Saturn's latitudinal C2H2 and C2H6 abundance profiles from Cassini/CIRS and ground-based observations

Hydrocarbons in the upper atmosphere of Saturn are known, from Voyager, ground-based, and early Cassini results, to vary in emission intensity with latitude. Of particular interest is the marked increase in hydrocarbon line intensity near the south pole during southern summer, as the increased line intensity cannot be simply explained by the increased temperatures observed in that region since the variations between C₂H₂ and C₂H₆ emission in the south pole region are different. In order to measure the latitudinal variations of hydrocarbons in Saturn's southern hemisphere we have used 3 cm⁻¹ resolution Cassini CIRS data from 2006 and combined this with measurements from the ground in October 2006 at NASA's IRTF using Celeste, an infrared high-resolution cryogenic grating spectrometer. These two data sets have been used to infer the molecular abundances of C₂H₂ and C₂H₆ across the southern hemisphere in the 1-10 mbar altitude region. We find that the latitudinal acetylene profile follows the yearly average mean daily insolation except at the southern pole where it peaks in abundance. Near the equator (5° S) the C₂H₂ abundance at the 1.2 mbar level is (1.6±0.19)×¹⁰−7 and it decreases by a factor of 2.7 from the equator toward the pole. However, at the pole (∼87° S) the C₂H₂ abundance jumps to (1.8±0.3)×¹⁰−7, approximately the equatorial value. The C₂H₆ abundance near the equator at the 2 mbar level is (0.7±0.1)×¹⁰−5 and stays approximately constant until mid-latitudes where it increases gradually toward the pole, attaining a value of (1.4±0.4)×¹⁰−5 there. The increase in ethane toward the pole with the corresponding decrease in acetylene is consistent with southern hemisphere meridional winds [Greathouse, T.K., Lacy, J.H., Bézard, B., Moses, J.I., Griffith, C.A., Richter, M.J., 2005. Icarus 177, 18-31]. The localized increase in acetylene at the pole provides evidence that there is dynamical transport of hydrocarbons from the equator to the southern pole.     

Dense planetary rings and the viscous overstability

This paper examines the onset of the viscous overstability in dense particulate rings. First, we formulate a dense gas kinetic theory that is applicable to the saturnian system. Our model is essentially that of Araki and Tremaine [Araki, S., Tremaine, S., 1986. Icarus 65, 83-109], which we show can be both simplified and generalised. Second, we put this model to work computing the equilibrium properties of dense planetary rings, which we subsequently compare with the results of N-body simulations, namely those of Salo [Salo, H., 1991. Icarus 90, 254-270]. Finally, we present the linear stability analyses of these equilibrium states, and derive criteria for the onset of viscous overstability in the self-gravitating and non-self-gravitating cases. These are framed in terms of particle size, orbital frequency, optical depth, and the parameters of the collision law. Our results compare favourably with the simulations of Salo et al. [Salo, H., Schmidt, J., Spahn, F., 2001. Icarus 153, 295-315]. The accuracy and practicality of the continuum model we develop encourages its general use in future investigations of nonlinear phenomena.     

Using an approximation of the three-point Gauss–Hermite quadrature formula for model prediction and quantification of uncertainty

 Computer models are commonly used by regulators and managers to make predictions regarding groundwater flow and contaminant concentrations at various locations and times. However, the uncertainty associated with those predictions is often overlooked, despite the fact that an assessment of such uncertainty is critical in the formulation of policy decisions. One method of quantifying the uncertainty of model predictions, based on the collective uncertainties of the model parameter input values, is to use an approximation of the three-point Gauss–Hermite quadrature formula. The Gauss–Hermite approximation is a convenient substitute for simple Monte Carlo sampling, because it requires fewer model runs and provides an immediate sensitivity analysis of parameter main effects and two-way interactions. For example, a model with four parameters, each with its own associated uncertainty, needs to be run only 33 times to complete the Gauss–Hermite analysis. For an application to a contaminant-transport model, the Gauss–Hermite approximation compares well to the full method, with considerable savings in computing effort. By comparison, Latin hypercube sampling can be more flexible, but it is more complex to use in some circumstances and cannot as easily generate the detailed sensitivity analysis that the Gauss–Hermite approach offers. Received, October 1997 Revised, August 1998 Accepted, August 1998     

Book reviews

THE CAPITALIST SPACE ECONOMY: Geographical Analysis after Ricardo, Marx and Sraffa by E. Sheppard and T. J. Barnes. 15 × 22 cm, xviii and 328 pages. Unwin Hyman: London 1990 (ISBN 004 330401 X) £40.00 hard; (ISBN 004 330402 8) £14.95 (soft).

THE INTERNATIONAL STEEL INDUSTRY: Restructuring, State Policies and Localities by R. Hudson and D. Sadler. 14 × 22 cm, xii and 163 pages. Routledge: London 1989 (ISBN 0 415 02186 3) $A89.95 (hard).

INDUSTRIAL TRANSFORMATION AND CHALLENGE IN AUSTRALIA AND CANADA (Carleton Library No. 164) edited by R. Hayter and P. D. White. 15 × 23 cm, x and 340 pages. Carleton University Press: Ottawa 1990 (ISBN 0 88629 129 1) $A34.95 (hard); (ISBN 0 88629 128 3) $A 19.95 (soft).

LABOUR MIGRATION. The Internal Geographical Mobility of Labour in the Developed World edited by J. H. Johnson and J. Salt. 15 × 24 cm, viii and 215 pages. David Fulton: London 1990 (ISBN 1 85346 120 2) £30.00 (hard).

CITIES IN SPACE: CITY AS PLACE by D. Herbert and C. Thomas. 15 × 23 cm, xi and 340 pages. David Fulton: London 1990 (ISBN 1 85346 138 5) £35.00 (hard); (ISBN 1 85346 109 1) £14.95 (soft).

THE NEW URBAN FRONTIER. Urbanisation and City Building in Australasia and the American West by L. Frost. 15 × 23 cm, xvii and 226 pages. New South Wales University Press: Sydney (ISBN 0 86840 268 0) $A24.95 (soft).

SYDNEY: A Social Atlas by R. Horvath, G. E. Harrison and R. M. Dowling. 19 × 28 cm, 110 pages. Sydney University Press: Sydney 1989 (ISBN 0 424 00144 6) $A19.95 (soft).

CHANGE AND ADJUSTMENT IN NORTHERN NEW SOUTH WALES edited by D. J. Walmsley. 17 × 23 cm. 118 pages. Department of Geography and Planning, University of New England: Armidale 1990 (ISBN 0 85834 887 X) $A10.00 (soft).

ANNOTATED BIBLIOGRAPHY OF URANIUM IN AUSTRALIA (Cover Title: URANIUM IN AUSTRALIA 1970–1987: An Annotated Bibliography) by C. O'Faircheallaigh, A. Webb and D. Wade‐Marshall. 18 × 25 cm, xi and 306 pages. North Australia Research Unit, Australian National University: Darwin 1989 (ISBN 07315 05433).     

X-ray absorption fine structure study of As(V) and Se(IV) sorption complexes on hydrous Mn oxides

X-ray absorption fine structure (XAFS) spectroscopic analysis at the As, Se, and Mn K-edges was used to study arsenate [As(V)O₄³⁻] and selenite [Se(IV)O₃²⁻] sorption complexes on the synthetic hydrous manganese oxides (HMOs) vernadite (δ-MnO₂) and K-birnessite (nominal composition: K₄Mn₁₄O₂₇ · 9H₂O). No significant changes were observed in sorption complex structure as a function of sorbent, pH (5 to 8), surface coverage (0.04 to 0.73 μmol/m²), or reaction time (5 to 22 h) in the arsenate or selenite systems. In the arsenate/HMO system, extended XAFS parameters indicate an average second-neighbor As(V) coordination of 2.0 ± 0.4 Mn at an average distance of 3.16 ± 0.01 Å, which is consistent with formation of As(V)O₄ sorption complexes sharing corners with two adjacent Mn(IV)O₆ surface species (i.e., bidentate, binuclear). In the selenite/HMO system, selenite surface complexes are surrounded by two shells of Mn atoms, which could represent two different adsorption complexes or a precipitate. The first shell consists of 1.6 ± 0.4 Mn at 3.07 ± 0.01 Å, which is consistent with the selenite anion forming bidentate (mononuclear) edge-sharing complexes with Mn(II)O₆ or Mn(III)O₆ octahedra. The second shell consists of 1.4 ± 0.4 Mn at 3.49 ± 0.03 Å, consistent with selenite forming monodentate, corner-sharing complexes with Mn(II)O₆ or Mn(III)O₆ octahedra. Pauling bond valence analysis that uses the extended XAFS-derived bond lengths for As(V)-O, Se(IV)-O, and Mn-O bonds indicates that the proposed surface complexes of selenite and arsenate on HMOs should be stable. Although a nearly identical Se(IV) coordination environment is found in a crystalline Mn(II)-Se(IV) precipitate (which has a structure similar to that of MnSeO₃ · H₂O), there are significant differences in the X-ray absorption near-edge structure and extended XAFS spectra of this precipitate and the selenite/HMO sorption samples. These differences coupled with transmission electron microscopy results suggest that if a precipitate is present it lacks long-range order characteristic of crystalline MnSeO₃ · H₂O.     

Devonshire marbles: history of the industry and the geology of these classic British ornamental stones

Devonshire ‘marbles’ come from Mid– to Late Devonian limestones of south Devon, UK. They are not true marbles in the geological sense but were nonetheless tectonically buried during the Variscan orogenesis. They retain abundant palaeontological and sedimentological characters, overstamped by limited to extensive veining, deformation and brecciation. Recent work has revealed how these marbles have been used to decorate a wealth of buildings in Britain and overseas. There were two distinct industries, one that produced decorative marble for architectural use, and one that produced portable artefacts such as specimen marble tables and ornaments. The stones used in these two sister industries can be very different, a result of different sourcing of the same Devonshire limestones. A third industry sought to slice and polish local limestone pebbles to reveal their diverse coral, stromatoporoid and other fossil contents, and was aimed at tourists, collectors and museums. The history and early development of the marble industry are explored and the distinct characteristics of the stones used in Devonshire marble inlay are explained. The stones used in the parallel architectural trade are analysed elsewhere.     

Predicting landscape sensitivity to present and future floods in the Pacific Northwest,USA

Floods are the most frequent natural disaster, causing more loss of life and property than any other in the USA. Floods also strongly influence the structure and function of watersheds, stream channels, and aquatic ecosystems. The Pacific Northwest is particularly vulnerable to climatically driven changes in flood frequency and magnitude, because snowpacks that strongly influence flood generation are near the freezing point and thus sensitive to small changes in temperature. To improve predictions of future flooding potential and inform strategies to adapt to these changes, we mapped the sensitivity of landscapes to changes in peak flows due to climate warming across Oregon and Washington. We first developed principal component‐based models for predicting peak flows across a range of recurrence intervals (2‐, 10‐, 25‐, 50‐, and 100‐years) based on historical instantaneous peak flow data from 1000 gauged watersheds in Oregon and Washington. Key predictors of peak flows included drainage area and principal component scores for climate, land cover, soil, and topographic metrics. We then used these regression models to predict future peak flows by perturbing the climate variables based on future climate projections (2020s, 2040s, and 2080s) for the A1B emission scenario. For each recurrence interval, peak flow sensitivities were computed as the ratio of future to current peak flow magnitudes. Our analysis suggests that temperature‐induced changes in snowpack dynamics will result in large (>30–40%) increases in peak flow magnitude in some areas, principally the Cascades, Olympics, and Blue Mountains and parts of the western edge of the Rocky Mountains. Flood generation processes in lower elevation areas are less likely to be affected, but some of these areas may be impacted by floodwaters from upstream. These results can assist land, water, and infrastructure managers in identifying watersheds and resources that are particularly vulnerable to increased peak flows and developing plans to increase their resilience. Copyright © 2015 John Wiley & Sons, Ltd.     

Simplified DMT-based methods for evaluating liquefaction resistance of soils

This paper presents simplified dilatometer test (DMT)-based methods for evaluation of liquefaction resistance of soils, which is expressed in terms of cyclic resistance ratio (CRR). Two DMT parameters, horizontal stress index (K_D) and dilatometer modulus (E_D), are used as an index for assessing liquefaction resistance of soils. Specifically, CRR–K_D and CRR–E_D boundary curves are established based on the existing boundary curves that have already been developed based on standard penetration test (SPT) and cone penetration test (CPT). One key element in the development of CRR–K_D and CRR–E_D boundary curves is the correlations between K_D (or E_D) and the blow count (N) in the SPT or cone tip resistance (q_c) from the CPT. In this study, these correlations are established through regression analysis of the test results of SPT, CPT, and DMT conducted side-by-side at each of five sites selected. The validity of the developed CRR–K_D and CRR–E_D curves for evaluating liquefaction resistance is examined with published liquefaction case histories. The results of the study show that the developed DMT-based models are quite promising as a tool for evaluating liquefaction resistance of soils.     

Holocene sedimentation history of the major fan valleys of Monterey fan

There are three major fan valleys on upper Monterey fan. Deep-tow geophysical profiles and 40 sediment cores provide the basis for evaluation of the sedimentation histories of these valleys. Monterey fan valley leads from Monterey canyon to a major suprafan and is bounded by levees that crest more than 400 m above the valley floor. The valley passes through a large z-bend or meander. Monterey East fan valley joins Monterey fan valley at the meander at about 150 m above the valley floor, and marks an earlier position of the lower Monterey fan valley. Ascension valley, a hanging contributary to the Monterey fan valley, appears to have once been the shoreward head of the lower part of the present Monterey fan valley. The relief of Monterey fan valley appears from deep-tow profiles to be erosional. The valley is floored with sand. Holocene turbidity currents do not overtop the levees 400 m above the valley floor, but do at times overflow and transport sand into Monterey East valley, producing a sandy floor. An 1100 m by 300 m dune field was observed on side scan sonar in Monterey East valley.Ascension fan valley was floored with sand during glacial intervals of lowered sea level, then was cut off from its sand source as sea level rose. A narrow (500 m), erosional, meandering channel was incised into the flat valley floor; the relief features otherwise appear depositional, with a hummocky topography perhaps produced in the manner of a braided riverbed. The sand is mantled by about 6 m of probable Holocene mud. Hummocky relief on the back side of the northwestern levees of both Ascension and Monterey valleys is characteristic of many turbidite valleys in the northeast Pacific. The hummocky topography is produced by dune-like features that migrate toward levee crests during growth.     

Estimates using fluorescence spectroscopy of the present state of petroleum hydrocarbon contamination in the water column of the northwest Atlantic Ocean

Concentrations of petroleum hydrocarbons in seawater from the general region between Nova Scotia and Bermuda were estimated using fluorescence spectroscopy. Concentrations in surface water (0–3 mm) averaged 20.4 μg/l, and in water from 1 and 5 m they averaged 0.8 and 0.4 μg/l respectively. No significant concentrations could be detected in deeper water. There was considerable variability in the concentrations suggesting that the distribution of oil in seawater is quite patchy, especially in surface waters. Seawater samples for hydrocarbon analysis cannot be collected with conventional sampling equipment. Due to adsorption problems, the inner surface of samplers must come into contact only with the water being sampled and must be rinsed with organic solvent after samples are removed. Because these precautions were not taken in previous investigations, much of the published data of hydrocarbons in seawater is unreliable.