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101.
C. Albarrán-Liso M. M. Jordán-Vidal T. Sanfeliu-Montolio M. J. Liso-Rubio 《Environmental Geology》2006,49(7):1043-1050
The necessity of eliminating debris from a granite quarry has awakened an interest in applications of by-products, called
“marginal arids”, in different fields, like construction and foundations for roadways, restoration, material for the manufacture
of artificial rocks, and artesian products etc. Conclusions obtained from the results of tests carried out by X-ray diffraction
of granite quarry by-products in Extremadura, Spain, submitted to different treatments, are established. Test pieces from
two quarries are analyzed and compared generally and specifically, for commercial use. Finally, conclusions relating to essays
in test pieces and mineral dynamics of marginal arid granite are exposed. 相似文献
102.
Summary Lenses and pods of mafic rocks from the Monotonous Unit near Svetlik are characterized by eclogite facies mineral assemblages;
however some inclusion patterns (oriented quartz rods in clinopyroxene and cuboids of disordered graphite in garnet) that
are usually known from ultra-high pressure rocks were also observed in one sample. Conventional thermobarometry yielded maximum
P–T conditions of 2.0–2.5 GPa and 750 °C. Decompression and heating at amphibolite and granulite facies conditions resulted in
the formation of at least five distinct types of symplectites. These include symplectitic intergrowth of ilmenite and clinopyroxene
after titanite, described here for the first time from the Moldanubian Zone. In addition, symplectites of plagioclase and
biotite with accessory amounts of spinel after tabular pseudomorphs (after phengite?) are also reported here. Mass balance
relations indicate that symplectites of diopside + plagioclase after omphacite and plagioclase + spinel (sapphirine) after
kyanite + garnet, formed by nearly isochemical reactions. All other symplectite-forming reactions were allochemical and were
accelerated by the presence of fluid in the primary phases. Preserved zoning pattern in garnet with high compositional gradient
in some samples suggests that the rocks were affected briefly by granulite facies overprint. 相似文献
103.
C. Schnitchen D. J. Charman E. Magyari M. Braun I. Grigorszky B. Tóthmérész M. Molnár Zs. Szántó 《Journal of Paleolimnology》2006,36(1):1-17
Peatlands offer the potential for high resolution records of water balance over Holocene timescales, yet this potential is
under-exploited in many areas of the world. Within Europe, peatlands are mostly confined to areas north of 55° N, but several
areas of southern and eastern Europe contain small peatlands which may be suitable for palaeoclimatic reconstruction. In this
paper we test the potential of peatlands in the Carpathian region for deriving quantified estimates of water table changes
using testate amoebae analysis. A training set for palaeohydrological reconstruction from testate amoebae assemblages was
obtained by collecting surface samples from 13 peatlands, including 9 from Hungary and 4 from Transylvania (Romania). Using
a simple measure of mean annual water tables estimated from staining of PVC tape, we found that some peatlands were heavily
influenced by runoff and groundwater, and were therefore not suitable as modern analogues of ombrotrophic climatically sensitive
sites. The relationship between the testate amoebae assemblages in the modern samples and the environmental variables was
explored using CCA. The CCA biplot showed that the most important variables are depth to water table and moisture content,
confirming that hydrology is a key control on taxon distribution. pH was a secondary gradient. A transfer function for % moisture
and depth to water table was established and applied to fossil assemblages from a sequence from Fenyves-tető, Transylvania,
Romania. The reconstructed water table shows a number of variations which have parallels with other palaeoclimatic records
from Europe and the North Atlantic prominent phases of higher water tables are associated with the periods 8000–8300 cal BP,
3000–2500 cal BP and after 600 cal BP. We suggest that these were periods of particular intensification of westerly airflow
which affected eastern Europe as well as western and central Europe. 相似文献
104.
Geraldo Magela da Costa Gabriel de Oliveira Polli Márcio A. Kahwage Eddy de Grave Antônio Claret Soares Sabioni Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166
Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be3Al2Si6O18) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe2+ doublet (ΔE
Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe3+ (ΔE
Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe2+ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites. 相似文献
105.
Environmental and health risk assessment in abandoned mining area, Zlata Idka, Slovakia 总被引:1,自引:0,他引:1
The Zlata Idka village is a typical mountainous settlement. As a consequence of more than 500 years of mining activity, its environment has been extensively affected by pollution from potentially toxic elements. This paper presents the results of an environmental-geochemical and health research in the Zlata Idka village, Slovakia. Geochemical analysis indicates that arsenic (As) and antimony (Sb) are enriched in soils, groundwater, surface water and stream sediments. The average As and Sb contents are 892 mg/kg and 818 mg/kg in soils, 195 mg/kg and 249 mg/kg in stream sediments, 0.028 mg/l and 0.021 mg/l in groundwater and 0.024 mg/l and 0.034 mg/l in surface water. Arsenic and Sb concentrations exceed upper permissible limits in locally grown vegetables. Within the epidemiological research the As and Sb contents in human tissues and fluids have been observed (blood, urine, nails and hair) in approximately one third of the village’s population (120 respondents). The average As and Sb concentrations were 16.3 μg/l and 3.8 μg/l in blood, 15.8 μg/l and 18.8 μg/l in urine, 3,179 μg/kg and 1,140 μg/kg in nails and 379 μg/kg and 357 μg/kg in hair. These concentrations are comparatively much higher than the average population. Health risk calculations for the ingestion of soil, water, and vegetables indicates a very high carcinogenic risk (>1/1,000) for as content in soil and water. The hazard quotient [HQ=average daily dose (ADD)/reference dose (RfD)] calculation method indicates a HQ>1 for groundwater As and Sb concentrations. 相似文献
106.
Márian Urban Rainer Thomas Vratislav Hurai Patrik Koneèný Martin Chovan 《Mineralium Deposita》2006,40(8):867-873
CO2 inclusions with density up to 1,197 kg m−3 occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO2 as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO2 phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km−1) and the CO2–CH4–N2 fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover. 相似文献
107.
Groundwater-flow modeling in the Yucatan karstic aquifer, Mexico 总被引:1,自引:0,他引:1
Roger González-Herrera Ismael Sánchez-y-Pinto José Gamboa-Vargas 《Hydrogeology Journal》2002,10(5):539-552
The current conceptual model of the unconfined karstic aquifer in the Yucatan Peninsula, Mexico, is that a fresh-water lens
floats above denser saline water that penetrates more than 40 km inland. The transmissivity of the aquifer is very high so
the hydraulic gradient is very low, ranging from 7–10 mm/km through most of the northern part of the peninsula. The computer
modeling program AQUIFER was used to investigate the regional groundwater flow in the aquifer. The karstified zone was modeled
using the assumption that it acts hydraulically similar to a granular, porous medium. As part of the calibration, the following
hypotheses were tested: (1) karstic features play an important role in the groundwater-flow system; (2) a ring or belt of
sinkholes in the area is a manifestation of a zone of high transmissivity that facilitates the channeling of groundwater toward
the Gulf of Mexico; and (3) the geologic features in the southern part of Yucatan influence the groundwater-flow system. The
model shows that the Sierrita de Ticul fault, in the southwestern part of the study area, acts as a flow barrier and head
values decline toward the northeast. The modeling also shows that the regional flow-system dynamics have not been altered
despite the large number of pumping wells because the volume of water pumped is small compared with the volume of recharge,
and the well-developed karst system of the region has a very high hydraulic conductivity.
Electronic Publication 相似文献
108.
Victor Pinto Xavier Font Miquel Salgot Jose Tapias Tomas Mañá 《Environmental Geology》2002,41(5):495-503
One of the most important environmental impacts resulting from opencast mining, and especially quarries, is the visual impact. Evaluation of this impact considers two aspects: first, the area occupied by the quarry as seen by an observer from a specific place, and, second, the chromatic contrast existing between landscape and exploitation. In this study we develop a methodology to assess the chromatic impact in an objective and comparable form. To assess this impact we developed a method based on image analysis that allows us to obtain from a picture or image its equivalent as a function of chromatic impact, according to the sensibility of the human eye to different wavelengths. The methodology was applied to the Martinenca limestone quarry (Alcanar, Tarragona) and to Cerro Kori Kollo mine, La Joya district (Bolivia). 相似文献
109.
Several types of anhydrite-bearing rocks have been found in the amphibolite-facies metamorphosed rocks at the north-eastern margin of the Moldanubian Zone. Anhydrite either forms monomineralic bands up to 40 cm thick, or occurs in the form of disseminated grains in surrounding calc-silicate gneiss together with feldspar, scapolite, amphibole, pyroxene, epidote and pyrite. The isotopic composition of sulphur ('34S=30.6 to 32.3) and strontium (87Sr/86Sr=0.70797 to 0.70781) in anhydrite may indicate a marine source of sulphate. The isotopic ratio of strontium is in the same range as that of metamorphosed strata-bound barite-sulphide ores, which have been previously described in the same area. The '34S values of coexisting pyrite range from 21.4 to 22.5, the (34Sanhydrite-pyrite corresponding to the metamorphic temperature of 600 to 660 °C. In contrast to many submarine-exhalative deposits, the oxygen isotopic compositions of anhydrite ('18O=9.3 to 10.2) are lighter than that of barite ('18O=10.4 to 13.8). This indicates that the both minerals are not in isotopic equilibrium. Therefore, it is probable that anhydrite and barite from the Roná district were deposited from fluids that contained different proportions of seawater and hydrothermal fluids or from hydrothermal fluids that underwent variable extent of oxygen isotope exchange with seafloor rocks. The '13C values in calcite ('13C=-17.2 to -18.7) from anhydrite-bearing rock are lower than those in distant marbles. As graphite is absent in anhydrite- and calcite-bearing rocks, impoverishment in the 13C isotope cannot be attributed to the graphite-carbonate isotopic exchange during metamorphism. It is proposed that low '13C values in carbonates are caused by pre-metamorphic oxidation of organic matter in course of hydrothermal processes. Anhydrite and anhydrite-bearing calc-silicate gneiss from the north-eastern part of the Moldanubian Zone are interpreted to be the high-grade metamorphosed analogue of anhydrite-rich exhalites commonly found in submarine-exhalative hydrothermal deposits. 相似文献
110.
Pilar Drake Alberto M. Arias Francisco Baldó José A. Cuesta Antonio Rodríguez Alfonso Silva-Garcia Ignacio Sobrino Diego García-González Carlos Fernández-Delgado 《Estuaries and Coasts》2002,25(3):451-468
The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary. 相似文献