The characteristics,origins, and geodynamic settings of supergiant gold metallogenic provinces

An investigation of the rock magnetic properties using stepwise isothermal remanence (IRM) acquisition, thermomagnetic analysis and temperature-dependent susceptibility history, identifies magnetite as the carrier of the main fraction of the remanence, associated with maghemite and hematite in Malan loess (L1), Holocene soil (S0) and last-glacial paleosol (S1). The presence of short-lived direction fluctuations indicates that no significant smoothing occurs in L1 when its remanence is locked, and thus L1 is capable of recording the geomagnetic secular variation (PSV), while the PSV has been severely smoothed or wiped out by pedogenic processes during S1 formation. It has been suggested that the Mono Lake and Laschamp excursions are two independent geomagnetic events based on this study.     

The characteristics,origins, and geodynamic settings of supergiant gold metallogenic provinces

There are six distinct classes of gold deposits, each represented by metallogenic provinces, having 100's to >1000 tonne gold production. The deposit classes are: (1) orogenic gold; (2) Carlin and Carlin-like gold deposits; (3) epithermal gold-silver deposits; (4) copper-gold porphyry deposits; (5) iron-oxide copper-gold deposits; and (6) gold-rich volcanic hosted massive sulfide (VMS) to sedimentary exhalative (SEDEX) deposits. This classification is based on ore and alteration mineral assemblages; ore and alteration metal budgets; ore fluid pressure(s) and compositions; crustal depth or depth ranges of formation; relationship to structures and/or magmatic intrusions at a variety of scales; and relationship to the P-T-t evolution of the host terrane. These classes reflect distinct geodynamic settings. Orogenic gold deposits are generated at mid-crustal (4–16 km) levels proximal to terrane boundaries, in transpressional subduction-accretion complexes of Cordilleran style orogenic belts; other orogenic gold provinces form inboard, by delamination of mantle lithosphere, or plume impingement. Carlin and Carlin-like gold deposits develop at shallow crustal levels (<4 km) in extensional convergent margin continental arcs or back arcs; some provinces may involve asthenosphere plume impingement on the base of the lithosphere. Epithermal gold and copper-gold porphyry deposits are sited at shallow crustal levels in continental margin or intraoceanic arcs. Iron oxide copper-gold deposits form at mid to shallow crustal levels; they are associated with extensional intracratonic anorogenic magmatism. Proterozoic examples are sited at the transition from thick refractory Archean mantle lithosphere to thinner Proterozoic mantle lithosphere. Gold-rich VMS deposits are hydrothermal accumulations on or near the seafloor in continental or intraoceanic back arcs.

The compressional tectonics of orogenic gold deposits is generated by terrane accretion; high heat flow stems from crustal thickening, delamination of overthickened mantle lithosphere inducing advection of hot asthenosphere, or asthenosphere plume impingement. Ore fluids advect at lithostatic pressures. The extensional settings of Carlin, epithermal, and copper-gold porphyry deposits result from slab rollback driven by negative buoyancy of the subducting plate, and associated induced convection in asthenosphere below the over-riding lithospheric plate. Extension thins the lithosphere, advecting asthenosphere heat, promotes advection of mantle lithosphere and crustal magmas to shallow crustal levels, and enhances hydraulic conductivity. Siting of some copper-gold porphyry deposits is controlled by arc parallel or orthogonal structures that in turn reflect deflections or windows in the slab. Ore fluids in Carlin and epithermal deposits were at near hydrostatic pressures, with unconstrained magmatic fluid input, whereas ore fluids generating porphyry copper-gold deposits were initially magmatic and lithostatic, evolving to hydrostatic pressures. Fertilization of previously depleted sub-arc mantle lithosphere by fluids or melts from the subducting plate, or incompatible element enriched asthenosphere plumes, is likely a factor in generation of these gold deposits. Iron oxide copper-gold deposits involve prior fertilization of Archean mantle lithosphere by incompatible element enriched asthenospheric plume liquids, and subsequent intracontinental anorogenic magmatism driven by decompressional extension from far-field plate forces. Halogen rich mantle lithosphere and crustal magmas likely are the causative intrusions for the deposits, with a deep crustal proximal to shallow crustal distal association. Gold-rich VMS deposits develop in extensional geodynamic settings, where thinned lithosphere extension drives high heat flow and enhanced hydraulic conductivity, as for epithermal deposits. Ore fluids induced hydrostatic convection of modified seawater, with unconstrained magmatic input. Some gold-rich VMS deposits with an epithermal metal budget may be submarine counterparts of terrestrial epithermal gold deposits. Real time analogs for all of these gold deposit classes are known in the geodynamic settings described, excepting iron oxide copper-gold deposits.

     

Energy fluxes of the (1,1,1) atmospheric oscillation

The global mean vertical energy flux of the (1,1,1) mode of atmospheric oscillation is evaluated at 80 km altitude by classical tidal theory for mean January, April, July and October conditions using revised profiles of water vapour and ozone heating. Fluxes calculated for January and July are lower than those for April and October due to seasonal changes in water vapour, solar declination and Sun-Earth distance. Flux values obtained are compared with a previously stated requirement for maintaining the residual thermosphere and are adequate unless damping, which is ignored in the present calculations, introduces a factor of more than an order of 10 in magnitude. The relative changes of flux between the above four months are noted to be similar in form to the semi-annual variation of thermospheric air densities.     

A unified model for gold mineralisation in accretionary orogens and implications for regional-scale exploration targeting methods

Accretionary orogens are the sites of long-lived convergent margin tectonics, both compressional and extensional. They are also the hosts to the majority of the world’s important gold deposits. A very diverse range of deposit types occurs within accretionary orogens, commonly in close proximity in space and time to each other. These include porphyry and associated high-sulphidation Au–Cu–Ag deposits, classic low-sulphidation Au–Ag deposits, low-sulphidation Au deposits centred on alkalic intrusive complexes, Carlin-type Au deposits, Au-rich volcanic-hosted massive sulphide deposits, orogenic Au deposits, intrusion-related Au deposits and iron oxide Cu–Au deposits. Empirical patterns of spatial distribution of these deposits suggest there must be fundamental generic controls on gold metallogeny. Various lines of evidence lead to the proposal that the underlying key generic factor controlling accretionary orogen gold metallogeny is regional-scale, long-term, pre- and syn-subduction heterogeneous fertilisation of the lithospheric mantle that becomes a source of mineralisation-associated arc magma or hydrothermal fluid components. This process provides a gold-enriched reservoir that can be accessed later in a diverse range of tectonomagmatic settings. Based on this concept, a unified model is proposed in which the formation of a major gold deposit of any type requires the conjunction in time and space of three essential factors: a fertile upper-mantle source region, a favourable transient remobilisation event, and favourable lithospheric-scale plumbing structure. This framework provides the basis for a practical regional-scale targeting methodology that is applicable to data-poor regions.     

利用因子分析确定岩溶地下河系统水质的影响因素

根据云南南洞地下河系统2008年旱季的水化学分析结果,利用因子分析方法探讨地下水水质的影响因素及程度,结果表明:流域地下水成分变动范围较大,具有明显的空间变异性;地下水水质受人类活动、水岩作用过程和土壤等自然因素的共同影响,三个因素能够解释地下水水质形成的79%,其中人类活动是主要影响因素;地下水中的Cl-、NO3-、SO42-、Na+、K+主要受人类活动特别是农业和生活废水等因素的控制,Ca2+主要是水-岩作用的产物,但也受人类活动的影响,pH值、电导率受水岩作用过程和人类活动的影响,Mg2+、HCO3-受土壤CO2含量和水-岩作用过程的共同影响。     

The petrogenesis of Merensky Reef potholes at the Western Platinum Mine, Bushveld Complex: Sr-isotopic evidence for synmagmatic deformation

Potholes represent areas where the normally planar PGE-rich Merensky Reef of the upper Critical Zone of the Bushveld Complex transgresses its footwall, such geometric relationships being unusual in layered intrusions. The recognition of vertical dykes of Merensky pyroxenite in the footwall suggests downward collapse of crystal mush into pull-apart sites resulting from tensional deformation due to the loading effects of major new magma additions. In contrast, crosscutting anorthosite veins display physical and isotopic evidence of upward emplacement. The Merensky Reef and its footwall have distinct initial Sr-isotope ratios (R ₀ > 0.7066 and <0.7066, respectively), which may be used to constrain these processes related to pothole formation. Merensky Reef in potholes (R ₀ = 0.7069−0.7078) shows no isotopic evidence of assimilation of, or reaction with, footwall material. Discrete, discordant replacement bodies of anorthosite extend from the footwall lithologies to cross-cut the Merensky Reef and its hanging wall. The initial Sr-isotope ratio in these replaced rocks is totally reset to footwall values (R ₀ = 0.7066), and immediately adjacent stratiform lithologies are slightly modified towards footwall values. In contrast, Neptunian pyroxenitic (Merensky) dykes cross-cutting the footwall lithologies, with a large surface area to volume ratio, and low Sr content, do not display footwall-like Sr-isotope initial-ratios (R ₀ = 0.7077), and thus show no evidence for assimilation of or reaction with footwall material. Furthermore, pegmatoidal replacement pyroxenite (“replacement pegmatoid”), at the base of the Merensky Reef within potholes, has a high initial-ratio (R ₀ > 0.7071), and so models of pervasive metasomatism by footwall material are not applicable. This isotopic evidence indicates that there was no active interaction of footwall material with the overlying magma during, or after, the formation of Merensky Reef potholes, a basic tenet of existing pothole formation hypotheses involving footwall mass-transfer. In contrast, the isotopic data are entirely consistent with an extensional model for pothole formation, with the more radiogenic Merensky magma migrating laterally to fill extensional zones in the footwall layers. Received: 11 October 1997 / Accepted: 21 December 1998     

Positioning fisheries in a changing world

Marine capture fisheries face major and complex challenges: habitat degradation, poor economic returns, social hardships from depleted stocks, illegal fishing, and climate change, among others. The key factors that prevent the transition to sustainable fisheries are information failures, transition costs, use and non-use conflicts and capacity constraints. Using the experiences of fisheries successes and failures it is argued only through better governance and institutional change that encompasses the public good of the oceans (biodiversity, ecosystem integrity, sustainability) and societal values (existence, aesthetic and amenity) will fisheries be made sustainable.     

Hydrochemical variations during flood pulses in the south‐west China peak cluster karst: impacts of CaCO3–H2O–CO2 interactions

High‐resolution measurements of rainfall, water level, pH, conductivity, temperature and carbonate chemistry parameters of groundwater at two adjacent locations within the peak cluster karst of the Guilin Karst Experimental Site in Guangxi Province, China, were made with different types of multiparameter sonde. The data were stored using data loggers recording with 2 min or 15 min resolution. Waters from a large, perennial spring represent the exit for the aquifer's conduit flow, and a nearby well measures water in the conduit‐adjacent, fractured media. During flood pulses, the pH of the conduit flow water rises as the conductivity falls. In contrast, and at the same time, the pH of groundwater in the fractures drops, as conductivity rises. As Ca²⁺ and HCO₃^? were the dominant (>90%) ions, we developed linear relationships (both r² > 0·91) between conductivity and those ions, respectively, and in turn calculated variations in the calcite saturation index (SI_C) and CO₂ partial pressure (P) of water during flood pulses. Results indicate that the P of fracture water during flood periods is higher than that at lower flows, and its SI_C is lower. Simultaneously, P of conduit water during the flood period is lower than that at lower flows, and its SI_C also is lower. From these results we conclude that at least two key processes are controlling hydrochemical variations during flood periods: (i) dilution by precipitation and (ii) water–rock–gas interactions. To explain hydrochemical variations in the fracture water, the water–rock–gas interactions may be more important. For example, during flood periods, soil gas with high CO₂ concentrations dissolves in water and enters the fracture system, the water, which in turn has become more highly undersaturated, dissolves more limestone, and the conductivity increases. Dilution of rainfall is more important in controlling hydrochemical variations of conduit water, because rainfall with higher pH (in this area apparently owing to interaction with limestone dust in the lower atmosphere) and low conductivity travels through the conduit system rapidly. These results illustrate that to understand the hydrochemical variations in karst systems, considering only water–rock interactions is not sufficient, and the variable effects of CO₂ on the system should be evaluated. Consideration of water–rock–gas interactions is thus a must in understanding variations in karst hydrochemistry. Copyright © 2004 John Wiley & Sons, Ltd.     

The giant Vergenoeg fluorite deposit in a magnetite–fluorite–fayalite REE pipe: a hydrothermally-altered carbonatite-related pegmatoid?

Summary The world-class Paleoproterozoic Vergenoeg fluorite deposit in South Africa is hosted in a breccia pipe comprising units with varying proportions of pegmatoidal fayalite, magnetite, fluorite and siderite. The adjacent A-type Bushveld granites also have associated fluorite deposits containing fluorite with similar REE patterns, fluid inclusion and Sr isotope compositions to those at Vergenoeg, leading to the proposal that there is a genetic relationship. This is despite the silica-undersaturated nature (SiO₂<30%) of the Pipe and its extreme enrichment in Ca, F, Fe, Nb, P and REE compared to granites. Both liquid immiscibility from a granitic melt and granitic magmato-hydrothermal activity have been proposed as genetic mechanisms to explain this exotic composition. However, the Vergenoeg Pipe shows greater similarities to alkaline rocks, in particular the Phalaborwa carbonatite of similar age, including: i) size and shape, ii) associated maars, iii) mineralogical zoning, iv) geochemical, radiogenic and stable isotope composition, and v) presence of both high-T and low-T fluid inclusions. This suggests an alternative genetic relationship with alkaline magmas, in which some geochemical and radiogenic isotopic similarities to Bushveld granites are the consequence of broadly contemporaneous development in the same tectonic setting within the same lithosphere, whereas others may be due to hydrothermal overprinting. Similarities with Phalaborwa and also with Bayan Obo, Mongolia, indicate that the Vergenoeg pegmatoid pipe could be an extreme carbonatite-associated member of the Fe-oxide Cu–Au (±REE±P) group of deposits.Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1007/s00710-003-0012-6Tables 1-4 available as electronic supplementary material