High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

Electrodynamic Disaggregation: Does it Affect Apatite Fission-Track and (U-Th)/He Analyses?

Apatite fission-track and (U-Th)/He analyses require the liberation of intact idiomorphic apatite grains from rock samples. While routinely being carried out by mechanical methods, electrodynamic disaggregation (ED) offers an alternative approach. The high-voltage discharges produced during the ED process create localised temperature peaks (10000 K) along a narrow plasma channel. In apatite, such high temperatures could potentially reduce the length of fission tracks, which start to anneal at temperatures > 60 °C, and could also enhance He diffusion, which becomes significant at 30–40 °C over geological time scales. A comparison of fission-track analyses and (U-Th)/He ages of apatites prepared both by mechanical (jaw crusher, disk mill) and ED processing provides a way of determining whether heating during the latter method has any significant effect. Apatites from three samples of different geological settings (an orthogneiss from Madagascar, the Fish Canyon Tuff, and a muscovite-gneiss from Greece) yielded statistically identical track length distributions compared to samples prepared mechanically. Additionally, (U-Th)/He ages of apatites from a leucogranite from Morocco prepared by both methods were indistinguishable. These first results indicated that during electrodynamic disaggregation apatite crystals were not heated enough to partially anneal the fission tracks or induce significant diffusive loss of He.     

Observation of MKN 501 at gamma-ray energies

During a balloon flight in September 1979 of the MISO low-energy -ray telescope, the BL Lac-object MkN 501 was studied in the hard X-ray range above 30 keV and in the low energy -ray range up to 19 MeV. No statistically significant X- and -ray fluxes were detected. The implications of the upper limits obtained are discussed in the light of the relativistic jet theories recently proposed.     

Magnetic Reconnection and Extraplanar Diffuse Ionized Gas

Photoionization by stars cannot be the only cause for the diffuseionized gas component in the distant halos of galaxies.Quasistationary localized magnetic reconnection can efficientlycontribute to the ionization of the extraplanar halo gas. The gas isheated and re-ionized in numerous current filaments fast enough tocompensate recombination. The necessary magnetic energy is provided bythe disk activity.     

First results from a dark matter search with liquid argon at 87 K in the Gran Sasso underground laboratory

A new method of searching for dark matter in the form of weakly interacting massive particles (WIMP) has been developed with the direct detection of the low energy nuclear recoils observed in a massive target (ultimately many tons) of ultra pure liquid argon at 87 K. A high selectivity for argon recoils is achieved by the simultaneous observation of both the VUV scintillation luminescence and of the electron signal surviving columnar recombination, extracted through the liquid–gas boundary by an electric field.

First physics results from this method are reported, based on a small 2.3 l test chamber filled with natural argon and an accumulated fiducial exposure of about 100 kg day, supporting the future validity of this method with isotopically purified ⁴⁰Ar and for a much larger unit presently under construction with correspondingly increased sensitivities.     

Gentrification as space domestication. The High Line Art case

In this paper, we critically examine the role of artistic locational choices and practices in the context of gentrification processes in urban renewal contexts. We characterize gentrification as a form of domestication of space, and explore the extent to which artistic choices and practices relate to such process with reference to the deontological dilemma of legitimization within the art system vs. responsible empowerment of vulnerable local constituencies. We illustrate our argument with an analysis of the High Line Art project, and show how this can be considered as a textbook example of art-driven space domestication leading to brutal forms of gentrification. We comment on the threat that this provides to the social credibility of artistic practices as an agency of responsible social change.     

Bayesian Methods for Reconstructing Sunspot Numbers Before and During the Maunder Minimum

The Maunder Minimum (MM) was an extended period of reduced solar activity in terms of yearly sunspot numbers (SSN) during 1610?–?1715. The reality of this “grand minimum” is generally accepted in the scientific community, but the statistics of the SSN record suggest a need for data reconstruction. The MM data show a nonstandard distribution compared with the entire SSN signal (1610?–?2014). The pattern does not satisfy the weakly stationary solar dynamo approximation, which characterizes many natural events spanning centuries or even millennia, including the Sun and the stars. Over the entire observation period (1610?–?2014), the reported SSN exhibits statistically significant regime switches, departures from autoregressive stationarity, and growing trends. Reconstruction of the SSN during the pre-MM and MM periods is performed using five novel statistical procedures in support of signal analysis. A Bayesian–Monte Carlo backcast technique is found to be most reliable and produces an SSN signal that meets the weak-stationarity requirement. The computed MM signal for this reconstruction does not show a “grand” minimum or even a “semi-grand” minimum.     

Organizational Dynamics of the U.S. Logistics Industry: An Economic Geography Perspective*

Although the logistics industry provides critical services to all sectors of the economy, few studies exist in economic geography that examine and explain the organizational dynamics of this industry. This article highlights the significance of the logistics industry in contemporary industrialization and argues that an enriched understanding of the interaction between technology and space can be achieved by examining the evolution of an industry that plays a central role in the contemporary economy. We focus on dimensions that are identified as particularly important: organizational, geographic, and risk and security.     

Global mass wasting during the Middle Ordovician: Meteoritic trigger or plate-tectonic environment?

Mass wasting at continental margins on a global scale during the Middle Ordovician has recently been related to high meteorite influx. Although a high meteorite influx during the Ordovician should not be neglected, we challenge the idea that mass wasting was mainly produced by meteorite impacts over a period of almost 10 Ma. Having strong arguments against the impact-related hypothesis, we propose an alternative explanation, which is based on a re-evaluation of the mass wasting sites, considering their plate-tectonic distribution and the global sea level curve. A striking and important feature is the distribution of most of the mass wasting sites along continental margins characterised by periods of magmatism, terrane accretion and continental or back-arc rifting, respectively, related to subduction of oceanic lithosphere. Such processes are commonly connected with seismic activity causing earthquakes, which can cause downslope movement of sediment and rock. Considering all that, it seems more likely that most of this mass wasting was triggered by earthquakes related to plate-tectonic processes, which caused destabilisation of continental margins resulting in megabreccias and debris flows. Moreover, the period of mass wasting coincides with sea level drops during global sea level lowstand. In some cases, sea level drops can release pore-water overpressure reducing sediment strength and hence promoting instability of sediment at continental margins. Reduced pore-water overpressure can also destabilise gas hydrate-bearing sediment, causing slope failure, and thus resulting in submarine mass wasting. Overall, the global mass wasting during the Middle Ordovician does not need meteoritic trigger.