Proposal for an International Molybdenum Isotope Measurement Standard and Data Representation

Molybdenum isotopes are increasingly widely applied in Earth Sciences. They are primarily used to investigate the oxygenation of Earth's ocean and atmosphere. However, more and more fields of application are being developed, such as magmatic and hydrothermal processes, planetary sciences or the tracking of environmental pollution. Here, we present a proposal for a unifying presentation of Mo isotope ratios in the studies of mass‐dependent isotope fractionation. We suggest that the δ^98/95Mo of the NIST SRM 3134 be defined as +0.25‰. The rationale is that the vast majority of published data are presented relative to reference materials that are similar, but not identical, and that are all slightly lighter than NIST SRM 3134. Our proposed data presentation allows a direct first‐order comparison of almost all old data with future work while referring to an international measurement standard. In particular, canonical δ^98/95Mo values such as +2.3‰ for seawater and ?0.7‰ for marine Fe–Mn precipitates can be kept for discussion. As recent publications show that the ocean molybdenum isotope signature is homogeneous, the IAPSO ocean water standard or any other open ocean water sample is suggested as a secondary measurement standard, with a defined δ^98/95Mo value of +2.34 ± 0.10‰ (2s).     

Trouble with Sense of Place in Working Landscapes

The sense of place (SOP) conceptual framework offers theoretical and empirical evidence that links peoples’ multifaceted connections to place(s) to their engagement in pro-environmental and conservation behaviors. The bulk of this research has focused on peoples’ connection to high-amenity places and landscapes. Recent research applies SOP in working landscapes—however, these studies encounter “troubles” that include measurement challenges and mixed results in predicting statistical relationships with conservation outcome variables. As authors of some of these studies, we propose three opportunities and corresponding survey items for developing meaningful SOP measures in future working landscapes research: (1) modify existing SOP dimensions and items to better capture the working landscape dynamics; (2) address how scale may affect behavior and SOP dimensions; and (3) incorporate a conservation ethic dimension into the SOP framework in working lands.     

Application of the method of dynamic calibration for IMS stations in regions with lower seismic activity

The Method of Dynamic Calibration (MDC) of stations of the International Monitoring System (IMS) was developed for calibrating regions where no underground nuclear explosions were carried out, with the purpose of providing conditions for implementation of the Comprehensive Nuclear-Test-Ban Treaty (CTBT) in nontrivial cases. Initially, the MDC had been presented in [Kedrov, 2001; Kedrov et al., 2001; Kedrov O.K. and Kedrov E.O., 2003] and then considered in detail in [Kedrov et al., 2008]. The core of MDC relates to adapting diagnostic parameters for the identification of underground nuclear explosions (UNE) and earthquakes elaborated for the region of Eurasia, taken as a basic region (BR), for other researched regions that differ from BR in the character of the attenuation of seismic waves. The unique characteristic of this method lies in the fact that calibration of diagnostic parameters with the help of attenuation coefficients b _Δ at varied source-station traces is implemented using only natural seismicity data within the limits of an explored region and does not require special underground chemical explosions. The MDC algorithm is implemented in the research program ”Kalibr”, which was tested by using the experimental data from Eurasia region. It is shown in this work that MDC can be used for calibration of regions where a very low level of natural seismicity is observed. According to the results of the calibration of diagnostic parameters at IMS stations in several regions of North America, Africa, and Asia, the approximate classification of propagation conditions for seismic signals at source-station traces in platform and tectonically active regions is made. The results for the development of two research programs, “Spektr” and “Signal”, are presented; this software is intended for automation of calculation procedures for spectral diagnostic parameters of UNEs’ and earthquakes’ identification by amplitude spectra of P waves and by the maximal amplitudes of P, S, and LR signals. The application of these programs allowed us to accelerate the whole calibration procedure for a particular source-station trace using the ”Kalibr” program.     

Petrological and trace element geochemical features of the Okete Volcanics,western North Island,New Zealand

The Okete Volcanics form small volume monogenetic volcanoes situated around the flanks of larger tholeiitic cones of the Plio-Pleistocene Alexandra Volcanics, in the back-arc tectonic environment of western North Island, New Zealand. The lavas and tuffs of the Okete Volcanics have compositions which include basanites, alkali olivine basalts, olivine tholeiites, and hawaiites. Most rocks have Mg numbers >66, >250 p.p.m. Ni, >500 p.p.m. Cr, and often contain ultramafic xenoliths, which indicate that they are very close to being primary magmas. The Okete Volcanics show geochemical trends, from basanite to hawaiite, of progressive depletion of both compatible and incompatible trace elements, progressive increase in Al₂O₃, and heavy REE and Y enrichment with crossingover REE patterns in the hawaiites. These geochemical trends can be accounted for by varying degrees of partial melting of a light REE enriched garnet peridotite with subsequent modification of the melts near source or during ascent by fractional crystallization of olivine and minor clinopyroxene. Mass balance calculations cannot quantitatively constrain the degree of partial melting or fractional crystallization, but nevertheless indicate that the Okete alkali olivine basalts, olivine tholeiites, and hawaiites have been derived by successively larger degrees of partial melting relative to basanites, and have also been progressively more modified by fractional crystallization than have the basanites. Sources of the alkalic melts lay at depths corresponding to >20 kb, and most of the ultramafic xenoliths, apart from some which may be cognate cumulates, are unrelated to the magmas that brought them to the surface. Magmas have changed in composition with time from older smaller-volume volcanoes of basanite or alkali olivine basalt compositions, to younger and more voluminous volcanoes which contain hawaiites. The geochemical trends shown by the Okete Volcanics and their spatial association with voluminous tholeiitic volcanism, are features which are different from those observed elsewhere in the Pliocene to Recent basaltic fields of northern North Island, and may be related to their unique tectonic setting, situated in a distinct structural domain.     

Devonshire marbles: history of the industry and the geology of these classic British ornamental stones

Devonshire ‘marbles’ come from Mid– to Late Devonian limestones of south Devon, UK. They are not true marbles in the geological sense but were nonetheless tectonically buried during the Variscan orogenesis. They retain abundant palaeontological and sedimentological characters, overstamped by limited to extensive veining, deformation and brecciation. Recent work has revealed how these marbles have been used to decorate a wealth of buildings in Britain and overseas. There were two distinct industries, one that produced decorative marble for architectural use, and one that produced portable artefacts such as specimen marble tables and ornaments. The stones used in these two sister industries can be very different, a result of different sourcing of the same Devonshire limestones. A third industry sought to slice and polish local limestone pebbles to reveal their diverse coral, stromatoporoid and other fossil contents, and was aimed at tourists, collectors and museums. The history and early development of the marble industry are explored and the distinct characteristics of the stones used in Devonshire marble inlay are explained. The stones used in the parallel architectural trade are analysed elsewhere.     

Integrated Global System Model for Climate Policy Assessment: Feedbacks and Sensitivity Studies

Alternative policies to address global climate change are being debated in many nations and within the United Nations Framework Convention on Climate Change. To help provide objective and comprehensive analyses in support of this process, we have developed a model of the global climate system consisting of coupled sub-models of economic growth and associated emissions, natural fluxes, atmospheric chemistry, climate, and natural terrestrial ecosystems. The framework of this Integrated Global System Model is described and the results of sample runs and a sensitivity analysis are presented. This multi-component model addresses most of the major anthropogenic and natural processes involved in climate change and also is computationally efficient. As such, it can be used effectively to study parametric and structural uncertainty and to analyze the costs and impacts of many policy alternatives. Initial runs of the model have helped to define and quantify a number of feedbacks among the sub-models, and to elucidate the geographical variations in several variables that are relevant to climate science and policy. The effect of changes in climate and atmospheric carbon dioxide levels on the uptake of carbon and emissions of methane and nitrous oxide by land ecosystems is one potentially important feedback which has been identified. The sensitivity analysis has enabled preliminary assessment of the effects of uncertainty in the economic, atmospheric chemistry, and climate sub-models as they influence critical model results such as predictions of temperature, sea level, rainfall, and ecosystem productivity. We conclude that uncertainty regarding economic growth, technological change, deep oceanic circulation, aerosol radiative forcing, and cloud processes are important influences on these outputs.     

Chemical and oxygen isotopic properties of ordinary chondrites (H5, L6) from Oman: Signs of isotopic equilibrium during thermal metamorphism

Mean bulk chemical data of recently found H5 and L6 ordinary chondrites from the deserts of Oman generally reflect isochemical features which are consistent with the progressive thermal metamorphism of a common, unequilibrated starting material. Relative differences in abundances range from 0.5–10% in REE (Eu = 14%), 6–13% in siderophile elements (Co = 48%), and >10% in lithophile elements (exceptions are Ba, Sr, Zr, Hf, U = >30%) between H5 and L6 groups. These differences may have accounted for variable temperature conditions during metamorphism on their parent bodies. The CI/Mg‐normalized mean abundances of refractory lithophile elements (Al, Ca, Sm, Yb, Lu, V) show no resolvable differences between H5 and L6 suggesting that both groups have experienced the same fractionation. The REE diagram shows subtle enrichment in LREE with a flat HREE pattern. Furthermore, overall mean REE abundances are ~0.6 × CI with enriched La abundance (~0.9 × CI) in both groups. Precise oxygen isotope compositions demonstrate the attainment of isotopic equilibrium by progressive thermal metamorphism following a mass‐dependent isotope fractionation trend. Both groups show a ~slope‐1/2 line on a three‐isotope plot with subtle negative deviation in ?¹⁷O associated with δ¹⁸O enrichment relative to δ¹⁷O. These deviations are interpreted as the result of liberation of water from phyllosilicates and evaporation of a fraction of the water during thermal metamorphism. The resultant isotope fractionations caused by the water loss are analogous to those occurring between silicate melt and gas phase during CAI and chondrule formation in chondrites and are controlled by cooling rates and exchange efficiency.     

A mesh deformation algorithm for free surface problems

Employing the simple iterative technique of adjusting the element positions using computed potentials to locate the free surface can lead to finite elements with large aspect ratios as the free surface drops towards the base of the mesh. In particular, free surface modelling of earth dams with base drains suffer from this problem. The paper suggests a number of steps which can be taken to alleviate mesh distortion problems and improve the numerical stability of the iterative finite element analysis. This leads to a mesh deformation algorithm which adjusts element widths in a simple fashion depending on the free surface height as the iterations proceed. The algorithm is specialized to the sloped earth dam problem, but may find application to other geometries. © 1997 by John Wiley & Sons, Ltd.     

Imaging Hydrological Processes in Headwater Riparian Seeps with Time‐Lapse Electrical Resistivity

Delineating hydrologic and pedogenic factors influencing groundwater flow in riparian zones is central in understanding pathways of water and nutrient transport. In this study, we combined two‐dimensional time‐lapse electrical resistivity imaging (ERI) (depth of investigation approximately 2 m) with hydrometric monitoring to examine hydrological processes in the riparian area of FD‐36, a small (0.4 km²) agricultural headwater basin in the Valley and Ridge region of east‐central Pennsylvania. We selected two contrasting study sites, including a seep with groundwater discharge and an adjacent area lacking such seepage. Both sites were underlain by a fragipan at 0.6 m. We then monitored changes in electrical resistivity, shallow groundwater, and nitrate‐N concentrations as a series of storms transitioned the landscape from dry to wet conditions. Time‐lapse ERI revealed different resistivity patterns between seep and non‐seep areas during the study period. Notably, the seep displayed strong resistivity reductions (～60%) along a vertically aligned region of the soil profile, which coincided with strong upward hydraulic gradients recorded in a grid of nested piezometers (0.2‐ and 0.6‐m depth). These patterns suggested a hydraulic connection between the seep and the nitrate‐rich shallow groundwater system below the fragipan, which enabled groundwater and associated nitrate‐N to discharge through the fragipan to the surface. In contrast, time‐lapse ERI indicated no such connections in the non‐seep area, with infiltrated rainwater presumably perched above the fragipan. Results highlight the value of pairing time‐lapse ERI with hydrometric and water quality monitoring to illuminate possible groundwater and nutrient flow pathways to seeps in headwater riparian areas.