Étude expérimentale de la réactivité du CO2 supercritique vis-à-vis de phases minérales pures. Implications pour la séquestration géologique de CO2

Carbon dioxide sequestration in deep aquifers and depleted oilfields is a potential technical solution for reducing green-house gas release to the atmosphere: the gas containment relies on several trapping mechanisms (supercritical CO₂, CO_2(sc), dissolution together with slow water flows, mineral trapping) and on a low permeability cap-rock to prevent CO_2(sc), which is less dense than the formation water, from leaking upwards. A leakproof cap-rock is thus essential to ensure the sequestration efficiency. It is also crucial for safety assessment to identify and assess potential alteration processes that may damage the cap-rock properties: chemical alteration, fracture reactivation, degradation of injection borehole seals, etc. The reactivity of the host-rock minerals with the supercritical CO₂ fluid is one of the potential mechanisms, but it is altogether unknown. Reactivity tests have been carried out under such conditions, consisting of batch reactions between pure minerals and anhydrous supercritical CO₂, or a two-phase CO₂/H₂O fluid at 200?°C and 105/160 bar. After 45 to 60 days, evidence of appreciable mineral-fluid reactivity was identified, including in the water-free experiments. For the mixed H₂O/CO₂ experiments, portlandite was totally transformed into calcite; anorthite displayed many dissolution patterns associated with calcite, aragonite, tridymite and smectite precipitations. For the anhydrous CO₂ experiments, portlandite was totally carbonated to form calcite and aragonite; anorthite also displayed surface alteration patterns with secondary precipitation of fibrous calcite. To cite this article: O. Regnault et al., C. R. Geoscience 337 (2005).     

Sources and history of heavy metal contamination and sediment deposition in Tivoli South Bay, Hudson River, New York

Persistent inorganic constitutents preserved in sediments of aquatic ecosystems record temporal variability of biogeochemical functioning and anthropogenic impacts.²¹⁰Pb and¹³⁷Cs dating techniques were used to study the past variations of heavy metals (Pb, Cu, and Zn) and accumulation rates of sediments for Tivoli South Bay, in the Hudson River National Estuarine Research Reserve ecosystem. South Bay, a tidal freshwater embayment of the Hudson, may play an important role in the sediment dynamics of this important river. The measured sedimentation rate range of 0.59 to 2.92 cm yr⁻¹ suggests that rapid accumulation occurred during the time period represented by the length of the cores (approximately the past 50 yr). Direct measurements of sediment exchange with the Hudson River reveal high variability in the sediment flux from one tidal cycle to the next. Net exchange does not seem to be adequate to explain sediment accumulation rates in the bay as measured by²¹⁰Pb and¹³⁷Cs. The difference may be supplied from upland streams or the Hudson River during storm events. Concentrations of the metals Pb, Cu and Zn were found to be well correlated with each other within individual cores at five of six sites tested. This suggests a common proximate source for the three metals at a specific site. The evidence is consistent with mixing in some environmental compartment before delivery to the bay. While metals self-correlate within individual cores, absolute concentrations, depth distribution patterns, and ratios of the metals to each other vary among the cores collected at different locations within the bay. Organic matter, Fe content, and particle size distribution of sediments do not account for the intercore variations in metal concentration. It is likely that cores collected from different sites may have derived metals from different sources, such as watershed streams and tidal exchange with the Hudson River.     

The Decline and Restoration of a Coastal Lagoon (Lake Veere) in the Dutch Delta

The former tidal inlet Lake Veere was turned into a stagnant brackish lake in 1961. Ever since, the system has shown a continuous degradation. The current study shows the monitoring results for the macrozoobenthic communities and the abiotic conditions for the period 1990–2008. This includes the first step to remediation, the restoration of the exchange between the tidal marine Eastern Scheldt and Lake Veere in 2004. A continuous decline in water clearance co-occurring with decreasing macrofauna densities and richness was observed till 2004. Water quality (e.g., secchi depth, nutrient levels, and oxygen conditions) improved significantly after the measure at a higher salinity level with less variation. But the macrofauna densities, biomass, and diversity did not improve yet. First indications of changes in the benthic communities by arrival of new and returning species are however observed and show that restoration at macrofauna level follows the improved abiotic conditions with a delay of several years.     

The influence of the coast on the dynamics of upwelling fronts: Part II. Numerical simulations

We investigated the dynamics of upwelling fronts near a coast. This work was first motivated by laboratory experiments [Bouruet-Aubertot, Linden, Dyn. Atmos. Oceans, 2002] in which the front is produced by the adjustment of a buoyant fluid initially confined within a bottomless cylinder. It was shown that cyclonic eddies consisting of coastal waters are enhanced when the front is unstable near the coast (the outer vertical boundary). The purpose of this paper is to provide further insights into this process. We reproduced the experimental configuration using a three-dimensional model of the primitive equations. We first show that for coastal fronts more potential energy, in terms of the maximum available potential energy, is released than for open-ocean fronts. Therefore, waves of larger amplitude are generated during the adjustment and the mean flow that establishes has a higher kinetic energy in the former case. Then as baroclinic instability starts and wave crests reach the boundary, cyclonic eddies are enhanced as in the laboratory experiments and in a similar way. However, in contrast to the laboratory experiments, offshore advection of cyclonic eddies can occur in two stages, depending on the spatial organization of the baroclinic wave. When the baroclinic wave consists of the sum of different modes and is thus highly asymmetric, the offshore advection of cyclonic eddies occurs just after their enhancement at the boundary, as in the laboratory experiments. By contrast, when a single-mode baroclinic wave develops, neighboring cyclonic eddies first merge before being advected offshore. Very different behavior is observed for open-ocean fronts. First a mixed baroclinic–barotropic instability grows. Then the eddies transfer their energy to the mean flow and the barotropic and baroclinic instabilities start again. An excellent agreement is obtained with the main result obtained in the laboratory experiments: the ratio between growth rates of surface cyclonic and anticyclonic vorticity increases as the instability develops nearer to the coast.     

Tropical cyclone environments over the northeastern Pacific, including mid-level dry intrusion cases

Summary This study uses a 1°×1° lat/long dataset, extracted from ECMWF re-analyses for the 15-year period 1979–1993 (ERA-15), to diagnose the synoptic-scale kinematic, thermodynamic and moisture environments in the vicinity of named tropical cyclones (TCs) in the eastern North Pacific. Based on the NCDC best track dataset, TCs are partitioned into one of three categories: weak (W), strong (S) or intensifying (I). In total, 63TCs are examined: 8Ws and 20Is at point A (maximum intensification) and 11Ws, 13Ss and 11Is at point B (maximum frequency). Composite maps are compiled for all five groups, and six individual case studies are examined, four for extreme TC cases and two for cases involving dry air intrusions.For the most part, peak values and patterns of composited ERA-15 variables display circulation, thermodynamic and moisture characteristics that are compatible with the strength represented by a groups classification. Intercomparison between Ws and Is at points A and B yielded larger conditional instability of low-level air parcels and upper-level outflow within the region of maximum intensification (point A).The intrusions of dry versus moist mid-level air are addressed for each storm with the assistance of 72-hour backward trajectories. Trajectory density maps indicate two preferred paths of air parcels that reach the environment of W storms at point A on the 700 and 500hPa levels. The first one crossed Central America in the region of the Isthmus of Tehuantepec and the second one south of the Central American mountains. Several storms revealed that these trajectories were associated with dry air intrusions into the larger storm area, and this might be one reason for their weak status at point A. One documented example is Kevin (1985). By the time it reached point B, the dry air was replaced by air that was moist and Kevin intensified, although it remained a W system. In contrast, Narda (1989) received a dry air intrusion from Central Mexico at 500hPa as a weak storm at point B and did not intensify. Despite possible analyses problems, the documentation in this study of mid-level dry air intrusions into eastern Pacific TCs from the Mexican-Central American region suggests a hitherto unexploited forecast potential. Received January 15, 2002; revised November 28, 2002; accepted December 19, 2002 Published online: May 8, 2003     

An Observational Study of the Mesoscale Mistral Dynamics

We investigate the mesoscale dynamics of the mistral through the wind profiler observations of the MAP (autumn 1999) and ESCOMPTE (summer 2001) field campaigns. We show that the mistral wind field can dramatically change on a time scale less than 3 hours. Transitions from a deep to a shallow mistral are often observed at any season when the lower layers are stable. The variability, mainly attributed in summer to the mistral/land–sea breeze interactions on a 10-km scale, is highlighted by observations from the wind profiler network set up during ESCOMPTE. The interpretations of the dynamical mistral structure are performed through comparisons with existing basic theories. The linear theory of R. B. Smith [Advances in Geophysics, Vol. 31, 1989, Academic Press, 1–41] and the shallow water theory [Schär, C. and Smith, R. B.: 1993a, J. Atmos. Sci. 50, 1373–1400] give some complementary explanations for the deep-to-shallow transition especially for the MAP mistral event. The wave breaking process induces a low-level jet (LLJ) downstream of the Alps that degenerates into a mountain wake, which in turn provokes the cessation of the mistral downstream of the Alps. Both theories indicate that the flow splits around the Alps and results in a persistent LLJ at the exit of the Rhône valley. The LLJ is strengthened by the channelling effect of the Rhône valley that is more efficient for north-easterly than northerly upstream winds despite the north–south valley axis. Summer moderate and weak mistral episodes are influenced by land–sea breezes and convection over land that induce a very complex interaction that cannot be accurately described by the previous theories.     

Temperature and precipitation trends in Canada during the 20th century

Abstract

Trends in Canadian temperature and precipitation during the 20th century are analyzed using recently updated and adjusted station data. Six elements, maximum, minimum and mean temperatures along with diurnal temperature range (DTR), precipitation totals and ratio of snowfall to total precipitation are investigated. Anomalies from the 1961–1990 reference period were first obtained at individual stations, and were then used to generate gridded datasets for subsequent trend analyses. Trends were computed for 1900–1998 for southern Canada (south of 60°N), and separately for 1950–1998 for the entire country, due to insufficient data in the high arctic prior to the 1950s.

From 1900–1998, the annual mean temperature has increased between 0.5 and 1.5°C in the south. The warming is greater in minimum temperature than in maximum temperature in the first half of the century, resulting in a decrease of DTR. The greatest warming occurred in the west, with statistically significant increases mostly seen during spring and summer periods. Annual precipitation has also increased from 5% to 35% in southern Canada over the same period. In general, the ratio of snowfall to total precipitation has been increasing due mostly to the increase in winter precipitation which generally falls as snow and an increase of ratio in autumn. Negative trends were identified in some southern regions during spring. From 1950–1998, the pattern of temperature change is distinct: warming in the south and west and cooling in the northeast, with similar magnitudes in both maximum and minimum temperatures. This pattern is mostly evident in winter and spring. Across Canada, precipitation has increased by 5% to 35%, with significant negative trends found in southern regions during winter. Overall, the ratio of snowfall to total precipitation has increased, with significant negative trends occurring mostly in southern Canada during spring.

Indices of abnormal climate conditions are also examined. These indices were defined as areas of Canada for 1950–1998, or southern Canada for 1900–1998, with temperature or precipitation anomalies above the 66th or below the 34th percentiles in their relevant time series. These confirmed the above findings and showed that climate has been becoming gradually wetter and warmer in southern Canada throughout the entire century, and in all of Canada during the latter half of the century.