Detailed mineralogical-geochemical study of a large spinel Lherzolite xenolith in alkali basalt of Shavaryn Tsaram paleovolcano,Mongolia

Mineralogical-geochemical data obtained on a large xenolith of spinel lherzolite from basanites of Shavaryn Tsaram volcano (Middle Pleistocene) provide evidence that the xenolith was affected by heat and fluid that came from the basalt melt and induced geochemical heterogeneity of the xenolith. Olivine crystals from the central portion of the xenolith contain much more CaO than this mineral from the peripheral zones of the xenolith as well as in xenocrystals of the host basalts. The large xenolith was unevenly annealed by the host basalt melt, and this predetermined the heterogeneous diffusion-controlled “purification” of olivine crystals from their CaO admixture. The xenolith is heterogeneously enriched in LREE and some trace elements (Zr, Hf, Nb, Th, and U), and their distribution demonstrates unclearly pronounced concentric zoning: these elements enriched the outer portions of the xenolith. The enrichment of the xenolith in LREE and other mobile trace elements is explained by their occurrence not only as structurally bound (isomorphic) components in minerals but also in the form of nonstructural admixtures (contaminant), as minute grains of compounds hosted in the interstitial space and tiny cracks cutting mineral grains. The enrichment of the xenolith in these admixtures proceeded via their infiltration-controlled introduction with fluid from the basalt along minute cracks.     

Low-amplitude, synsedimentary folding of a deltaic complex: Roda Sandstone (lower Eocene), South-Pyrenean Foreland Basin

The South‐Pyrenean Foreland Basin is a sedimentary trough developed during Palaeogene times in response Pyrenean orogenesis. The structural development of the chain progressively involved the foreland basin deposits resulting in synsedimentary thrusting and growth of folds through the basin. The lower Eocene Roda Sandstone was deposited in a shallow‐marine environment whose topography (bathymetry) was modified by a series of growing gentle folds. This synsedimentary folding is evidenced in the field (i) thickening of sedimentary units above synclinal structures and thinning over anticlines; (ii) carbonate platform deposits growing on top of anticlines; (iii) the areal distribution of benthic foraminifera in transgressive facies assemblages determined by an irregular, fold‐influenced palaeobathymetry; (iv) variation of sandstone palaeocurrents related to the presence of a sedimentary trough formed by the synsedimentary growth of a syncline. In addition, synsedimentary folding has been evidenced from seismic data. In the Roda Sandstone example, the growth of gentle folds occurred in an area with high sedimentation rates (～0.21 ± 0.06 mm y^?1). Due to the high sedimentation rates, exceeding the folds uplift rate (～0.10 ± 0.01 mm y^?1), there are no noticeable unconformities in the growth strata at outcrop scale. However, the effects on the sedimentation are very significant, because the sediments were deposited close to sea level, and thus were very sensitive to fauna and facies distribution.     

Native aluminium (spherules and particles) in the Central Indian Basin sediments: Implications on the occurrence of hydrothermal events

We have sampled particles of native aluminium (Al°) in two sediment cores from the Central Indian Basin (CIB). The cores are geographically separated but are located at the base of two seamounts. The native Al° particles occurring as grains and spherules, have an average Al content of  95% and are associated with volcanogenic–hydrothermal material. Morphologically and compositionally, the specimens are similar to those reported from the East Pacific Rise. After ruling out several processes for the presence of the native Al°, we hypothesize that during progressive melting of magma, a basaltic magma is produced which has high contents of reductants such as methane and hydrogen, and a low oxygen fugacity. During the upward migration of such magma, reduction to metallic aluminium and the formation of native Al° particles takes place.     

Detection of free gas and gas hydrate based on 3D seismic data and cone penetration testing: An example from the Nigerian Continental Slope

We present a new method to characterize free gas, gas hydrates and carbonate concretions occurrence which are considered as high-risk factors for sub-sea developments in the Niger delta. This method is based on the combination of 3D seismic data to the geotechnical site characterizations using piezocone CPTU tests (Cone Penetration Test with additional measurement of the pore water pressure). A special processing of the 3D seismic data has enabled the determination of the interval compressional velocity. Using the effective-medium theory, velocity anomalies (negative and positive) within the first 15 m were translated in gas hydrate and free gas distribution. The calibration of the P wave velocity anomalies was done thanks to in-situ geotechnical testing carried out during two oceanographic surveys (2003 and 2004). Comparison between in-situ testing, recovered cores and the prediction of the gas and the gas hydrate distribution based on the compressional wave velocity have shown that 3D seismic data is a valuable tool to identify heterogeneous areas but the use of the piezocone was essential to discriminate between gas hydrate occurrences and carbonate concretions' presence. Furthermore, in-situ compressional wave velocity (V_p) measurements have clearly demonstrated what it was suspected from the 3D seismic data, the co-existence in the study area between gas hydrate and free gas.     

Model estimates for the mean gas exchange between the ocean and the atmosphere under the conditions of the present-day climate and its changes expected in the 21st century

Annual mean fluxes of CO₂ and oxygen across the sea surface are estimated with the use of numerical modeling for several regions located in the Gulf Stream and Kuroshio zones. The present-day climatic conditions and the climatic conditions expected in the middle and at the end of the 21st century are considered. Specific features of gas exchange under a strong wind that are associated with gas exchange by bubbles and with changes in the air-water difference of the gas concentrations were taken into account in the calculations. The estimates obtained differ substantially from the results based on the traditional approach, which disregards the above features. A considerable increase in the absorption of CO₂ by the ocean, which is mainly caused by the continuing increase in the CO₂ concentration in the air during its small changes in the ocean, is expected in the 21st century. At the same time, no trends are revealed in the annual mean fluxes of oxygen across the ocean surface. The conclusion is made that, in calculations of CO₂ absorption by the world ocean, it is necessary to take into account both specific features of gas transfer under a strong wind and an increase in the atmospheric concentration of CO₂.     

Record-breaking chemical destruction of ozone in the arctic during the winter of 2004/2005

The extremely cold winter of 2004/2005 was accompanied by an intensive formation of polar stratospheric clouds and a significant chemical destruction of ozone. The results of calculating chemical losses of ozone in the polar cyclone from the SAGE-III satellite data are given. Over the period January 1–March 25, 2005, at the isentropic levels 450–500 K, about 60% of ozone was destroyed. During that winter, the zone of formation of polar stratospheric clouds went down to levels with very low values of potential temperature (down to 350 K), thus resulting in a noticeable destruction of ozone at low altitudes. By March 25, 2005, the chemical losses of total ozone attained 116 ± 10 DU (128 ± 10 DU at the cyclone boundary), which is a recordbreaking value of the Arctic.     

Numerical simulation of a quasi-tropical cyclone over the Black Sea

The paper describes results of numerical experiments on the simulation of a mesoscale quasi-tropical cyclone, a rare event for the Black Sea, with the MM5 regional atmospheric circulation model. General characteristics of the cyclone and its evolution and physical formation mechanisms are discussed. The balances of the momentum components have been estimated, and sensitivity experiments have been performed. It is shown that, according to its main physical properties and energy supply mechanisms, the cyclone can be related to quasi-tropical cyclones.     

Analysis of correlations between time series with the use of the phase spectrum

In connection with the problem of revealing cause-effect relations among different climatic characteristics, methods for determining the dependence between time series on the basis of selected auto-and cross-covariance functions and periodograms expressed in terms of the Fourier coefficients of the initial series are discussed. Real time series do not always satisfy the conditions of statistical stationarity, so that their analysis requires a combination of statistical and deterministic approaches. The possibility of using the above numerical characteristics in relation to such series is considered. Characteristic features of describing finite segments of time series with the use of their Fourier coefficients is studied in detail. The main emphasis is on the determination of the time shifts (delays) at which the covariance between the series is maximal. The problems that appear during a practical implementation of the periodogram method for shift estimation are discussed. A previously unknown formula that is necessary for further studies and relates the Fourier transform of a selected correlation function to the periodogram of the series is derived.     

Agglutinated abyssal foraminifers of the equatorial pacific

The quantitative study of the distribution and taxonomic composition of recent living and dead (without plasma) benthic foraminifers revealed three foraminiferal assemblages in the bottom sediments of the Pacific Ocean at depths of 3350 to 4981 m. The assemblage dominated by the epibenthic Lagenammina difflugiformis, Reophax dentaliniformis, and Saccorhiza ramosa occupies the slopes of underwater hills. The assemblage with a high share of the infaunal Cribrostomoides subglobosum, C. nitidum, and Ammobaculites agglutinans is registered on the abyssal plateau. The assemblage with a significant proportion of the large Astrorhiza and Reophax species, which are characterized by an active way of life, populates gentle slopes and narrow depressions with potentially strong bottom currents.     

Constraining the origin and evolution of confined turbidite systems: southern Cretan margin,Eastern Mediterranean Sea (34°30–36°N)

Bathymetric, 9.5-kHz long-range sidescan sonar (OKEAN), seismic reflection and sediment-core data are used in the analysis of two tectonic troughs south of Crete, Eastern Mediterranean Sea. Here, up to 1.2 s two-way travel time (TWTT) of strata have accumulated since the Middle Miocene in association with extension in the South Aegean region. The study area comprises >100-km- long by >25-km-wide basins filled by sediments subdivided into two seismic units: (1) an upper Unit 1 deposited in sub-basins which follow the present-day configuration of the southern Cretan margin; (2) a basal Unit 2, more than 500 ms (TWTT) thick, accumulated in deeper half-graben/grabens distinct from the present-day depocentres. Both units overlap a locally stratified Unit 3 comprising the pre-Neogene core complex of Crete and Gavdos. In this work, the interpreted seismic units are correlated with the onshore stratigraphy, demonstrating that denudation processes occurring on Crete and Gavdos in response to major tectonic events have been responsible for high sedimentation rates along the proximal southern Cretan margin. Consequently, topographically confined sedimentary units have been deposited south of Crete in the last 12 Ma, including turbidites and other mass-flow deposits fed by evolving transverse and axial channel systems. Surface processes controlling facies distribution include the direct inflow of sediment from alluvial-fan systems and incising mountain rivers onto the Cretan slope, where significant sediment instability processes occur at present. In this setting, seismic profiles reveal eight different types of stratigraphic contacts on basin-margin highs, and basinal areas show evidence of halokinesis and/or fluid escape. The acquired data also show that significant changes to the margin’s configuration occurred in association with the post-Alpine tectonic and eustatic episodes affecting the Eastern Mediterranean.