Spectrophotometric pH measurement in estuaries using thymol blue and m-cresol purple

The conditional acid dissociation constants (pK_a′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pK_a′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln⁻¹):

The estimated accuracy of pH measurements using these calculated pK_a′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.     

Reduction of sand demand for shore protection

Beach nourishment is an environmentally preferred method of shore protection, but the annual sand requirement may lead to substantial maintenance costs. The shoreline processes, involving the surf zone, beach and dune, are reviewed with the aim of reducing the annual sand requirement of eroding shorelines. It is shown that surf zones with equilibrium profiles, on which the wave energy conversion is evenly distributed across the surf zone, from experience for given conditions indicate least loss of sand. On steep, eroding shorelines it may be difficult to establish an equilibrium profile. For such cases, the use of perched surf zones is recommended, which are supported at the seaward limit by an underwater sill. For reduction of littoral transport, the use of pervious pile groynes is recommended. These are arguably more efficient than impervious groynes. The sand loss from a usually dry beach by raised water levels is shown to be a function of the beach slope and is least when the storm waves at raised water levels do not cut an erosion escarpment. The loss of sand from a dune by infrequent severe storm tides can be prevented with the aid of a built-in membrane. These sand losses are usually large and constitute an uneconomic use of this sand resource. The proposed concepts and measures are linked to existing knowledge, augmented by data from the large wave flume (LWF) in Germany and field data from the North and Baltic Sea coasts.     

The mineralogy and provenance of deep-sea sediments recovered by gravity corer off Sierra Leone,West Africa

The mineralogy of eight gravity cores recovered between Sierra Leone and 25°W longitude has been examined in an investigation of the provenance of the recent sediments in the eastern Equatorial Atlantic. X-ray analyses show that the principal mineral components are calcite, quartz, feldspar, kaolinite, illite and montmorillonite. One core taken from the upper continental slope off Freetown also contains gibbsite, a product of intense tropical weathering. Biogenic material forms the dominant component of most sections of the cores but it is clear from the abundance of quartz, kaolinite and freshwater diatoms that an aeolian supply of continental detritus has been important in the formation of the recent sediment cover. A significant contribution from volcanic sources can be recognised to the west of the Sierra Leone Rise. The occurrence of calcareous turbidites in two cores from the St. Paul's Fracture Zone and from the basin west of the Sierra Leone Rise appears to be a reflection of recent tectonic activity.     

An overview and general results of the Lopez island OBS experiment

The purpose of the experiment was to determine the effects of coupling and bottom currents on ocean bottom seismometers. Twelve operational OBSs, three specially designed three-component systems, and a hydrophone were compared with each other. Unlike seismometers placed on hard rock at land stations, ocean bottom seismometers can be affected by soft sediments (which act as lossy mechanical springs) and by buoyancy. Coupling through soft sediments can modify the response to ground motion much as a low pass filter does, and high buoyancy tends to counteract this effect. These effects are observed in the Lopez data, which consist of signals from mechanical transient tests, cap shots, airgun pulses, and general background noise. The modification of response is pronounced for some instruments and barely noticeable in others. Instruments that stand high in the water relative to their base width tend to be susceptible to rocking motion that shows up as a mechanical cross coupling between horizontal and vertical motion. Correlation of Lopez results with coupling theory suggests that it is possible to design ocean bottom seismometers that will couple well to any sediment. Current levels at the Lopez site (<5 cm s^-1) were too small to produce noticeable effect on any of the instruments; however, the same design criteria that will minimize coupling problems will also lessen problems caused by ocean currents.Hawaii Institute of Geophysics Contribution No. 1171.     

Topography and a magnetic analysis of an area south-east of the Azores (36°N, 23°W)

A detailed survey of a 1°×1°-square of seafloor 100 miles south-east of the Azores shows a strong correlation between directions of regional topographic and magnetic lineations. The area is dissected by the East Azores Fracture Zone at 36°55N, identified as the active Eurasian-African plate boundary, and by another large, non-active fracture zone at 36°10N. Both fracture zones strike 265° and are accompanied by large amplitude magnetic anomalies. The general strike in the area in between is 000°–015°. The skewing effect at this magnetic latitude is very sensitive to variations in strike of the magnetic contrasts. This effect was eliminated by a non-linear transformation which also gives the positions of magnetic contrasts. Some N-S contrasts were identified as sea floor spreading polarity contrasts (anomalies 31 and 32). Weak contrasts could be identified as topographic effects and gave a magnetization intensity of 5 A m^-1. The identified sea floor spreading anomalies to both sides of the fracture zone at 36°10N agree very well, also quantatively, with a three-dimensional model for the fracture zone anomalies. This model describes the non-linear anomalies as end effects of the magnetic layer which is divided in blocks of alternating polarity.     

Radium and lead-210 in marine barite

Measurements of ²²⁶Ra and ²¹⁰Pb in barite samples separated from different depths of a piston core from the eastern equatorial Pacific are reported. ²²⁶Ra is enriched in the barite as would be expected from the chemistries of Ra and Ba; the ${}^{226}\text{Ra}\text{Ba}$ ratio centers around 1.5 · 10¹⁴ atoms/mole. The results suggest that barite is concentrating Ra at a rate comparable to its decay rate, viz. 5.78 · 10^?3 yr^?1. The gross ²¹⁰Pb depletion with respect to ²²⁶Ra is indicative of ²²²Rn loss due to the smallness of the barite crystals.     

Anatomy of a shore face ridge system,False Cape,Virginia

The Middle Atlantic Shelf of North America is a broad sand plain, characterized by a subdued ridge and swale topography. Some ridges extend into or merge with the shore face.     

Southern Segment of the European Geotraverse — a wide-angle seismic refraction experiment in the Sardinia Channel

The Sardinia Channel dataset was collected as part of the European Geotraverse (EGT)—a 4000 km seismic refraction line running from Northern Norway to the Sahara, designed to investigate the structure of the lithosphere beneath Europe. Wideangle seismic data recorded by ocean bottom seismometers deployed in the Sardinia Channel as part of the Southern Segment of the EGT, together with gravity data, were used to constrain the final crustal model. In the centre of the Channel the crust is identified as thinned continental in nature, with a crystalline thickness of 10 km overlain by 4 km of sediments and 2.5 km of water in the most extended region. High velocities in the lower crust in the central region are thought to represent an area of underplating or intrusion by igneous material caused by extension related to the opening of the Tyrrhenian Sea. The crust overlies an anomalously low velocity upper mantle.