Hydrogeochemical Characterization and Groundwater Quality of Jamshedpur Urban Agglomeration in Precambrian Terrain,Eastern India

This paper reports petrography, geochemistry and Rb-Sr age data on the rare metal bearing Neoarchean fertile (Nb-Ta) granite at Allapatna and elucidates its petrogenesis and role in Nb-Ta-Li-Be mineralization. The Allapatna granite (AG) intrudes the Tonalitic-Trondhjemitic - Granodioritic (TTG) Peninsular Gneiss and analysed SiO₂ (72.3-75.6 wt%), K₂O (4.0-5.7wt%), Na2O (3.0-4.4wt%), CaO (0.7-1wt%), MgO (0.13-0.25wt%) and K₂O/Na₂O (>1) indicating evolved nature. The presence of muscovite, biotite and garnet in the mode, peraluminous nature and high initial ⁸⁷Sr/⁸⁶Sr ratio (0.7284±0.0083) attest to their S-type characteristics. Varying Nb/Ta ratio and high Li with moderate abundance of Cs further indicate affinity to Li-Cs-Ta (LCT) type granite-pegmatite system. TheAG showing whole rock Rb-Sr isochron age of 2803± 68 Ma, is the oldest reported fertile granite in India parental to rare metal pegmatites hosting Nb-Ta, Be, and Li resources. Partial melting of a mixed source consisting of both basement TTG rocks and metapelites has generated such type of granitic magma. Fractionation of such granitic magma possibly has given rise to the rare metal (Ta-Nb-Li-Be) bearing pegmatites intruding the nearby schist belt.     

Rainfall flood hazard at nuclear power plants in India

Flood hazard evaluation is an important input for Nuclear Power Plants external events safety studies. In the present study, flood hazard at various nuclear sites in India due to rainfall has been evaluated. Hazard estimation is a statistical procedure by which rainfall intensity versus occurrence frequency is estimated from historical records of rainfall data and extrapolated with asymptotic extreme value distribution. Rainfall data needed for flood hazard assessment are daily annual maximum rainfall (24?h data). The observed data points have been fitted using Gumbel, power law and exponential distribution, and return period has been estimated. To study the stationarity of rainfall data, a moving window estimate of the parameters has been performed. The rainfall pattern is stationary in both coastal and inland regions over the period of observation. The coastal regions show intense rainfall and higher variability than inland regions. Based on the plant layout, catchment area and drainage capacity, the prototype fast breeder reactor (PFBR) site is unlikely to be flooded.     

Pedotransfer functions to estimate soil water content at field capacity and permanent wilting point in hot Arid Western India

Characterization of soil water retention, e.g., water content at field capacity (FC) and permanent wilting point (PWP) over a landscape plays a key role in efficient utilization of available scarce water resources in dry land agriculture; however, direct measurement thereof for multiple locations in the field is not always feasible. Therefore, pedotransfer functions (PTFs) were developed to estimate soil water retention at FC and PWP for dryland soils of India. A soil database available for Arid Western India (N=370) was used to develop PTFs. The developed PTFs were tested in two independent datasets from arid regions of India (N=36) and an arid region of USA (N=1789). While testing these PTFs using independent data from India, root mean square error (RMSE) was found to be 2.65 and 1.08 for FC and PWP, respectively, whereas for most of the tested ‘established’ PTFs, the RMSE was >3.41 and >1.15, respectively. Performance of the developed PTFs from the independent dataset from USA was comparable with estimates derived from ‘established’ PTFs. For wide applicability of the developed PTFs, a user-friendly soil moisture calculator was developed. The PTFs developed in this study may be quite useful to farmers for scheduling irrigation water as per soil type.     

Geology, petrography and geochemistry of rhyolite-hosted uranium mineralization at Mohar, Shivpuri district, Madhya Pradesh

In the westernmost part of the Bundelkhand Granitoid Complex (BGC), a mesa structure represents a unique outlier, surrounded by brecciated granite and filled with Vindhyan sedimentary rocks locally known as the Dhala Formation near Mohar village of Shivpuri district, Madhya Pradesh. Uranium mineralisation located in the area is mostly associated with rhyolite of peralkaline to peraluminous in nature, that has a high average uranium concentration (30 ppm). The mineralization is in or adjacent to caldera and is hydrothermal vein-type. Radioactivity is mainly due to coffinite with limited radioactivity due to U-Ti complex, uranium adsorbed in clay and labile uranium along fracture. Coffinite occurs in association with pyrite and chalcopyrite or chlorite with presence of fluorite. Features such as chloritisation, clay formation and sulfide mineralisation manifest hydrothermal alteration. Chemical analysis indicates the aluminous nature of the rock and their high K₂O/Na₂O (3.81–12.84) ratios are suggestive of predominance of potash feldspar over sodic. The alteration index varies from 49.88–92.40, which, reflects high intensity of hydrothermal alteration. Chlorite-carbonatepyrite index (CCPI), a measure of the intensity of replacement of sodic feldspars and glass by sericite, chlorite, carbonate, and pyrite associated with hydrothermal alteration proximal to the ore bodies varies from 3.84–49.66. On the basis of core study, geochemistry and mineralogy, it is envisaged that epigenetic hydrothermal solutions were responsible for concentration of uranium as coffinite, radioactive carbonaceous matter and adsorbed uranium phases in rhyolite with sulfide confined to weak planes.     

Reconstruction of specific mass balance for glaciers in Western Himalaya using seasonal sensitivity characteristic(s)

Seasonal sensitivity characteristics (SSCs) were developed for Naradu, Shaune Garang, Gor Garang and Gara glaciers, Western Himalaya to quantify the changes in mean specific mass balance using monthly temperature and precipitation perturbations. The temperature sensitivities were observed high during summer (April–October) and precipitation sensitivities during winter months (November–March), respectively. The reconstructed mass balance correlates well with the field and remote sensing measurements, available between 1980 and 2014. Further, SSCs were used with the monthly mean temperatures and precipitation estimates of ERA 20CM ensemble climate reanalysis datasets to reconstruct the specific mass balance for a period of 110 years, between 1900 and 2010. Mass balance estimates suggest that the Shaune Garang, Gor-Garang and Gara glaciers have experienced both positive and negative mass balance, whereas the Naradu glacier has experienced only negative mass balance since 1900 AD. Further, a cumulative loss of \(-133 \pm 21.5\) m.w.e was estimated for four glaciers during the observation period. This study is the first record from Indian Himalaya in evaluating the mass balance characteristics over a century scale.     

Multiple episodes of tectonothermal processes in the Eastern Ghats granulite belt

A suite of rocks from Borra Carbonate Granulite Complex (BCGC) in the Eastern Ghats granulite belt displays superposed structures and overprinted mineral assemblages that reveal multiple episodes of tectonothermal reworking of the complex under granulite facies condition. Five distinct episodes of deformation (D₁, D₂, D₃, D₄ and D₅) and four phases of metamorphism (M₁, M₂, M₃ and M₄) are recorded. The signature of the earliest tectonothermal event, D₁ is a gneissic foliation (S₁) denned by segregation of peak granulite facies mineral assemblages corresponding to prograde M₁ metamorphism. M₂ metamorphic overprint represents an episode of near-isobaric cooling of the complex under a static condition. D₂ represents an episode of ductile deformation manifested by isoclinal folding (F₂) and associated extensional structures, within a broad framework of coaxial bulk deformation. The present study reveals that D₂ took place subsequent to M₂ - Subsequent deformation, D₃, produced F₃ folds and also deformations of boudins formed during D₂. M₃, which is synchronous with F₃, represents a near isothermal decompression of the BCGC. This was followed by a weak structural readjustment (D₄), producing E-W cross folds. The latter was not, however, associated with any recognizable petrological reworking. In the terminal events, deformation (D₅) and mineral reactions (M₄) were localized along narrow intersecting shear zones. The latter acted as channelways for carbonic and still later hydrous fluid infiltration. The available thermobarometric data from BCGC and other areas of the Eastern Ghats belt reveal that reworking during M₂ and M₃ ensued in a thermally perturbed regime. The high thermal regime might also have persisted during carbonic fluid infiltration related to terminal reworking (M₄).     

Static deformation of two welded half-spaces due to very long strike-slip dislocations

Closed form analytic expressions for displacement and stresses at any point of either of the two homogeneous, isotropic, perfectly elastic half-spaces in welded contact due to very long strike-slip dislocations are obtained. Both cases of vertical and horizontal strike-slip dislocations are discussed in detail. Variation of the displacement with horizontal distance from the fault and with vertical distance from the interface for a vertical strike-slip fault is studied numerically.     

Utilization of ochre as an adsorbent to remove Pb(II) and Cu(II) from contaminated aqueous media

The ability of ochre to remove Pb(II) and Cu(II) from aqueous media has been studied by batch sorption studies varying the contact time, initial metal concentration, initial solution pH and temperature to understand the adsorption behaviour of these metals through adsorption kinetics and isotherms. The pH of the solution and the temperature controlled the adsorption of metal ions by ochre and rapid uptake occurred in the first 30 min of reaction. The kinetics of adsorption followed a pseudo-second-order rate equation (R ² > 0.99) and the isotherms are well described by the Freundlich model. Adsorption of metals onto ochre is endothermic in nature. Between the two metals, Pb(II) showed more preference towards the exchangeable sites on ochre than Cu(II). This study indicates that ochre is a very effective adsorbent in removing Pb(II) and Cu(II) from the aqueous environment with an adsorptive capacity of 0.996 and 0.628 mg g^?1 and removal efficiency of 99.68 and 62.80 %, respectively.     

Analysing the spatio-temporal evolution of an active debris slide in Eastern Himalaya,India

Landslide is one of the prominent geohazards in the Himalayas where loss of lives and property are common. Owing to the complicated geomorphic and tectono-stratigraphic setting of this active Fold-thrust belt (FTB), landsliding of all possible types and spatial scales observed exhibit conspicuous spatio-temporal signatures and evolution. This evolution of landslides is commonly studied by regional assessment and by examining the multi-temporal landslide inventories of a particular area. The success of creating such multi-temporal landslide inventory depends on (i) the availability of relevant past source data (e.g., images, post event maps, air photos etc.) of suitable resolution, scale and quality, (ii) time of generation of source data with respect to the time of landsliding event, (iii) skill of the investigators in interpreting the old images, air photos etc. However, this method is of restricted use in studying the spatio-temporal evolution of a single landslide which is perennially active in the Himalayan terrain, where rapid changes in land use and land cover patterns readily obliterate the signatures of past landsliding. Moreover because of scale constraints, subtle and frequent changes in the spatial dimensions of these individual landslides, and their temporal activity become difficult to identify in such regional assessment carried out over a larger area. In this study therefore, a different approach is adopted whereby the spatio-temporal activity and style of Lanta Khola landslide, a perennially active and large (0.25 km²) debris flow in the Eastern Himalayas, has been studied in detail through detailed scale (1:1000) site-specific geological mapping in phases during the last 28 years (1983–2011). Such site-specific geological observations coupled with numerical slope stability analysis utilising the limit equilibrium method facilitate in detailed understanding of the temporal and spatial evolution and inherent mechanism of this perennial landslide.