Activated release of alkalis during the vesiculation of molten basalts under high vacuum: implications for lunar volcanism

Knudsen cell-quadrupole mass spectrometry was used to study the high-temperature vaporization of Hawaiian basalts, plagioclase, tektites, and samples from the Allende meteorite. Procedures are described by which mass loss rates and vapor pressures of Na and K were measured quantitatively.Gas-rich glassy basalts were observed to vesiculate under vacuum over the 900–1000°C region and simultaneously evaporate alkalis in nonequilibrium fashion at rates (units of μg/g/hr) of approximately 200–300 Na and 75–250 K. Degassed residues of the same basalts demonstrated equilibrium evaporation rates (over the same temperature range) of 60–120 Na and 30–60 K. The gas-deficient plagioclase and tektite sample showed only equilibrium vaporization with rates of 60 Na, 10 K (plagioclase) and 10 Na, 5K (tektites) at 900–1000°C. The Allende meteorite vaporized at rates of 2400 Na and 200 K at 900–1000°C, possibly by the reaction of Na₂O and K₂O with C or S₂, or by the thermal decomposition of nepheline or sodalite.The nonequilibrium vaporization of alkalis from the gas-rich basalts is attributed to vigorous agitation of the melt during its vesiculation by a gas phase composed principally of SO₂, CO₂, H₂O, CO, and H₂S. The major gases released from the Allende meteorite at 900–1000°C are, in order of decreasing abundance, CO, S₂, CO₂, H₂O, SO₂, and H₂S.It is proposed that nonequilibrium vaporization of alkalis during the vesiculation of lunar lavas was responsible for the production of alkali-rich vapors which subsequently deposited plagioclase crystals in the vugs of lunar rocks. The vesiculative, nonequilibrium vaporization of Na and K during a lunar volcanic eruption should be expected to occur at a high rate upon initial extrusion of the lava into vacuum but then decrease by a factor of approximately three when degassing is nearing completion. Vaporization losses remain inadequate to explain the uniformly low alkali concentrations in lunar basalts.     

Variations in Gegenschein polarization

Our observations of small scale angular structure and night-to-night variation of the polarized component of the zodiacal light near the anti-solar point have been criticized. We find that these criticisms are unsubstantiated.     

Coherent amplification and pulsar phenomena

A modification of the rotating-star model has been developed to interpret the periodic energy bursts from pulsars. This new configuration involves -directed oscilltion modes in the stellar atmosphere or magnetosphere, and most aspects of the typical pulse characteristics are well accounted for. Gain is provided by resonant interactions with particles trapped in the stellar magnetic field. The most significant feature is the fact that highly directional beaming of the output energy results as a natural consequence of coherence between the radiation fields emerging from various locations about the pulsar; and a localized radiation origin is not required.     

Pregalactic nucleosynthesis

We discuss the behavior of density fluctuations in an expanding universe and show that these should lead to the early formation of pregalactic hydrogen-helium stars of several hundred to several thousand solar masses. These stars flood the universe with radiation having a color temperature ≳10⁵ K; this terminates star formation but permits galaxy formation to continue. About 10⁻² of the mass of the galaxies is converted into heavy elements by pregalactic nucleosynthesis, with an error factor of a few.     

Solar particle propagation from 1 to 5 AU

A statistical analysis of solar particle events, observed by the GSFC-UNH charged particle detector on board Pioneer 10 and Pioneer 11 from March 1972 to December 1974 (from 1 to 5 AU for each spacecraft), is carried out with the goal of experimentally determining the statistical average interplanetary propagation conditions from 3 to 30 MeV. A numerical propagation model is developed that includes diffusion with a diffusion coefficient of the form k _r =k _o r , convection, adiabatic deceleration, and a variable coronal injection profile. The statistical analysis is carried out by individually analyzing each of five parameters (t _max, (t_max), t ₅, ) that are uniquely defined in a solar particle event. Each of the five parameter data sets were analyzed in terms of both a spacecraft-solar flare connection longitude 50°, and a numerical model that employed a variable exponential decaying coronal injection profile.The five individual parameter analyses are combined with the results that the statistical average radial interplanetary diffusion coefficient from 1 to 5 AU is given by k _r = (1.2 ± 0.4) × 10²¹ cm² s^-1 with = 0.0± 0.3 for 3.4 to 5.2 MeV protons and k _r = (2.6 ± 0.6) × 10²¹ cm² s^-1 with () = 0.0± 0.3 for 24 to 30 MeV protons. Using the classical relationship for the radial scattering mean free path _r, i.e. k _r = _r/3, we obtain _r = 0.09 ± 0.03 AU and 0.075 ± 0.020 AU for the low and high energy data, respectively. These results show, from 1 to 5 AU and from 3 to 30 MeV, that _r is both independent of radial distance and approximately independent of rigidity (for _r~P , where P = rigidity, = -0.15 ± 0.20).The above diffusion coefficients are inconsistent With both the predictions of the diffusion coefficient from present theoretical transport models and with the diffusion coefficient used in modulation studies at low energies.     

A pictorial comparison of interplanetary magnetic field polarity,solar wind speed,and geomagnetic disturbance index during the sunspot cycle

Observations of interplanetary magnetic field polarity, solar wind speed, and geomagnetic disturbance index (C9) during the years 1962–1975 are compared in a 27-day pictorial format that emphasizes their associated variations during the sunspot cycle. This display accentuates graphically several recently reported features of solar wind streams including the fact that the streams were faster, wider, and longer-lived during 1962–1964 and 1973–1975 in the declining phase of the sunspot cycle than during intervening years (Bame et al., 1976; Gosling et al., 1976). The display reveals strikingly that these high-speed streams were associated with the major, recurrent patterns of geomagnetic activity that are characteristic of the declining phase of the sunspot cycle. Finally, the display shows that during 1962–1975 the association between long-lived solar wind streams and recurrent geomagnetic disturbances was modulated by the annual variation (Burch, 1973) of the response of the geomagnetic field to solar wind conditions. The phase of this annual variation depends on the polarity of the interplanetary magnetic field in the sense that negative sectors of the interplanetary field have their greatest geomagnetic effect in northern hemisphere spring, and positive sectors have their greatest effect in the fall. During 1965–1972 when the solar wind streams were relatively slow (500 km s^-1), the annual variation strongly influenced the visibility of the corresponding geomagnetic disturbance patterns.Visiting Scientist, Kitt Peak National Observatory, Tucson, Arizona.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

Magnetic properties of x-ray bright points

Using high resolution KPNO magnetograms and sequences of simultaneous S-054 soft X-ray solar images we have compared the properties of X-ray bright points (XBP) and ephemeral active regions (ER). All XBP appear on the magnetograms as bipolar features, except for very newly emerged or old and decayed XBP. We find that the separation of the magnetic bipoles increases with the age of the XBP, with an average emergence growth rate of 2.2 ± 0.4 km s^–1. The total magnetic flux in a typical XBP living about 8 hr is found to be 2 x 10¹⁹ Mx. A proportionality is found between XBP lifetime and total magnetic flux, equivalent to 10²⁰ Mx per day of lifetime.Operated by the Association of Universities for Research in Astronomy, Inc. under contract with the National Science Foundation.     

Secular brightness increases of Titan,Uranus, and Neptune, 1972–1976

The brightnesses of Titan, Uranus, and Neptune in b (4718 ÅA) and y (5508 ÅA) have increased linearly since 1972 at rates ranging from 0.005 to 0.025 mag yr^?1. The observations were made differentially on a number of nights each season with respect to a network of comparison stars whose relative magnitudes were determined by independent measurements. Solar phase coefficients were derived for each object, and all observations have been normalized to zero solar phase angle and mean heliocentric distances. No explanation for the changes has been found, but a possible influence of solar activity upon planetary albedo is suggested by the fact that all of the objects observed have brightened during the declining half of the solar cycle.     

High spectral resolution ground-based observations of Venus in the 450- to 1250-cm−1 region

Ground-based observations of Venus were made with a 5-cm drive Michelson interferometer during December 1970 and December 1973. The thermal emission spectrum of the central portion of the apparent disk was recorded from 450–1250 cm^?1 with an apodized spectral resolution of 0.25 cm^?1. All statistically significant sharp line absorption features in the spectrum have been identified with gaseous CO₂. Comparison between the observed spectrum and a synthetic spectrum computed from a model atmosphere, assuming gaseous CO₂ and a sulfuric acid haze as opacity sources, indicates good agreement. A broad diffuse absorption feature associated with the sulfuric acid haze is evident in the 870- to 930 cm^?1 region. With the exception of the rotational lines of the 927-cm^?1 CO₂ band, the above feature appears as a continuum down to 0.25 cm^?1 resolution. In the 750- to 1250-cm^?1 range, the spectrum exhibits moderate thermal contrast with maximum brightness temperatures of 234–238°K occurring near 825 cm^?1. These temperatures are in general agreement with previous measurements.     

The Jovian surface condition and cooling rate

A theory which is almost fully analytic is used to investigate Jupiter's cooling rate. We find that a simple model of contraction with adiabatic interior structure gives a total cooling time to the present which is in good agreement with the age of the solar system. The interplay between the surface condition and the cooling rate is exhibited and discussed. The current rate of change of the effective temperature is calculated to be ?1°K/0.145×10⁹ yr. Discrepancies with fully numerical investigations of the Jovian age and cooling rate are noted.