A potentially new type of nonchondritic interplanetary dust particle with hematite,organic carbon,amorphous Na,Ca‐aluminosilicate,and FeO‐spheres

Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe₂O₃) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.     

Origin of peraluminous granites and granodiorites, Iberian massif, Spain: an experimental test of granite petrogenesis

The discrimination between potential source materials involved in the genesis of Iberian granites and granodiorites, as well as the role of mantle-crust interactions, are examined using constraints imposed by melting experiments, melting-assimilation experiments and Sr-Nd isotope systematics. The Sr-Nd isotope relationships indicate the existence of different genetic trends in which juvenile mantle materials are involved by different mechanisms: (1) a source trend, traced by a particular evolution of the pre-Hercynian basement and indicating mantle participation at the time of sedimentation; (2) a set of magmatic trends traced by gabbro-tonalite-enclave-granodiorite associations, implying the incorporation of new mantle material at the time of granite generation. These relationships strongly support a pure crustal origin for the peraluminous leucogranites, derived from partial melting of crustal protoliths, and a hybrid origin for the peraluminous granodiorites. These granodiorites are the most abundant granitic rocks of the Central Iberian zone (CIZ) of the Iberian massif, implying that processes of hybridisation by assimilation and/or magma mixing played an important role in granitoid production during the Hercynian orogeny. These hypotheses have been tested by means of melting and assimilation experiments. Melting experiments in the range 800–900 °C and at pressures of 3, 6, 10 and 15 kbar indicate that: (1) several potential source materials such as Bt-Ms gneisses and metagreywackes are suitable for the production of peraluminous leucogranite melts; (2) the melt compositions are always leucogranitic, regardless of pressure; (3) pressure exerts a strong influence on the fertility of the source: experiments at 3 kbar produce more than 20 vol% of melt, compared with less than 5 vol% of melt produced at 10 and 15 kbar and at the same temperature. The melting-assimilation experiments carried out at 1000 °C and 4, 7 and 10 kbar and using a proportion of 50% gabbro and 50% gneiss give high melt proportions (more than 50 vol.%) and noritic residues. These melts have the composition of leucogranodiorites, and overlap with part of the compositional range of peraluminous granodiorites of the Iberian massif. The generation of more mafic granodiorites may be explained by the incorporation of some residual orthopyroxene to the granodiorite magmas. The low solubility of Fe + Mg prevents the generation of granodiorite melts with more than 3 wt% of MgO + FeO at all crustal pressures. The large volumes of peraluminous, hybrid granodiorites, produced by assimilation of crustal rocks by mantle magmas, imply that an important episode of crustal growth took place during the Late-Palaeozoic Hercynian orogeny in the Iberian massif. Received: 30 June 1998 / Accepted: 27 November 1998     

Reconstruction of fluvio-lacustrine landscapes and settlement history in the Texcoco region,Mexico, using a modern geomorphic analog

Located in the Basin of Mexico, the eastern shore of former Lake Texcoco sustained a variety of human occupations throughout the Holocene, including preceramic hunter-gatherers, incipient agriculturalists, and a variety of settlements in the ceramic periods. Nonetheless, the environmental dynamics of occupations on the lakeshore have not been fully addressed. The Archaic preagricultural Texcoco Man site (>5000 B.C.E.) and the Late Formative TX-LF-14 site (c. 550-200 B.C.E.), among others, occupy this fluvio-lacustrine transitional environment. Few stratigraphic works in and around the sites have been performed. Consequently, it is difficult to understand the dynamics of the sedimentary system in space and time. This work highlights and describes the fluvio-lacustrine sedimentary dynamics and the resulting landscape that past societies inhabited on the eastern shore of Texcoco Lake. Because the study area has been altered by historic and modern draining, our work employs Lake Santiaguillo and its main tributary, the Tejamen River in the Durango state, as a modern analog to study their sedimentary dynamics. The analyses of surface geomorphology in the Texcoco study area were employed to corroborate the modern analog interpretation. To achieve these goals, we conducted a GIS-based morphometric analysis and LANDSAT-8 imagery to study the variations in landforms through wet and dry events. The results indicate an increase in the lake volume, low bifurcation in the active fluvial channels, few inundated surfaces, and the presence of bird-foot deltaic channels during high precipitation events. In contrast, low precipitation events are characterized by reduced lake volume, increased fluvial channel bifurcation, and expanded floodplains. This heterogeneous landscape thus provided a rich source of diverse natural resources of saline and freshwater aquatic habitats. Simultaneously, constant or recurring flooding events generated a challenging landscape for prehistoric settlers who implemented diverse technologies, such as the construction of tlateles, on the levees of deltaic channels to reduce the risk and impact of flooding events.     

Water relations and hydraulic architecture of two Patagonian steppe shrubs: Effect of slope orientation and microclimate

On a local scale, topography influences microclimate, vegetation structure and the morpho-physiological attributes of plants. We studied the effects of microclimatic differences between NE- and SW-facing slopes on the water relations and hydraulic properties of two dominant shrubs of the Patagonian steppe in Argentina (Retanilla patagonica and Colliguaja integerrima). The NE-facing slope had higher irradiance and air saturation deficits and lower soil water availability and wind speed than the SW-facing slope. Predawn and midday Ψ_L and osmotic potentials were significantly lower in shrubs on the NE-facing slope. Osmotic adjustment and more elastic cell walls helped the plants to cope with a more xeric environment on NE-facing slope. Higher water deficits on NE-facing slope were partially compensated by a higher leaf and stem water storage. While stem hydraulic efficiency did not vary between slopes, leaf hydraulic conductance was between 40% and 300% higher on the NE-facing slope. Changes observed in leaf size and in SLA were consistent with responses to mechanical forces of wind (smaller and scleromorphic leaves on SW-facing slope). Morpho-physiological adjustments observed at a short spatial scale allow maintenance of midday Ψ_L above the turgor loss point and demonstrate that leaves are more responsive to microclimatic selective pressures than stems.     

Colluvial sedimentation in a hyperarid setting (Atacama Desert,northern Chile): Geomorphic controls and stratigraphic facies variability

Research on colluvial depositional systems has recently emphasized periglacial and high‐altitude settings, and the relations between Quaternary slope stratigraphy and climate change. This article examines the role of variable slope morphology, surface hydrology and microclimate in controlling colluvial sedimentation along a coastal tract of the hyperarid Atacama Desert in northern Chile. Direct accessibility of active surfaces is accompanied by uninterrupted stratigraphic exposures along the base of slopes, allowing direct comparisons between surface processes and the resulting sedimentary record. Four slope sectors are identified, based on differences in morphology and processes over active surfaces. Colluvial sedimentation is controlled by complex interactions of slope gradients and profiles, exposure to dominant winds, and potential runoff pathways, which vary considerably between different sectors. Major differences are evident between these hyperarid deposits and slope sedimentation in periglacial and temperate settings, including the complete absence of pedogenic activity and clay minerals; the volume of aeolian deposits and their role in controlling processes which redistribute sediment downslope, extending colluvial aprons; and the occurrence of runoff processes only where favoured by particular topographic configurations. Depositional surfaces range from steep talus cones, to debris‐flow‐dominated and aeolian‐dominated colluvial aprons, to an aeolian ramp subject to reworking by mass flows and flash floods. Consequently, facies associations and architectures at outcrop are highly variable and highlight the importance of spatial variations in slope morphology and processes in producing distinct, coeval colluvial stratigraphies within a single environmental context. Discrepancies between active processes and the corresponding stratigraphic signatures are also evident in some sectors; for example, preservation of alluvial and aeolian facies in stratigraphic sections does not always reflect the dominant processes over active slopes. Together with the spatial variability in processes and deposits along these slopes, this suggests that caution is required when extracting palaeoenvironmental information from analyses of colluvial successions.     

Analysis of anisotropy of magnetic susceptibility in iron-oolitic beds: a potential tool for paleocurrent identification

A combined sedimentological, shape-preferred orientation and anisotropy of magnetic susceptibility (AMS) analysis has been performed at the Arroyofrío Bed (Callovian–Oxfordian boundary level) in the locality of Moneva (Iberian Range, NE Spain). The Arroyofrío bed is a widespread iron-ooid limestone interval forming a condensed sequence. The present study has focused on the analysis of the potential presence of a preferred ooid orientation at the Arroyofrío bed. The obtained data show that ooids were originally ellipsoidal and had an imbricate disposition with respect to the bedding/lamination surface. The main ooid orientation within the bedding plane shows a NNE–SSW trend. Results of AMS analyses show a magnetic foliation parallel or slightly imbricated with respect to bedding and magnetic lineation parallel to the main ooid orientation. Magnetic mineralogy of studied samples shows that AMS is mainly controlled by magnetite with minor contributions of hematite and paramagnetic minerals (that can reach contributions of 35 %). The analyzed ooids show axial ratios between 1.4 and 2.8 (intrinsic anisotropy), while the anisotropy of their distribution shows lower anisotropies (e.g., Rs = 1.15) or very low values of the anisotropic magnetic parameters (e.g., P′ < 1.01). Sedimentary texture, matrix features, bioturbation and fossil content influenced both ooid main orientation and the magnetic fabric. Magnetic lineation and main orientation of long ooid axes are transverse to the inferred coastline in the studied area and parallel to the expected paleocurrent direction with respect to the Ejulve-Maestrazgo paleogeographic high. The direct correlation between AMS magnetic lineation and the ooid analysis permits to demonstrate that the paleocurrent imprint can be recorded by means of AMS despite the highly ferromagnetic context fabric and at coarse deposits. Obtained results support the interest and reliability of AMS to unravel paleocurrent imprints for paleogeographic reconstructions.     

Anthropogenic debris on beaches in the SE Pacific (Chile): Results from a national survey supported by volunteers

Anthropogenic marine debris (AMD) is an ubiquitous problem, which has motivated public participation in activities such as beach surveys and clean-up campaigns. While it is known that beaches in the SE Pacific are also affected by this problem, the quantities and types of AMD remain largely unknown. In the context of an outreach project, volunteers (1500 high-school students) participated in a nation-wide survey of AMD on 43 beaches distributed randomly along the entire Chilean coast (18°S to 53°S). The mean density of AMD was 1.8 items m⁻² and the major types were plastics, cigarette butts and glass. Densities in central Chile were lower than in northern and southern Chile, which could be due to different attitudes of beach users or to intense beach cleaning in central regions. We suggest that public participation in surveys and cleaning activities will raise awareness and thereby contribute to an improvement of the situation.     

Volcanoes in the pre-Columbian life,legend, and archaeology of Costa Rica (Central America)

Costa Rica is located geographically in the southern part of the Central American Volcanic Front, a zone where interaction between the Mesoamerican and South American cultures occurred in pre-Columbian times. Several volcanoes violently erupted during the Holocene, when the first nomadic human hunters and later settlers were present. Volcanic rocks were the most important geo-resource in making artifacts and as construction materials for pre-Columbian inhabitants. Some pottery products are believed to resemble smoking volcanoes, and the settlements around volcanoes would seem to indicate their influence on daily life. Undoubtedly, volcanic eruptions disrupted the life of early settlers, particularly in the vicinity of Arenal and Irazú volcanoes, where archaeological remains show transient effects and displacement caused by periodical eruptions, but later resilient occupations around the volcanoes. Most native languages are extinct, with the exception of those presently spoken in areas far away from active volcanoes, where no words are related to volcanic phenomena or structures. The preserved legends are ambiguous, suggesting that they were either produced during the early Spanish conquest or were altered following the pre-Columbian period.