New data on geology of the Shatak Complex (western slope of the Southern Urals)

The comprehensive study of sections of the Shatak Complex has revealed that conglomerates at the base of Middle Riphean rocks are not basal but intraformational rocks. Previously described angular unconformities between shales of the Sukhin Subformation (Yusha Formation, R₁) and conglomerates of the Kuz”elga Subformation (Mashak Formation, R₂) are related to late tectonic movements. Magmatic rocks developed at the base of the Middle Riphean section are represented by sheet intrusions formed in the course of emplacement of a fluid-saturated magmatic melt into partially or completely lithified terrigenous rocks at the graben formation stage during the origination of synkinematic faults that served as magma conduits. It is inferred that distribution of provenances of clastic materials and sedimentation basins in the Burzyanian and Yurmatian should be scrutinized in the study region, because the normal regressive sequence of rocks from the uppermost Yusha Formation to the lowermost Mashak Formation, which was established in the Shatak Ridge, eliminates a clear boundary distinguished between them at present. The idea about an older age of the Mashak conglomerates is substantiated.     

Archean high-Mg monzodiorite–syenite,epidote skarn,and biotite–sericite gold lodes in the Granny Smith–Wallaby district,Australia: U–Pb and Re–Os chronometry of two intrusion-related hydrothermal systems

The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie, in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia. At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma, cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km) thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite + calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series, high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + Fe_TOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO₂ metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid. At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid released by the source pluton of the differentiated alkali granite dikes.     

Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Some types of small clinoforms in latest continental deposits

Some rare types of small clinoforms found in the latest continental deposits of lowland platform and mountain regions are described. The clinoforms are represented by prodelta deposits of mountain lakes, oblique-bedded horizons of floodplain alluvium of strongly meandering rivers, thick and short lenses of mountain alluvium, and alluvium horizons of great lowland rivers with oblique bedding grading into horizontal bedding. Such structures bear information on paleogeographic, morphological, and lithodynamic features of continental sedimentation.     

Age and depositional environment of the Draa Sfar massive sulfide deposit, Morocco

The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints.     

Age estimates of coastal terraces in the Andaman and Nicobar Islands and their tectonic implications

The great Indian Ocean earthquake of December 26, 2004 caused significant vertical changes in its rupture zone. About 800 km of the rupture is along the Andaman and Nicobar Islands, which forms the outer arc ridge of the subduction zone. Coseismic deformation along the exposed land could be observed as uplift/subsidence. Here we analyze the morphological features along the coast of the Andaman and Nicobar Islands, in an effort to reconstruct the past tectonics, taking cues from the coseismic effects. We obtained radiocarbon dates from coastal terraces of the island belt and used them to compute uplift rates, which vary from 1.33 mm yr^− 1 in the Little Andaman to 2.80 mm yr^− 1 in South Andaman and 2.45 mm yr^− 1 in the North Andaman. Our radiocarbon dates converge on  600 yr and  1000 yr old coastal uplifts, which we attribute to the level changes due to two major previous subduction earthquakes in the region.     

Detrital zircon provenance of Neoproterozoic to Cenozoic deposits in Iran: Implications for chronostratigraphy and collisional tectonics

Ion-microprobe U–Pb analyses of 589 detrital zircon grains from 14 sandstones of the Alborz mountains, Zagros mountains, and central Iranian plateau provide an initial framework for understanding the Neoproterozoic to Cenozoic provenance history of Iran. The results place improved chronological constraints on the age of earliest sediment accumulation during Neoproterozoic–Cambrian time, the timing of the Mesozoic Iran–Eurasia collision and Cenozoic Arabia–Eurasia collision, and the contribution of various sediment sources of Gondwanan and Eurasian affinity during opening and closure of the Paleotethys and Neotethys oceans. The zircon age populations suggest that deposition of the extensive ~ 1 km-thick clastic sequence at the base of the cover succession commenced in latest Neoproterozoic and terminated by Middle Cambrian time. Comparison of the geochronological data with detrital zircon ages for northern Gondwana reveals that sediment principally derived from the East African orogen covered a vast region encompassing northern Africa and the Middle East. Although most previous studies propose a simple passive-margin setting for Paleozoic Iran, detrital zircon age spectra indicate Late Devonian–Early Permian and Cambrian–Ordovician magmatism. These data suggest that Iran was affiliated with Eurasian magmatic arcs or that rift-related magmatic activity during opening of Paleotethys and Neotethys was more pronounced than thought along the northern Gondwanan passive-margin. For a Triassic–Jurassic clastic overlap assemblage (Shemshak Formation) in the Alborz mountains, U–Pb zircon ages provide chronostratigraphic age control requiring collision of Iran with Eurasia by late Carnian–early Norian time (220–210 Ma). Finally, Cenozoic strata yield abundant zircons of Eocene age, consistent with derivation from arc magmatic rocks related to late-stage subduction and/or breakoff of the Neotethys slab. Together with the timing of foreland basin sedimentation in the Zagros, these detrital zircon ages help bracket the onset of the Arabia–Eurasia collision in Iran between middle Eocene and late Oligocene time.     

Changes of deformational and reservoir properties of arenaceous-argillaceous rocks due to operation of underground gas storage facilities

This paper discusses issues of the decline of the reservoir properties of arenaceous-argillaceous rocks as a result of declining porosity due to long-term operation of underground gas storage facilities. An analysis of the many-year operation of storage facilities, as well as calculation, has revealed that the active capacity of a storage reservoir gradually decreases under certain conditions of underground storage operations. We performed a series of experiments with model specimens in order to support the hypothesis of decreasing reservoir (capacity-filtration) properties because of changes in the value and structure of the pore space. These experiments showed that the cyclic loading and unloading of arenaceous-silty rocks during long-term operation of underground gas storage facilities can significantly decrease the reservoir parameters of reservoirs created within worked out gas-and-gas condensate fields. Laboratory studies of model specimens corresponding to feldspar sandstone in their composition, porosity, and strength proved that porosity considerably decreases in such reservoirs at actually existing values of formation pressure. Tests of sand performed under conditions close to those existing during the development of hydrocarbon fields also showed that their permeability gradually decreases in the process of cyclic changes of effective pressure.     

Mineralogy and composition of Kuroko deposits from northeastern Honshu and their possible modern analogues from the Izu-Ogasawara (Bonin) Arc south of Japan: Implications for mode of formation

The Kuroko deposits of NE Honshu are a key type deposit for the study of volcanogenic massive sulfide deposits. However, these deposits have not been studied in detail since the early 1980's and knowledge of their mode of formation is now dated. In this study, we present the analysis of 12 samples of the Kuroko deposits, 12 samples of submarine hydrothermal minerals from the Sunrise deposit and 6 samples from Suiyo Seamount, both of which are located on the Izu-Ogasawara (Bonin) Arc, for 27 elements. For the Kuroko deposit, Cd>Sb>Ag>Pb>Hg>As>Zn>Cu are highly enriched, Au>Te>Bi>Ba>Mo are moderately enriched, In>Tl are somewhat enriched and Fe is not significantly enriched relative to the average continental crust. Within each of these deposits, a similar pattern of element associations is apparent: Zn–Pb with As, Sb, Cd, Ag, Hg, Tl and Au; Fe–Cu–Ba with As, Sb, Ag, Tl, Mo, Te and Au; Si–Ba with Ag and Au; CaSO₄. The enrichment of the chalcophilic elements in these deposits is consistent with hydrothermal leaching of these elements from the host rocks which are dominantly rhyolite–dacite in the case of the Kuroko deposits, rhyolite in the case of the Sunrise deposit and dacite–rhyolite in the case of the Suiyo Seamount deposit. However, this pattern of element enrichment is also similar to that observed in fumarolic gas condensates from andesitic volcanoes. This suggests that there may be a significant magmatic contribution to the composition of the hydrothermal fluids responsible for the formation of the Kuroko deposits, although it is not yet possible to quantify the relative contributions of these two sources of elements.The compositional data show that Sunrise and Suiyo Seamount deposits are much closer compositionally to the Kuroko deposits from NE Honshu than are the submarine hydrothermal deposits from the JADE site in the Okinawa Trough which contain, on average, significantly higher concentrations of Pb, Zn, Sb, As and Ag than each of these deposits. In spite of the greater similarity in tectonic setting of the Hokuroku Basin in which the Kuroko deposits formed to the Okinawa Trough (intracontinental rifted back-arc basin) compared to Myojin Knoll and Suiyo Seamount (active arc volcanoes), it appears that submarine hydrothermal deposits from Myojin Knoll and Suiyo Seamount are closer analogues of the Kuroko deposit than are those from the Okinawa Trough. The present data are consistent with the magmatic hydrothermal model for the formation of Kuroko-type deposits as formulated by Urabe and Marumo [Urabe, T., Marumo, K., 1991. A new model for Kuroko-type deposits of Japan. Episodes 14, 246–251].     

Seismic hazard assessment of Chennai city considering local site effects

Chennai city suffered moderate tremors during the 2001 Bhuj and Pondicherry earthquakes and the 2004 Sumatra earthquake. After the Bhuj earthquake, Indian Standard IS: 1893 was revised and Chennai city was upgraded from zone II to zone III which leads to a substantial increase of the design ground motion parameters. Therefore, a comprehensive study is carried out to assess the seismic hazard of Chennai city based on a deterministic approach. The seismicity and seismotectonic details within a 100 km radius of the study area have been considered. The one-dimensional ground response analysis was carried out for 38 representative sites by the equivalent linear method using the SHAKE91 program to estimate the ground motion parameters considering the local site effects. The shear wave velocity profile was inferred from the corrected blow counts and it was verified with the Multichannel Analysis of Surface Wave (MASW) test performed for a representative site. The seismic hazard is represented in terms of characteristic site period and Spectral Acceleration Ratio (SAR) contours for the entire city. It is found that structures with low natural period undergo significant amplification mostly in the central and southern parts of Chennai city due to the presence of deep soil sites with clayey or sandy deposits and the remaining parts undergo marginal amplification.