Data quality in applied geochemistry: the requirements, and how to achieve them

To obtain a reliable interpretation of geochemical data, we need to ensure that the measurements are of sufficiently high quality. To do this we need to be able to specify quantitatively the data quality that we need, and then to be certain that we are getting it. The latter can be achieved only if properly validated analytical methods are employed, and well-designed quality control schemes are used as a matter of routine.     

Paleorainfall Reconstructions from Pedogenic Magnetic Susceptibility Variations in the Chinese Loess and Paleosols

The rock magnetic properties of the Chinese loess and paleosols constitute a unique and sensitive record of East Asian paleoclimate through the Quaternary Period. Systematic variations in the concentration and grain size of the magnetic minerals in these sediments have produced systematic variations in the magnetic susceptibility signal, which can be easily and rapidly measured at many sites across the Loess Plateau. Variations in many other rock magnetic properties can be used to identify the key shifts in ferrimagnetic grain size, but magnetic susceptibility alone is sufficiently sensitive to record stadial and interstadial climate stages, as well as glaciations and interglaciations. Past changes in rainfall and monsoon activity for this region are reconstructed from the susceptibility variations. The susceptibility record is calibrated using the modern relationship between rainfall and pedogenic susceptibility on the Loess Plateau. Our rainfall reconstructions identify enhanced summer monsoonal activity in the Chinese Loess Plateau region in the early Holocene and the last interglaciation. In the presently semiarid western area of the plateau, annual precipitation in interglacial times was up to 80% higher than at present; in the more humid southern and eastern areas, values were up to 20% higher than today's levels. During the last glaciation, precipitation decreased across the entire plateau, typically by 25%. The relationship between pedogenic susceptibility, climate, and weathering age was examined over the Northern Hemisphere temperate zone and the observed positive correlation between rainfall and susceptibility indicates that climate, rather than soil age, is the predominant factor that controls pedogenic susceptibility enhancement in loess soils.     

Late Quaternary Vegetation and Climate of the Wind River Range, Wyoming

Sediments from Rapid Lake document glacial and vegetation history in the Temple Lake valley of the Wind River Range, Wyoming over the past 11,000 to 12,000 yr. Radiocarbon age determinations on basal detrital organic matter from Rapid Lake (11,770 ± 710 yr B.P.) and Temple Lake (11,400 ± 630 yr B.P.) bracket the age of the Temple Lake moraine, suggesting that the moraine formed in the late Pleistocene. This terminal Pleistocene readvance may be represented at lower elevations by the expansion of forest into intermontane basins 12,000 to 10,000 yr B.P. Vegetation in the Wind River Range responded to changing environmental conditions at the end of the Pleistocene. Following deglaciation, alpine tundra in the Temple Lake valley was replaced by a Pinus albicaulis parkland by about 11,300 ¹⁴C yr B.P. Picea and Abies, established by 10,600 14C yr B.P., grew with Pinus albicaulis in a mixed conifer forest at and up to 100 m above Rapid Lake for most of the Holocene. Middle Holocene summer temperatures were about 1.5°C warmer than today. By about 5400 ¹⁴C yr B.P. Pinus albicaulis and Abies became less prominent at upper treeline because of decreased winter snowpack and higher maximum summer temperatures. The position of the modern treeline was established by 3000 ¹⁴ C yr B.P. when Picea retreated downslope in response to Neoglacial cooling.     

One-atmosphere melting behaviour and nomenclature of terrestrial lavas

On a plot of MgO against one-atmosphere liquidus almost all published data for lavas delineate a single trend, which is fairly well-defined above 1160° C. Segments of this trend form a convenient set of major classificatory subdivisions of lavas. It appears to be hard to justify the use of the term basalt for lavas with less than 6 percent MgO. Even with this restriction, basaltic aphanites occupy a substantial thermal (1150 to 1250° C one-atmosphere liquidi) and chemical (e.g. 6 to 11 percent MgO) range, which might profitably be subdivided. Finally, it is shown that the one-atmosphere liquidus thermal range occupied by the strongly alkalic sodic and potassic lavas is as wide as that covered by the entire set of basaltic volcanic suites from picrites and ankaramites to rhyolites, trachytes and phonolites.Presented at the symposium Recent Advances in the Studies of Rocks and Minerals at High Pressures and Temperatures held in Montreal, 1972. Jointly sponsored by the International Mineralogical Association and the Commission on Experimental Petrology.     

Mineral zones and isograds in “impure” calcareous rocks,an alternative means of evaluating metamorphic grade

Although regional mineral zoning in pelitic rocks has been described in numerous metamorphic terrains, relatively little is known about zoning in carbonate-bearing rocks. Regional metamorphism has resulted in a distinctive sequence of mineral zones in calcareous rocks (containing Fe, K and Al) of the Lessard Formation in the Bishop Corners-Madoc area, Grenville Province, Canada. The variation in metamorphic grade represented by the mineral zoning is attributed to a gradient in physical conditions (mainly temperature) at the time of metamorphism.In areas where pelitic schist and siliceous dolomite marble are rare or restricted in distribution, the mineral zones and isograds in impure calcareous rocks provide an alternative to conventional isograds for evaluating variations in metamorphic grade. In a metamorphic terrain where all three rock types occur, comparison of these isograds to those in pelitic and siliceous dolomite rocks results in a more accurate assessment of the distribution of isotherms and may provide some insight into the properties of the metamorphic fluid phase.     

Multi-wavelength observations of the onset phase of a coronal mass ejection

The structure and dynamics of the initial phases of a coronal mass ejection (CME) seen in soft X-ray, extreme ultraviolet and optical emission are described. The event occurred on the SW limb of the Sun in active region AR 8026 on 9 April 1997. Just prior to the CME there was a class C1.5 flare. Images taken with the Extreme Ultraviolet Imaging Telescope (EIT) reveal the emergence of a candle-flame shaped extreme ultraviolet (EUV) cavity at the time of the flare. Yohkoh images, taken about 15 min later, show that this cavity is filled with hot X-ray emitting gas. It is most likely that this is the site of the flare. Almost simultaneous to the flare, an H surge or small filament eruption occurs about 50 arc sec northwards along the limb from the EUV cavity. At both the site of the core of the hot, EUV cavity and the filament ejection are X-ray jets. These jets seem to be connected by hot loops near their bases. Both jets disappear within a few minutes of one another.Clear evidence of the CME first appeared in the Large Angle Spectrometric Coronagraph (LASCO) and EIT images 40 min after the flare and onset of the filament ejection. It seems to come from a region between the two X-ray jets. This leads to the speculation that magnetic field reconnection near one footpoint of a loop system triggers reconnection near its other footpoint. The loop system is destabilized and ultimately gives rise to the CME. This possibility is supported by magnetic field and H images taken when the active region was at disk center which show that the active region had a double bipole structure with dark H filaments between the bipoles.     

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.     

Radar determination of the spatial structure of hydraulic conductivity

Spatial variability of hydraulic conductivity exerts a predominant control on the flow of fluid through porous media. Heterogeneities influence advective pathways, hydrodynamic dispersion, and density-dependent dispersion; they are, therefore, a key concern for studies of ground water resource development, contaminant transport, and reservoir engineering. Ground-penetrating radar contributes to the remote, geophysical characterization of the macroscale variability of natural porous media. On a controlled excavation of a glacial-fluvial sand and gravel deposit in the Fanshawe Delta area (Ontario, Canada), the hydraulic conductivity field of a 45 x 3 m vertical exposure was characterized using constant-head permeameter measurements performed on undisturbed horizontal sediment cores. Ground-penetrating radar data were collected along the excavation face in the form of both reflection and common midpoint surveys. Comparison of geostatistical analyses of the permeameter measurements and the radar data suggests thatthe horizontal correlation structure of radar stack velocity can be used to directly infer the horizontal correlation structure of hydraulic conductivity. The averaging nature of the common midpoint survey is manifest in the vertical correlation structure of stack velocity, making it less useful. Radar reflection data do not exhibit a spatial structure similar to that of hydraulic conductivity possibly because reflections are a result of material property contrasts rather than the material properties themselves.