The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

A Critical review of theoretical models of negatively polarized light scattered by atmosphereless solar system bodies

About a dozen physical mechanisms and models aspire to explain the negative polarization of light scattered by atmosphereless celestial bodies. This is too large a number for the reliable interpretation of observational data. Through a comparative analysis of the models, our main goal is to answer the question: Does any one model have an advantage over the others? Our analysis is based on new laboratory polarimetric and photometric data as well as on theoretical results. We show that the widely used models due to Hopfield and Wolff cannot realistically explain the phase-angle dependence of the degree of polarization observed at small phase angles. The so-called interference or coherent backscattering mechanism is the most promising model. Models based on that mechanism use well-defined physical parameters to explain both negative polarization and the opposition effect. They are supported by laboratory experiments, particularly those showing enhancement of negative polarization with decreasing particle size down to the wavelength of light. According to the interference mechanism, pronounced negative branches of polarization, like those of C-class asteroids, may indicate a high degree of optical inhomogeneity of light-scattering surfaces at small scales. The mechanism also seems appropriate for treating the negative polarization and opposition effects of cometary dust comae, planetary rings, and the zodiacal light.     

The middle pleistocene deposits of Waverley Wood Pit,Warwickshire, England

A complex of channels underlying the Baginton-Lillington Gravel (Baginton Formation) at Waverley Wood Quarry, Warwickshire is described. Fossil pollen and plant macrofossils, Coleoptera, Ostracoda, Mollusca and Mammalia are described from the channel-fill deposits. Consideration of all the evidence allows the identification of four separate stages of channel fill which largely occurred under a cool temperate climate. At the top of Channel 2 evidence for a cold, continental climatic episode can be recognised, suggesting that the whole complex was deposited under a fluctuating climate at the end of a temperate stage. At two levels in the channels human artefacts were recovered confirming the presence of Palaeolithic people in Warwickshire during the deposition of the sediments. Amino-acid geochronology suggests an age within the ‘Cromerian Complex’ Stage for the channels. The small vertebrate and molluscan faunas indicate that the deposits are no older than the latter part of the ‘Cromerian Complex’ Stage of East Anglia. The regional stratigraphic significance of the Waverley Wood succession is outlined.     

Fluid infiltration during contact metamorphism of interbedded marble and calc-silicate hornfels, Twin Lakes area, central Sierra Nevada, California

Abstract In the Twin Lakes area, central Sierra Nevada, California, most contact metamorphosed marbles contain calcite + dolomite + forsterite ± diopside ± phlogopite ± tremolite, and most calc-silicate hornfelses contain calcite + diopside + wollastonite + quartz ± anorthite ± K-feldspar ± grossular ± titanite. Mineral-fluid equilibria involving calcite + dolomite + tremolite + diopside + forsterite in two marble samples and wollastonite + anorthite + quartz + grossular in three hornfels samples record P± 3 kbar and T± 630° C. Various isobaric univariant assemblages record CO₂-H₂O fluid compositions of χCO₂= 0.61–0.74 in the marbles and χCO₂= 0.11 in the hornfelses. Assuming a siliceous dolomitic limestone protolith consisting of dolomite + quartz ° Calcite ± K-feldspar ± muscovite ± rutile, all plausible prograde reaction pathways were deduced for marble and hornfels on isobaric T-XCO₂ diagrams in the model system K₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂. Progress of the prograde reactions was estimated from measured modes and mass-balance calculations. Time-integrated fluxes of reactive fluid which infiltrated samples were computed for a temperature gradient of 150 °C/km along the fluid flow path, calculated fluid compositions, and estimated reaction progress using the mass-continuity equation. Marbles and hornfelses record values in the range 0.1–3.6 × 10⁴ cm³/cm² and 4.8–12.9 × 10⁴ cm³/cm², respectively. For an estimated duration of metamorphism of 10⁵ years, average in situ metamorphic rock permeabilities, calculated from Darcy's Law, are 0.1–8 × 10^?6 D in the marbles and 10–27 × 10^?6 D in the hornfelses. Reactive metamorphic fluids flowed up-temperature, and were preferentially channellized in hornfelses relative to the marbles. These results appear to give a general characterization of hydrothermal activity during contact metamorphism of small pendants and screens (dimensions ± 1 km or less) associated with emplacement of the Sierra Nevada batholith.     

Prognosis of pool phase state and hydrocarbon fluid composition for the Pre-Caspian OGP

The results of detailed studies and interpretations are presented for composition variations, structural properties and the phase state of hydrocarbon fluids from subsalt pools of the Pre-Caspian depression. These data serve as a basis for substantiating the existence of several types of condensate, and identifying the locations of the main centres of fluid generation. The basic geological-geochemical conditions controlling the composition of condensate and free gases have been determined as well as their present phase state. A set of basic criteria is proposed as well as prognostic maps for the condensate and free gas composition, and the pool phase states.     

Late Holocene relative sea level rise and the Neoglacial history of the Greenland ice sheet

In West Greenland, early and mid Holocene relative sea level (RSL) fall was replaced by late Holocene RSL rise during the Neoglacial, after 4–3 cal. ka BP (thousand calibrated years before present). Here we present the results of an isolation basin RSL study completed near to the coastal town of Sisimiut, in central West Greenland. RSL fell from 14 m above sea level at 5.7 cal. ka BP to reach a lowstand of ?4.0 m at 2.3–1.2 cal. ka BP, before rising by an equivalent amount to present. Differences in the timing and magnitude of the RSL lowstand between this and other sites in West and South Greenland record the varied interplay of local and non‐Greenland RSL processes, notably the reloading of the Earth's crust caused by a Neoglacial expansion of the Greenland Ice Sheet (GIS) and the subsidence associated with the collapse of the Laurentide Ice Sheet forebulge. This means that the timing of the sea level lowstand cannot be used to infer directly when the GIS advanced during the Neoglacial. The rise in Late Holocene RSL is contrary to recently reported bedrock uplift in the Sisimiut area, based on repeat GPS surveys. This indicates that a belt of peripheral subsidence around the current ice sheet margin was more extensive in the late Holocene, and that there has been a switch from subsidence to uplift at some point in the last thousand years or so. Copyright © 2008 John Wiley & Sons, Ltd.     

Rapid Lateglacial tree population dynamics and ecosystem changes in the eastern Baltic region

A growing body of evidence implies that the concept of 'treeless tundra' in eastern and northern Europe fails to explain the rapidity of Lateglacial and postglacial tree population dynamics of the region, yet the knowledge of the geographic locations and shifting of tree populations is fragmentary. Pollen, stomata and plant macrofossil stratigraphies from Lake Kurjanovas in the poorly studied eastern Baltic region provide improved knowledge of ranges of north‐eastern European trees during the Lateglacial and subsequent plant population responses to the abrupt climatic changes of the Lateglacial/Holocene transition. The results prove the Lateglacial presence of tree populations (Betula, Pinus and Picea) in the eastern Baltic region. Particularly relevant is the stomatal and plant macrofossil evidence showing the local presence of reproductive Picea populations during the Younger Dryas stadial at 12 900–11 700 cal. a BP, occurring along with Dryas octopetala and arctic herbs, indicating semi‐open vegetation. The spread of Pinus–Betula forest at ca. 14 400 cal. a BP, the rise of Picea at ca. 12 800 cal. a BP and the re‐establishment of Pinus–Betula forest at ca. 11 700 cal. a BP within a span of centuries further suggest strikingly rapid, climate‐driven ecosystem changes rather than gradual plant succession on a newly deglaciated land. Copyright © 2009 John Wiley & Sons, Ltd.     

The brightness temperature problem in extreme intra-day variable quasars: a model for PKS 0405-385

I re-examine the brightness temperature problem in PKS 0405-385, which is an extreme intra-day variable radio quasar with an inferred brightness temperature of  ∼5 × 10¹⁴ K  at 5 GHz, well above the Compton catastrophe limit of  ∼10¹¹ K  that is reached when the synchrotron photon energy density exceeds the energy density of the magnetic field. If one takes into account the uncertainty in the distance to the ionized clouds responsible for interstellar scintillation causing rapid intra-day variability in PKS 0405-385, it is possible that the brightness temperature could be as low as  ∼10¹³ K  at 5 GHz, or even lower. The radio spectrum can be fitted by optically thin emission from mono-energetic electrons, or an electron spectrum with a low-energy cut-off such that the critical frequency of the lowest energy electrons is above the radio frequencies of interest. If one observes optically thin emission along a long narrow emission region, the average energy density in the emission region can be many orders of magnitude lower than calculated from the observed intensity if one assumed a spherical emission region. I discuss the physical conditions in the emission region and find that the Compton catastrophe can then be avoided using a reasonable Doppler factor. I also show that MeV to 100-GeV gamma-ray emission at observable flux levels should be expected from extreme intra-day variable sources such as PKS 0405-385.