Sr isotopic composition of Paleoproterozoic C-rich carbonate rocks: The Tulomozero Formation,SE Fennoscandian Shield

Rb–Sr systematics has been studied in ¹³C-rich carbonate rocks of the Paleoproterozoic (2.09 ± 0.07 Ga) Tulomozero Formation in the northern Onega Lake area, the SE Fennoscandian Shield. The formation is divided into eight members (A–F) consisting of greenschist-facies-grade, variegated sandstones, siltstones, mudstones, stromatolitic dolostones and subordinate crystalline limestones. Samples of carbonate rocks were obtained from two overlapping drillholes intersecting the entire thickness of the Tulomozero Formation. Prior to isotope analysis, the rocks powders were treated with 1N ammonium acetate for partial removal of the late epigenetic carbonate phases. Major resetting of the Rb–Sr systems in the Tulomozero carbonate rocks appears to take place during the Svecofennian regional metamorphic event, and it was screened by using Mn/Sr, Fe/Sr, Mg/Ca, and ¹⁸O/¹⁶O ratios. High Sr content (up to 2080 μg/g in limestones, and 530 μg/g in dolostones) coupled with low Fe/Mn (<0.40) ratios in the Tulomozero carbonate rocks of Members A, B (the lower part), D, F, and E are consistent with accumulation of original carbonate sediments in evaporitic lacustrine, playa, and sabkha environments. A decrease in the Sr content with concurrent increase in the Fe/Mn ratio (>0.40) in dolostones of the upper part of Member B, and of Members G and H is indicative of seawater influxes (sea transgression) into the Tulomozero basin. The ⁸⁷Sr/⁸⁶Sr values in the least altered (Mn/Sr < 2.0) marine dolostones are 0.70418–0.70442 and 0.70343–0.70409 for the earlier and late phases of the marine transgression, respectively. The decrease in the ⁸⁷Sr/⁸⁶Sr ratio in ca. 2.1 Ga seawater is attributable to an increase in hydrothermal flux Sr into the Palaeoproterozoic ocean.     

Pb-Pb age of sedimentary phosphorite reworking in Lower Riphean carbonate sediments,the Satka Formation of Southern Urals

The mineral composition and U-Pb and Rb-Sr systematics of phosphorites from the Satka Formation of Lower Riphean carbonates, the Burzyan Group of Southern Urals, are studied. Phosphorites occurring as small lenses between stromatolite layers are composed largely of fluorapatite with admixture of detrital quartz, feldspars, illite, and chlorite. Phosphorite samples have been subjected to stepwise dissolution in 1 N (fraction L-1) and 2 N (fraction L-2) HCl. As is established, the maximum apatite content is characteristic of fraction L-1, while fraction L-2 is enriched in products of dolomite and sulfide dissolution and in elements leached from siliciclastic components. The Sr content in the Satka apatites (280–560 ppm) is substantially lower as compared with that in unaltered marine apatite. The ⁸⁷Sr/⁸⁶Sr “initial ratio in the phosphorites studied (0.71705–0.72484) and host dolomites from the lower part of the Satka Formation is significantly higher than in the Early Riphean seawater that indicates a reset of the Rb-Sr original systems in sediments. The Pb-Pb age of 1340 ± 30 Ma (MSWD = 6.4) estimated based on 7 data points characterizing fractions L-1 and L-2 is younger than the formation time of overlying Burzyan sediments, being consistent, within the error range, with date of the Mashak rifting event recorded at the Early-Middle Riphean boundary. The comparative U-Pb characteristics of two soluble fractions (L-1 and L-2) and silicate residue of phosphorites show that epigenetic redistribution of Pb and U was characteristic of the phosphorite horizon only. The initial Pb isotope composition and μ (²³⁸U/²⁰⁴Pb) estimated according to model by Stacey and Kramers for the early diagenetic fluids in carbonate and phosphate sediments of the Satka Formation suggest that they were in isotopic equilibrium with erosion products of the Taratash crystalline complex.     

Territorial Development of Christianity in Africa in the 20<Superscript>th</Superscript>–Early 21<Superscript>st</Superscript> Centuries

The characteristic features of the transformation of the territorial geospace structure in the African Christianity religious geospace during 1910–2010 have been revealed. African countries within the boundaries of 2010 are used as territorial cells that have been fixed retrospectively over the course of the period analyzed. We used indicators, such as Ryabtsev’s index of relative structural shifts and the trajectory of the demographic center of the Christianity to assess changes in the inertia level of the territorial structure for the entire time interval as a whole and for each of the components of its 20-year long periods. It is found that to date the adherents of Christianity are extremely unevenly distributed in the countries of Africa; however, over the course of the period under consideration there was taking place a homogenization of their settlement. In accordance with changes of the values of the indicators used, we identified two development stages of geospace of African Christianity: colonial and post-colonial. It is determined that the colonial stage (1910–1970) is characterized by a “compression” of territorial structure from east and north, and by a predominance of the south-westward direction of movement of the demographic center because of a decrease in the proportion in the Christian population of East Africa first on account of Egypt and Ethiopia and Madagascar (1910–1930) and then North Africa on account of Egypt and Algeria (1930–1950). The territorial structure of Christianity’s geospace during the post-colonial stage is characterized by a higher degree of inertia at the background of the westward ”expansion” and the “compression” from the south as well as by a change of the vector of movement of the demographic center for north-westward.     

Mössbauer characteristics,mineralogy and isotopic age (Rb-Sr,K-Ar) of Upper Riphean glauconites from the UK Formation,the southern Urals

Comprehensive mineralogical analysis, Mössbauer spectroscopy and isotopic-geochronological study have been carried out for globular phyllosilicates (GPS) of glauconite group from the Uk Formation, the second one below the top of the Upper Riphean stratotype in the southern Urals. Glauconites have been sampled in the Kurtaza and Kulmas sections remote from each other in the Alatau anticlinorium that corresponds to western facies zone of the Bashkirian meganticlinorium. As is shown, size and density monomineral fractions of globules are represented by Al-glauconite according to established structural formula. The isotopic (Rb-Sr and K-Ar) dating of glauconites from the Uk Formation is performed for the first time along with computer simulation of cation arrangements in their crystal lattice and comparison of the results obtained with data of Mössbauer spectroscopy. It has been assumed by simulation that origin and transformation of the Rb-Sr and K-Ar systems in glauconite are concurrent to stages in structural evolution of this mineral, which have been controlled by geological and geochemical events in the history of sedimentary successions. The approach has been aimed at recognition of stratigraphically meaningful isotopic dates corresponding to the glauconite formation at the stage of the early diagenesis close to sedimentation time and the “rejuvenated” dates characterizing ages of subsequent geological events. The comparison of simulated cation arrangements with data of Mössbauer spectroscopy shows that the Rb-Sr (663 ± 9 Ma) and K-Ar (669 ± 16 Ma) dates established for glauconites correspond to the time of early diagenesis in their host sediments, being suitable for age assessment of the Uk Formation. The dates obtained are of interregional and wider significance, as they must be taken into consideration when constructing the general curve of Sr isotope variations in the Late Riphean oceans.     

Rb-Sr geochronology of Vendian shales,the Staraya Rechka Formation,Anabar Massif,northern Siberia

Fine-grained clayey subfractions (SF) with particle sizes of 1–2, 0.6–1.0, 0.3–0.6, 0.2–0.3, 0.1–0.2, and <0.1 μm were extracted from shales of the Vendian Staraya Rechka Formation in the Anabar Massif and studied by XRD and Rb-Sr methods. All the clayey subfractions are represented by illite with high crystallinity indices, which are characteristic of the low-temperature diagenesis/catagenesis zone and grow with the decrease of the particle size. The Rb-Sr systematics in clayey subfractions combined with mineralogical data provide grounds for the conclusion that illite from clayey rocks of the Staraya Rechka Formation was forming during two periods: approximately 560 and 391–413 Ma ago. The first illite generation was likely formed in the course of lithostatic subsidence of the Staraya Rechka sediments and the second one, during the Devonian lithogenesis stage. It is assumed that age of the first generation (∼560 Ma) is close to that of the Staraya Rechka Formation. This inference is consistent with biostratigraphic, chemostratigraphic, and geochronological data obtained for both rocks of the Anabar Massif and Vendian sediments from other regions of Siberia.     

Mineralogy,Mossbauer Characteristics,and K-Ar Isotopic Age of Glauconite from the Lower Cambrian Sediments,Western Lithuania

The paper presents results of lithological-mineralogical, Mossbauer, and isotope-geochronological study of globular phyllosilicates (glauconite and illite) from the Lower Cambrian Virbalis Formation in western Lithuania. K-Ar dates of these minerals (382 and 374 Ma) do not correspond to stratigraphic positions of the studied samples and indicate the loss of radiogenic ⁴⁰Ar, probably, in Middle Devonian. Simulation of cation distribution in the mineral structure and comparison of the obtained data with Mossbauer spectral characteristics suggest that loss of ⁴⁰Ar was caused by the structural rearrangement of globular phyllosilicates during the postdiagenetic substitution of Fe²⁺, Mg²⁺, and Fe³⁺ by Al³⁺, with the subsequent ordering of cation distribution in octahedral layers. These processes were presumably related to the same Caledonian tectonic events that were responsible for metasomatic dolomitization of Lower Paleozoic rocks in adjacent areas of the Baltic region at the terminal Silurian-Devonian. Diffraction analysis showed that globules consist of two micaceous phases with different Fe contents (illite and glauconite). Two alternative models are considered to explain the formation of two-phase globules: (1) disequilibrium conditions of diagenetic mineral formation; (2) transformation of glauconite into illite. Although the available data are insufficient to make an unambiguous choice between these models, the second mechanism seems to be more preferable.__________Translated from Litologiya i Poleznye Iskopaemye, No. 4, 2005, pp. 403–415.Original Russian Text Copyright © 2005 by Zaitseva, Gorokhov, Ivanovskaya, Zvyagina, Mel’nikov, Yakovleva.     

Mineralogical,Mössbauer,and Isotopic–Geochronological Study of Upper Riphean Al-glauconites,Kil'din Group,Srednii Peninsula

The paper presents mineralogical, crystallochemical, and Rb–Sr age data on globular layer silicates of the glauconitic series from lower horizons of the Upper Riphean Kil'din Group, Srednii Peninsula. Chloritization significantly changed the globular Al-glauconite in sandstones of the Päräjarvinskaya Formation. However, it almost did not affect glauconite globules in sandstones of the Palvinskaya Formation and altered only clayey component of the rock. Mössbauer spectroscopy showed that Al-glauconite in the Palvinskaya Formation was affected by secondary transformations, which caused the Fe²⁺ oxidation in octahedral sheets and loss of radiogenic ⁸⁷Sr. The transformations were presumably related to exhumation of rocks of the Päräjarvinskaya and Palvinskaya formations to the circulation level of the oxygen-rich meteoric waters. Thus, Rb–Sr datings obtained for Al-glauconites of the Palvinskaya (781–786 Ma) and Päräjarvinskaya(744–751 Ma) formations correspond to the tectonic uplift of Kil'din rocks and have no stratigraphic significance.     

The state of the aquatic environment and biota during operation of trout-breeding pond farms

The paper presents the results of studying chemical and biological quality characteristics of the aquatic environment in the area of operation of trout farms in Kondopoga Bay, Onega Lake. The concentrations of biochemically labile substances and phosphorus were found to increase near the ponds. The development dynamics of phytoplankton, zooplankton, and benthic organisms in the zone of pond farms. When the procedure of fish production is strictly followed, the effect of ponds on the aquatic environment and biota is minimal.     

Rb-Sr and U-Pb systematics of metasedimentary carbonate rocks: The Paleoproterozoic Kuetsjarvi Formation of the Pechenga Greenstone Belt, Kola Peninsula

The Rb-Sr and U-Pb systematics have been studied in the metasedimentary carbonate rocks from the Paleoproterozoic Kuetsjarvi Formation. Samples were taken from the borehole drilled in the northern zone of the Pechenga Greenstone Belt in the northwestern Kola Peninsula. The carbonate section of the formation is made up of three units (from the bottom to top): (I) dolomite (68 m), (II) calcareous-dolomite (9 m), and (III) clayey calcareous (1 m) ones. Dolomites (Mg/Ca = 0.55–0.61) from the lowermost unit I contain 70.3–111 ppm Sr. Initial ⁸⁷Sr/⁸⁶Sr ratio in them varies within 0.70560–0.70623 and characterizes the primary continental-lacustrine carbonate sediments. Calcareous dolomites (Mg/Ca = 0.39–0.59) and dolomitic limestones of units II and III (Mg/Ca = 0.02–0.36) are enriched in Sr (285–745 and 550–1750 ppm, respectively). Initial ⁸⁷Sr/⁸⁶Sr ratios in these rocks (0.70406–0.70486 and 0.70407–0.70431, respectively) fall within the range typical of the Jatulian seawater, which indicates that the carbonate sediments of two upper units were formed in an open marine basin. Study of dolomites from unit I showed that the Svecofennian metamorphism more significantly affected the U-Pb systems of carbonate rocks as compared to their Rb-Sr systems. In the ²⁰⁷Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb diagram, most data points corresponding to the carbonate constituent of dolomites define isochron with an age of 1900 ± 25 Ma (MSWD = 0.5). The same samples define a positive correlation in the ²⁰⁸Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb plot. Since sedimentary carbonates usually do not contain Th, this correlation points to secondary enrichment of the studied dolomites in Th or thorogenic ²⁰⁸Pb. Hence, the obtained Pb-Pb dating can be regarded as the age of the Svecofennian metamorphic event. Three samples from dolomites of unit I lack any disturbance of the initial U-Th-Pb systematics, but their trend in the ²⁰⁷Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb diagram deviates from the 1900 Ma isochron. Based on these samples, the model U-Pb premetamorphic age of the Kuetsjarvi carbonate sediments is 2075–2100 Ma. This interval is consistent with the age range of the Lomagundi-Jatulian event, which was responsible for the formation of carbonate sediments with high positive δ¹³C values.