Saturn's cloud structure and temporal evolution from ten years of Hubble Space Telescope images (1994-2003)

We present a study of the vertical structure of clouds and hazes in the upper atmosphere of Saturn's Southern Hemisphere during 1994-2003, about one third of a Saturn year, based on Hubble Space Telescope images. The photometrically calibrated WFPC2 images cover the spectral region between the near-UV (218-255 nm) and the near-IR (953-1042 nm), including the 890 nm methane band. Using a radiative transfer code, we have reproduced the observed center-to-limb variations in absolute reflectivity at selected latitudes which allowed us to characterize the vertical structure of the entire hemisphere during this period. A model atmosphere with two haze layers has been used to study the variation of hazes with latitude and to characterize their temporal changes. Both hazes are located above a thick cloud, putatively composed of ammonia ice. An upper thin haze in the stratosphere (between 1 and 10 mbar) is found to be persistent and formed by small particles (radii ∼0.2 μm). The lower thicker haze close to the tropopause level shows a strong latitudinal dependence in its optical thickness (typically τ∼20-40 at the equator but τ∼5 at the pole, at 814 nm). This tropospheric haze is blue-absorbent and extends from 50 to 100 mbar to about ∼400 mbar. Both hazes show temporal variability, but at different time-scales. First, there is a tendency for the optical thickness of the stratospheric haze to increase at all latitudes as insolation increases. Second, the tropospheric haze shows mid-term changes (over time scales from months to 1-2 years) in its optical thickness (typically by a factor of 2). Such changes always occur within a rather narrow latitude band (width ∼5-10°), affecting almost all latitudes but at different times. Third, we detected a long-term (∼10 year) decrease in the blue single-scattering albedo of the tropospheric haze particles, most intense in the equatorial and polar areas. Long-term changes follow seasonal insolation variations smoothly without any apparent delay, suggesting photochemical processes that affect the particles optical properties as well as their size. In contrast, mid-term changes are sudden and show various time-scales, pointing to a dynamical origin.     

TiN PRODUCTION IN A GLOW DISCHARGE

We have been studying direct current glow discharges aiming at the production of different paint of coatings on steel substrates. In a set of preliminary experiments, long lasting (hours) discharges performed in a Nitrogen atmosphere between a stell anode (holding the substrates) and a titanium cathode separated by a small gap (few mm) produced very thin coatings of the substrates whose colour depend on the parameter of (interelectrodes gap, gas pressure, discharge current and time duration). In some conditions, the coatings showed a golden colour, typical of the Nti compound. A discussion of the results is given.     

Neoproterozoic–Cambrian synsedimentary magmatism in the Central Iberian Zone (Spain): geology,petrology and geodynamic significance

Petrographic, geochemical and field studies in low grade metamorphic areas (Ciudad Rodrigo-Hurdes-Sierra de Gata domain, CRHSG, central-western Spain) show that Neoproterozoic-Lowermost Cambrian series in the Central Iberian Zone (CIZ) record two kinds of provenance sources including: (1) detrital material derived from recycled orogens and (2) a Cadomian coeval juvenile contribution that governs their isotopic signature. Evidence of magmatism contemporaneous with Neoproterozoic-Cambrian sedimentation is provided by the presence of coherent, massive volcanic rocks (metabasalts, metaandesites, and metarhyolites), volcaniclastic shales, sandstones, conglomerates and breccias. The appearance of volcanogenic lithic fragments and crystals mixed in different proportions with siliciclastic constituents and also present within calcareous components in the sedimentary succession, reinforces this evidence. Although most of the selected volcanic and volcaniclastic samples appear to show tholeiitic affinity, some of them display calc-alkaline affinity. Different trace element ratios, such as Sm/Nd, Nb/Yb and Ta/Yb, suggest a magmatic evolution in the same tectonic setting. The geochemical results reported here support the existence of an active geodynamic setting as a direct contributor to the synsedimentary and magmatic content of the Neoproterozoic–Lowermost Cambrian successions in the CIZ. In particular, the relatively high Nd _(T) values and the high range of f ^Sm/Nd ratios are consistent with an active margin during the Neoproterozoic–Early Cambrian. The existence of tectonic activity is also confirmed by the presence of synsedimentary deformation and volcanic rocks. All of these traits favour a geodynamic model in which the Iberian Cadomian segment represented in the CIZ would have been part of an active northern margin of Gondwana, with an associated magmatic arc and related basins during Neoproterozoic–Lower Cambrian times. A proposed link between the Ossa Morena and the Central Iberian Zones might account for late Cadomian pull-apart basins developed on both sides of the magmatic arc, sharing the same scenario and involving similar magmatic activity during the Neoproterozoic–Cambrian transition.

The Ushnus in the astronomy of the Inca culture

Inferences are made about the relationship that existed between the Ushnus, pyramid-shaped, terraced structures used by the Incas in the most important ceremonies of the Tawantinsuyo, and Inka Astronomy. We draw attention to Ayni, Kawsaypacha, Duality, and Tinkuy principles, multidimensional codes of conduct and wisdom that are at the root of the Andean cosmovision and on their perception of the world and the Cosmos. These principles, examined as postulates, allow to elaborate axiomatic propositions to identify the Ushnus with ancient Astronomy practices. In a complementary statement, starting from a bi-conditional proposition, we may infer through reciprocal corollaries that the Inka earliest roots to a holistic learning and educational ambient in the Tawantinsuyo was not elitist, instead it was based on a epistemological construct that differs from the corresponding Western educational ambients. An epistemological and cognitive approach allows to identify an ancient elaborate process of knowledge construction, based on the four fundamental principles, corresponding to different levels of assimilation and comprehension. As a complementary aspect, we identify some of the most preserved Ushnus of the Inka “Empire.” Then we complement this contribution with a broader interpretation for the Ushnus.     

In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS

Bastnäsite is the end member of a large group of carbonate–fluoride minerals with the common formula (REE) CO₃F·CaCO₃. This group is generally widespread and, despite never occurring in large quantities, represents the major economic light rare earth element (LREE) mineral in deposits related to carbonatite and alkaline intrusions. Since bastnäsite is easily altered and commonly contains inclusions of earlier‐crystallised minerals, in situ analysis is considered the most suitable method to measure its U‐Th‐Pb and Sr‐Nd isotopic compositions. Electron probe microanalysis and laser ablation (multi‐collector) inductively coupled plasma‐mass spectrometry of forty‐six bastnäsite samples from LREE deposits in China, Pakistan, Sweden, Mongolia, USA, Malawi and Madagascar indicate that this mineral typically has high Th and LREE and moderate U and Sr contents. Analysis of an in‐house bastnäsite reference material (K‐9) demonstrated that precise and accurate U‐Th‐Pb ages could be obtained after common Pb correction. Moreover, the Th‐Pb age with its high precision is preferable to the U‐Pb age because most bastnäsites have relatively high Th rather than U contents. These results will have significant implications for understanding the genesis of endogenous ore deposits and formation processes related to metallogenic geochronology research.     

Cretaceous deformation of the southern Central Andes: synorogenic growth strata in the Neuquén Group (35° 30′–37° S)

The Neuquén Group is an Upper Cretaceous continental sedimentary unit exhumed during the latest Miocene contractional phase occurred in the southern Central Andes, allowing a direct field observation and study of the depositional geometries. The identification of growth strata on these units surrounding the structures of the frontal parts of the Andes, sedimentological analyses and U–Pb dating of detrital components, allowed the definition of a synorogenic unit that coexisted with the uplift of the early Andean orogen since ca. 100 Ma, maximum age obtained in this work, compatible with previous assignments and constrained in the top by the deposition of the Malargüe Group, in the Maastrichtian (ca. 72 Ma). The definition of a wedge top area in this foreland basin system, where growth strata were described, permitted to identify a Late Cretaceous orogenic front and foredeep area, whose location and amplitude contrast with previous hypotheses. This wedge top area was mostly fed from the paleo‐Andes with small populations coming from sources in the cratonic area that are interpreted as a recycling in Jurassic and Lower Cretaceous sections, which contrasts with other analyses performed at the foredeep zone that have mixed sources. In particular, Permian sources are interpreted as coming directly from the cores of the basement structures, where Neopaleozoic sections are exposed, next to the synorogenic sedimentation, implying a strong incision in Late Cretaceous times with an exhumation structural level similar to the present. The maximum recognised advance for this Late Cretaceous deformation in the study area is approximately 500 km east of the Pacific trench, which constitutes an anomaly compared with neighbour segments where Late Cretaceous deformations were found considerably retracted. The geodynamic context of the sedimentation of this unit is interpreted as produced under the westward fast moving of South America, colliding with two consecutive mid‐ocean ridges during a period of important plate reorganisation. The subduction of young, anhydrous, buoyant lithosphere would have produced changes in the subduction geometry, reflected first by an arc waning/gap and subsequently by an arc migration that coexisted with synorogenic sedimentation. These magmatic and deformational processes would be the product of a shallow subduction regime, following previous proposals, which occurred in Late Cretaceous times, synchronous to the sedimentation of the Neuquén Group.     

Enhanced identification of a hydrologic model using streamflow and satellite water storage data: A multicriteria sensitivity analysis and optimization approach

Hydrologic model development and calibration have continued in most cases to focus only on accurately reproducing streamflows. However, complex models, for example, the so‐called physically based models, possess large degrees of freedom that, if not constrained properly, may lead to poor model performance when used for prediction. We argue that constraining a model to represent streamflow, which is an integrated resultant of many factors across the watershed, is necessary but by no means sufficient to develop a high‐fidelity model. To address this problem, we develop a framework to utilize the Gravity Recovery and Climate Experiment's (GRACE) total water storage anomaly data as a supplement to streamflows for model calibration, in a multiobjective setting. The VARS method (Variogram Analysis of Response Surfaces) for global sensitivity analysis is used to understand the model behaviour with respect to streamflow and GRACE data, and the BORG multiobjective optimization method is applied for model calibration. Two subbasins of the Saskatchewan River Basin in Western Canada are used as a case study. Results show that the developed framework is superior to the conventional approach of calibration only to streamflows, even when multiple streamflow‐based error functions are simultaneously minimized. It is shown that a range of (possibly false) system trajectories in state variable space can lead to similar (acceptable) model responses. This observation has significant implications for land‐surface and hydrologic model development and, if not addressed properly, may undermine the credibility of the model in prediction. The framework effectively constrains the model behaviour (by constraining posterior parameter space) and results in more credible representation of hydrology across the watershed.     

Role of time variant and invariant terms on soil moisture spatio-temporal variability in a subhumid coastal wetland

The knowledge of soil moisture spatio-temporal variability is highly relevant for water resources management. This paper reports an analysis of the spatial–temporal variability of soil moisture data for a small to medium-scale soil-sensors network in a coastal wetland of southwestern Spain. Measurements were taken from five sites located in the Doñana National Park over the time-period of one hydrological year from September 2017 to September 2018. The total area of the soil-sensors network shows an extension about 25 × 3 km. Soil moisture data was separated into time invariant (the temporal mean of the whole period at each site) and time-variant terms (the deviations of soil moisture from the mean, or anomalies). The time-invariant component was generally the main contributor to the total spatial variance of soil moisture and it was mostly controlled by the groundwater levels in the area. Nevertheless, the time variant terms have a huge effect on soil moisture variability in very dry states. Characteristic convex time-dependent patterns for this field site were found between spatially averaged soil moisture and its variability. This information could be used for the up and downscaling of soil moisture from satellite data. Those patterns of relation between spatial mean and variability of soil moisture were only affected by heavy rainfalls giving rise to hysteretic behaviour. This study shows that even though groundwater level is a time-variant variable, it significantly affects soil moisture's time-variant but also time-invariant terms due to the different average groundwater level depths at the different sites.     

Digital mapping of coastal boulders – high-resolution data acquisition to infer past and recent transport dynamics

Coastal boulder fields provide clues to long-term frequency-magnitude patterns of coastal flooding events and have the potential to play an important role in coastal hazard assessment. Mapping boulders in the field is time and labour-intensive, and work on intertidal reef platforms, as in the present study, is physically challenging. By addressing coastal scientists who are not specialists in remote sensing, this contribution reports on the possibilities and limitations of digital applications in boulder mapping in Eastern Samar, Philippines, where recent supertyphoons Haiyan and Hagupit induced high waves, coastal flooding and boulder transport. It is demonstrated how satellite imagery of sub-metre resolution (from Pléiades and WorldView-3 imagery) enables efficient analysis of transport vectors and distances of larger boulders, reflecting variation in latitudes of both typhoon tracks and approaching angles of typhoon-generated waves. During the investigated events, boulders with a-axes of up to 8 m were clearly identified to have been shifted for up to 32 m, mostly along the seaward margin of the boulder field. It is, however, hard to keep track of smaller boulders, and the length of a-axes and b-axes including their orientation is often impossible to map with sufficient accuracy. Orthophotographs and digital surface models created through the application of an unmanned aerial vehicle and the ‘Structure from Motion’ technique provide ultra-high-resolution data, and have the potential to not only improve the results of satellite image analysis, but also those from field mapping and may significantly reduce overall time in the field. Orthophotographs permit unequivocal mapping of a-axes and b-axes including their orientation, while precise values for c-axes can be derived from the respective digital surface models. Volume of boulders is best inferred from boulder-specific Structure from Motion-based three-dimensional models. Battery power, flight speed and altitude determine the limits of the area covered, while patches shielded by the boulders are difficult to resolve. For some tasks, field mapping remains mandatory and cannot be replaced by currently available remote sensing tools: for example, sampling for rock type, density and age dating, recording of lithological separation of boulders from the underlying geological unit and of geomorphic features on a millimetre to decimetre-scale, or documentation of fine-grained sediment transport in between the boulders in supratidal settings. In terms of future events, the digital products presented here will provide a valuable reference to track boulder transport on a centimetre to decimetre-scale and to better understand the hydrodynamics of extreme-wave events on a fringing reef coastline.