balance of these glaciers shows a similar pattern: positive years and negative years are synchronous.
A new glacier map was made from a special aerial survey in 1993 at the same scale and of similar accuracy as the first map, so a comparison could be made to calculate the change in glacier volume from 1960 to 1993. From digital terrain models it could be shown that the glacier surface had dropped more than 60 m vertically on the tongue, while the thickness increased above the equilibrium line by up to 20 m. The overall mass loss amounted to 16.8×10⁶ m³ water during 33 years, which corresponds to an extra 2.6 l·s⁻¹·km⁻² (litres per sec. per sq. km) delivered to the river, in addition to the "normal" discharge
due to annual precipitation, which is 36 l·s⁻¹·km⁻² in the area.
A copy of the new glacier map is enclosed with this article.     

The effects of controlled drainage on subsurface outflow from level agricultural fields

Daily outflow frequencies and recession curves were used to identify differences in storage–outflow relationships between two different drainage systems, conventional and controlled drainage. A three‐year (1996–1999) field drainage experiment was carried out on a loamy sand soil in southern Sweden. Plots with an area of 0·2 hectares were drained by conventional subsurface drainage (CD) or by controlled drainage (CWT1 and CWT2). The controlled drainage system allowed the groundwater level in the soil to be varied during the year. It was kept at least 70 cm below the soil surface during the growing season but allowed to rise to a maximum of 20 cm below the soil surface during the rest of the year. Measurements were performed to record precipitation, drain outflow and groundwater levels. Daily values of outflow were divided into 10 categories, based on the size of outflow. Recession curves of hourly measurement of outflow were selected. They behaved like single reservoirs and a linear storage–outflow model was applied. Least squares estimates of the parameters initial outflow, initial storage volume and retention constant were calculated. Controlled drainage had a significant effect on total drain outflow and outflow pattern during the three years of measurement. The total drain outflow was 70% to 90% smaller in CWT than in CD. The analysis revealed that the initial outflows were higher, the retention constant and the temporary storage lower in CWT. The hydrological impacts of the reduction in temporary storage were higher peak flow, shorter lag time and shorter recession time and these effects increased with an increased groundwater level. Copyright © 2003 John Wiley & Sons, Ltd.