Geochemistry and Evolution of Subcontinental Lithospheric Mantle in Central Europe: Evidence from Peridotite Xenoliths of the Kozakov Volcano, Czech Republic

Neogene basanite lavas of Kozákov volcano, located alongthe Lusatian fault in the northeastern Czech Republic, containabundant anhydrous spinel lherzolite xenoliths that providean exceptionally continuous sampling of the upper two-thirdsof central European lithospheric mantle. The xenoliths yielda range of two-pyroxene equilibration temperatures from 680°Cto 1070°C, and are estimated to originate from depths of32–70 km, based on a tectonothermal model for basalticunderplating associated with Neogene rifting. The sub-Kozákovmantle is layered, consisting of an equigranular upper layer(32–43 km), a protogranular intermediate layer that containsspinel–pyroxene symplectites after garnet (43–67km), and an equigranular lower layer (67–70 km). Negativecorrelations of wt % TiO₂, Al₂O₃, and CaO with MgO and clinopyroxenemode with Cr-number in the lherzolites record the effects ofpartial fusion and melt extraction; Y and Yb contents of clinopyroxeneand the Cr-number in spinel indicate 5 to 15% partial melting.Subsequent metasomatism of a depleted lherzolite protolith,probably by a silicate melt, produced enrichments in the largeion lithophile elements, light rare earth elements and highfield strength elements, and positive anomalies in primitivemantle normalized trace element patterns for P, Zr, and Hf.Although there are slight geochemical discontinuities at theboundaries between the three textural layers of mantle, theretends to be an overall decrease in the degree of depletion withdepth, accompanied by a decrease in the magnitude of metasomatism.Clinopyroxene separates from the intermediate protogranularlayer and the lower equigranular layer yield ¹⁴³Nd/¹⁴⁴Nd valuesof 0·51287–0·51307 (_Nd = +4·6 to+8·4) and ⁸⁷Sr/⁸⁶Sr values of 0·70328–0·70339.Such values are intermediate with respect to the Nd–Srisotopic array defined by anhydrous spinel peridotite xenolithsfrom central Europe and are similar to those associated withthe present-day low-velocity anomaly in the upper mantle beneathEurope. The geochemical characteristics of the central Europeanlithospheric mantle reflect a complex evolution related to Devonianto Early Carboniferous plate convergence, accretion, and crustalthickening, Late Carboniferous to Permian extension and gravitationalcollapse, and Neogene rifting, lithospheric thinning, and magmatism. KEY WORDS: xenoliths; lithospheric mantle; REE–LILE–HFSE; Sr–Nd isotopes; Bohemian Massif     

Causes and Consequences of Mangrove Deforestation in the Volta Estuary, Ghana: Some Recommendations for Ecosystem Rehabilitation

The damming of the Volta River has resulted in reduced flooding and an increase in mangrove cutting, due to the virtual collapse of agriculture and fishing in the estuary. Another ecological consequence of the reduced level of flooding has been reduced dispersal of seedlings of the principal mangrove Rhizophora racemosa. Therefore, after cutting of this species, recolonisation is either by conspecifics growing at very high densities or by one of a number of weed species. Environmental data collected in the vicinity of the mangroves and each of the weed species have enabled suggestions to be made as to whether R. racemosa or Avicennia africana would be the more suitable mangrove to replant. Recommendations have also been made to introduce the palm Nypa fruticans to the area, together with the development of nature-based tourism, both of which would provide alternative means of income generation, thereby reducing the need to cut remaining mangroves.     

Combined electromagnetic, geochemical and thermal surveys of Taal volcano (Philippines) during the period 2005–2006

Since 1572, 33 phreatic to phreatomagmatic eruptions have occurred on Taal volcano (Philippines), some of them causing several hundred casualties. Considering the time delay between two consecutive eruptions, there is an 88% probability that Taal volcano should have already erupted. Since 1992, several phases of seismic activity have been recorded accompanied by ground deformation, opening of fissures, and surface activity. The volcanic activity of Taal appears to be controlled by dike injections and magma supply, buffered by a hydrothermal system that releases fluids and heat through boiling and subsequent steaming. In early 2005, a multidisciplinary project was launched for studying the hydrothermal activity. To map the hydrothermal system, combined surveys were carried out to investigate self-potential, total magnetic field, ground temperature and carbon dioxide soil degassing, along with satellite thermal imaging of the Main Crater Lake. The elevated temperatures and high concentrations of carbon dioxide, as well as electromagnetic anomalies, indicate large-scale hydrothermal degassing. This process is enhanced along the tectonic features (e.g., crater rim and faults) of the volcano, while active fissures opened along the E–W northern flank during the 1992–1994 seismic activity. Heat and fluids from the hydrothermal system are essentially released in the northern part of the crater, which is bounded to the South by a suspected NW–SE fault along which seismicity seems to take place, and dikes are thought to be intruded. During the January 2005 surveys, a new seismic crisis started, and the felt earthquakes prompted spontaneous evacuation of hundreds of inhabitants living on the volcano. Repeated surveys show changes of self-potential, total magnetic field, and ground temperature with time, without any noticeable spatial enlargement. These observations suggest that the northern flank located between the crater rim and the 1992–1994 fissures is connected with a deep thermal source in Main crater and is reactivated during seismic crises. This sector could be subjected to flank failure.     

Application of the dynamic calibration method to international monitoring system stations in Central Asia using natural seismicity data

The dynamic calibration method (DCM), using natural seismicity data and initially elaborated in [Kedrov, 2001; Kedrov et al., 2001; Kedrov and Kedrov, 2003], is applied to International Monitoring System (IMS) stations in Central Asia. The algorithm of the method is refined and a program is designed for calibrating diagnostic parameters (discriminants) that characterize a seismic source on the source-station traces. The DCM calibration of stations in relation to the region under study is performed by the choice of attenuation coefficients that adapt the diagnostic parameters to the conditions in a reference region. In this method, the stable Eurasia region is used as the latter. The calibration used numerical data samples taken from the archive of the International Data Centre (IDC) for the IMS stations MKAR, BVAR, EIL, ASF, and CMAR. In this paper, we used discriminants in the spectral and time domains that have the form

$D_i = X_i - a_m m_b - b_\Delta \log \Delta $

and are independent of the magnitude m _b and the epicentral distance Δ; these discriminants were elaborated in [Kedrov et al., 1990; Kedrov and Lyuke, 1999] on the basis of a method used for identification of events at regional distances in Eurasia. Prerequisites of the DCM are the assumptions that the coefficient a _m is regionindependent and the coefficient b _Δ depends only on the geotectonic characteristics of the medium and does not depend on the source type. Thus, b _Δ can be evaluated only from a sample of earthquakes in the region studied; it is used for adapting the discriminants D(X _i ) in the region studied to the reference region. The algorithm is constructed in such a way that corrected values of D(X i) are calculated from the found values of the calibration coefficients b _Δ, after which natural events in the region under study are selected by filtering. Empirical estimates of the filtering efficiency as a function of a station vary in a range of 95–100%. The DCM was independently tested using records obtained at the IRIS (Incorporated Research Institutions for Seismology) stations BRVK and MAKZ from explosions detonated in India on May 11, 1998, and Pakistan on May 28, 1998; these stations are similar in location and recording instrumentation characteristics to the IMS stations BVAR and MKAR. This test resulted in correct recognition of the source type and thereby directly confirmed the validity of the proposed calibration method of stations with the use of natural seismicity data. It is shown that the calibration coefficients b _Δ for traces similar in the conditions of signal propagation (e.g., the traces from Iran to the stations EIL and ASF) are comparable for nearly all diagnostic parameters. We arrive at the conclusion that the method of dynamic calibration of stations using natural seismicity data in a region where no explosions were detonated can be significant for a rapid and inexpensive calibration of IMS stations. The DCM can also be used for recognition of industrial chemical explosions that are sometimes erroneously classified in regional catalogs as earthquakes.

     

Optimal cost‐effective topology of column bearings for reducing vertical acceleration demands in multistory base‐isolated buildings

Base‐isolation is regarded as one of the most effective methods for protecting the structural and nonstructural building elements from design level horizontal earthquake ground shaking. However, base‐isolation as currently practiced does not offer unlimited protection for these buildings, especially when the ground shaking includes a strong vertical component. The vulnerability of nonstructural systems in a base‐isolated building was made evident during recent shake table testing of a full‐scale five‐story base‐isolated steel moment frame where nonstructural system damage was observed following tests including vertical excitation. Past research efforts have attempted to achieve 3D isolation of buildings and nuclear structures by concentrating both the horizontal and vertical flexibility at the base of the building that are either quite limited or not economically viable. An approach whereby the vertical flexibility is distributed up the height of the building superstructure to passively reduce vertical acceleration demands in base‐isolated buildings is presented. The vertical flexibility is achieved by placing laterally restrained elastomeric ‘column’ bearings at one or more floor levels along the height of the building. To broadly investigate the efficacy of the vertically distributed flexibility concept and the trade‐off between mitigation and cost, a multi‐objective optimization study was conducted considering 3‐story, 9‐story, and 20‐story archetype buildings that aimed to minimize the median peak vertical floor acceleration demands and to minimize the direct cost of column bearings. Based on the results of the optimization study, a practical rule for determining the number of levels and locations of column bearings is proposed and evaluated. Copyright © 2013 John Wiley & Sons, Ltd.     

The influence of sediment resuspension on the degradation of phenanthrene in flow-through microcosms

The effect of sediment resuspension on the mineralization of phenanthrene was examined in microcosms and sediment slurries. In computer-controlled, flow-through microcosms, 14C-phenanthrene-amended sediments were resuspended into overlying oxic water at frequencies of 12, 4, 1, 0.25 and 0 d(-1). In slurry bottle experiments 14C-phenanthrene-amended sediments were continuously resuspended under oxic (excess air headspace) and anoxic (N2 headspace) conditions and mineralization was measured at periods from 2 h to 7 days. Our main findings were: (1) mineralization rate constants from the microcosms ranged from 0.001 to 0.01 d(-1) and increased with frequency of resuspension, (2) these rates fell between those measured in oxic and anoxic slurries and were predicted within a factor of 2.5 by a model in which mineralization depended on the degree of oxygen exposure, and (3) the phenanthrene-degrading bacterial community was more active in resuspended sediments incubated in the microcosms than in sediments which were not resuspended, or which were stored under refrigeration. We conclude from these experiments that the effects of sediment resuspension on phenanthrene degradation are consistent with a primary role of average oxygen exposure, and also an alteration in the PAH-degrading activity of microbial populations.     

Period–luminosity relations for red supergiant variables – II. The distance to M101

We report the discovery of 42 red supergiant variables (RSVs) in the late-type spiral galaxy M101. Periods for the luminosity variation of these RSVs were determined from 20 epochs of ground-based CCD photometry in the Kron–Cousins R band obtained with the KPNO 2.1-m and WIYN 3.5-m telescopes over a span of three years. The periods found were in the range 200–1300 days. Using the relationship between the RSV periods and their luminosity in the Kron–Cousins I band, we estimate a reddening-corrected distance modulus to M101 of 29.40±0.16 mag (based on a distance modulus of 18.5±0.1 mag for the Large Magellanic Cloud). This distance is consistent with the Hubble Space Telescope Key Project Cepheid distances of 29.34±0.17 mag for the outer field of M101 and 29.21±0.17 mag for the inner field.     

Have there been recent changes in climate? Ask the fish

It is generally accepted that a climate shift occurred about 1977 that affected the dynamics of North Pacific marine ecosystems. Agreement on the possibility of further climate shifts in 1989 and the late 1990s is yet to be achieved. However, there have been changes in the dynamics of key commercial fishes that indicate changes in their environment occurred in the early 1990s, and possibly around 1998. One method of measuring climate change is to observe the dynamics of species that could be affected.Several studies have described decadal-scale changes in North Pacific climate–ocean conditions. Generally, these studies focus on a single index. Using principal components analysis, we use a composite index based on three aspects of climate ocean conditions: the Aleutian Low Pressure Index, the Pacific Atmospheric Circulation Index and the Pacific Interdecadal Oscillation Index. We link this composite index (Atmospheric Forcing Index) to decadal-scale changes in British Columbia salmon and other fish populations. Around 1989 there was a change from intense Aleutian Lows (above average south-westerly and westerly circulation patterns and warming of coastal sea surface temperatures) to average Aleutian Lows (less frequent south-westerly and westerly circulation and slightly cooler coastal sea surface temperatures in winter). These climate–ocean changes were associated with changes in the abundance and ocean survival of salmon (Oncorhynchus spp.), distribution and spawning behaviour of hake (Merluccius productus) and sardines (Sardinops sagax) and in recruitment patterns of several groundfish species.     

Trace metal concentrations in the Ross Sea and their relationship with nutrients and phytoplankton growth

Dissolved and particulate trace metal concentrations (dissolved Fe, Zn, Cd, Co, Cu and Ni; particulate Fe, Mn and Al) were measured along two transects in the Ross Sea during austral summer of 1990. Total Fe concentrations in southern Ross Sea and inshore waters were elevated >3.5 times that of northern waters. Dissolved Zn, Cd and Co concentrations were lower by factors of 4.5, 3.5 and 1.6 in southern surface waters relative to northern waters. Dissolved Cu and Ni concentrations were similar in both areas. Elevated Fe concentrations coincided with areas of increased productivity, phytoplankton biomass and nutrient drawdown, indicating that Fe is an important factor controlling the location of phytoplankton blooms in the Ross Sea. Particulate concentrations of Fe, Mn and Al indicate two possible sources of iron to the Ross Sea, resuspension of continental shelf sediments and iron incorporated in annual sea ice and released with meltwaters.