赣南地区寒武纪高滩组碎屑锆石U-Pb年龄和Hf同位素特征及地质意义

寒武纪高滩组广泛分布于赣南武功山-雩山地区,主体为一套浅变质砂岩夹板岩的复理石建造。为分析其物源,并对源区地壳生长和构造演化提供约束,本文对采自高滩组的变长石石英杂砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学和Hf同位素研究。锆石U-Pb年龄数据显示2 500 Ma、1 100~900 Ma和900~700 Ma 3个主要年龄峰值。2 500 Ma的年龄峰值代表了新太古代末期—古元古代的古陆核生长事件。1 100~900 Ma和900~700 Ma两个峰最显著,表明Rodinia超大陆聚合裂解在华南地区的响应,为该区寒武纪地层提供了主要物源。此外,3 003 Ma锆石年龄的捕获说明,华夏地块可能存在太古宙地壳基底。Hf同位素数据表明,源区锆石结晶多为古老地壳组分部分熔融产生的岩浆。结合锆石年龄数据分析认为,华南地区存在强烈的新元古代岩浆活动,该时期岩浆活动主要是古老地壳物质的再循环。     

伏牛山构造带变质流体脉变形特征及构造意义

伏牛山构造带由多条近平行的断裂带和夹持其间的变形岩片组成,洛南-栾川断裂带和瓦穴子-乔端断裂带为其中的两条主要断裂带。这两条断裂带虽遭受多期强烈构造活动的影响,但主造山期的构造特征至今仍然保存完好,并以中深层次的韧性剪切变形为主,形成了典型的糜棱岩和同构造期石英脉。本文从宏观、微观、超微观变形特征及年龄等方面对这些变质流体脉进行了研究,以探讨与其形成密切相关的构造活动特征、年代及其在秦岭造山带和华北板块南缘强变形带中的作用。石英脉中石英颗粒动态重结晶特征总体显示远离剪切带只有少量的膨凸式,靠近断裂带为亚颗粒式,形成核-幔结构,位错特征显示远离剪切带位错密度较小,靠近断裂带较大,位错形态显示瓦乔断裂带以挤压为主,洛南-栾川断裂带以剪切为主。两条断裂带石英脉的变形特征说明它们的糜棱岩化过程均为塑性变形中的晶质塑性变形,形成过程均为挤压在先,剪切在后。所测糜棱岩中石英脉的ESR年龄分别为372.9±30.0 Ma、275.0±20.0 Ma和218.0±20.0 Ma,真实地记录了晚加里东至中-晚海西期北秦岭的构造活动及所受影响。其中372.9±30.0 Ma是宽坪岩块向华北板块下的斜向俯冲汇聚和走滑的年代, 275.0±20.0 Ma是瓦乔断裂带的形成年龄。218.0±20.0 Ma的年龄则反映了华南、华北两大板块印支晚期全面闭合作用在秦岭造山带内部的影响。从以上3个年龄可以看出:北秦岭各构造带自北向南演化,时代上自北向南变新。     

Chemistry and Evolution of Fergusonite—Group Minerals,Bayan Obo,Inner Mongolia

A new classification scheme of the fergusnoite-group minerals is suggested on the basis of mineral chemistry and high temperature XRD. A number of new varieties such as M-thorian fergusonite-(Ce). M-neodymian fergusonite-(Ce). T-titanian fergusonite-(Nd) and T-yttrian fergusonite-(Nd) have been recognized in the light of detailed chemical studies, particularly with reference to REE, SRE and solid solution relationship. The results indicate strong REE and SRE differentiation and evolution in the fergusonite group, which can be interpretated by differences in the stability of various REE complexes in response to variations in physicochemical conditions during the multi-stage mineralization process in the Bayan Obo ore deposit. The crystallization of the minerals is closely related to hydrolysis of REE and Nb complexes. REE (OH)₃ Nb(OH)₅ coprecipitation, dehydration, polymerization and nucleation.The significance of SRE (Eu)in the western part of the deposit is emphasized. This project was finantially supported by the National Natural Science Foundation of China.     

Ore-Forming Fluid Characteristics of the Dayingezhuang Gold Deposit, Jiaodong Gold Province, China

The Dayingezhuang gold deposit is located in the central part of the Zhaoping Fault Zone, which is one of the most important gold-hosting faults in the Jiaodong gold province of China. Dayingezhuang is a typical large-scale shear zone-hosted disseminated gold deposit with superimposed silver mineralization. Fluid inclusion (FI) petrography and microthermometry, and analysis of oxygen and hydrogen isotopes for fluid inclusions were conducted to determine the characteristics of the ore-forming fluids and the processes of silver mineralization. Microthermometry data of FI indicated that ore-forming fluids are characterized by low salinity and low density. Homogenization pressures of FI are estimated at 20 × 10⁵–220 × 10⁵ Pa. The change in ore-forming fluids from K₂SO₄ type to NaCl type indicates the superposition of two hydrothermal mineralizing events. Ore-forming fluids were dominated by magmatic components in the early mineralization period, and affected by meteoric waters in the late period. Gold may have been transported as Au-S or Au-Cl complexes, whereas silver was transported as Ag-Cl complexes. Early fluid boiling and later fluid mixing are thought to be two of the main factors causing the deposition and superimposing of gold and silver to form the large deposit.     

TBP萃淋树脂微色谱柱分离富集钼的研究及应用

研究了ＴＢＰ萃淋树脂微色谱柱分离富集微量钼的柱性能,确定了分离钼的最佳条件。在减压条件下,运用零空床体积洗脱技术,以３ｍｏｌ／ＬＨＣｌ为上柱介质,０．５ｍｏｌ／ＬＨＣｌ洗脱,可使钼（ＶＩ）与钨（Ⅵ）、铁（Ⅲ）、锡（Ⅳ）等干扰离子快速分离,采用邻氯苯基荧光酮胶束增溶光度法,测定矿石中微量钼,结果满意。     

Postcollisional flow of aqueous fluid within ultrahigh-pressure eclogite in the Dabie orogen

A combined study of chronometric dating and oxygen isotope analysis for minerals from vein and host eclogite as well as regional country-rock gneiss in the Dabie orogen provides a direct constraint on timing of fluid flow in this orogen formed by continental collision. Oxygen isotope ratios of vein minerals are significantly lower than those of the host eclogite, but comparable with those of the regional gneiss. This suggests the veining fluid came from the regional gneiss (i.e. exhumed slab itself) rather than the host eclogite. While zircon U–Pb and phengite Ar–Ar dating yields ages of 214 to 222 Ma for the eclogite and gneiss, the vein gives a quartz–muscovite Rb–Sr isochron age of 181 Ma and a muscovite K–Ar age of 179 Ma. Thus the veining postdates the Triassic ultrahigh pressure metamorphic event, witnessing postcollisional fluid flow after the orogenic cycle of continental collision.     

华北地区人类文化遗址的地球化学环境演变

在地球演化历史上,第四纪是人类诞生、发展和壮大的时代,它所形成的地质产物中记录了丰富的生态环境信息。河北省境内第四纪岩石地层(泥河湾组、赤城组、马兰组、迁安组)的风化指数CIA,Fe2O3/FeO,Fe/Mn等地球化学参数可作为年均气温、年均降雨量等气候因子的近似代用指标;华北地区人类文化遗址所在地水系沉积物中Hg,Sn和Au等元素含量随人类文明的演进而阶段性增高。这一结果表明,人类为了适应不断变化的自然地理环境(寒冷、干旱),不得不进行技术创新,从而产生了农业耕作、工业革命及现代信息产业等文明进步成果,但与此同时,却也导致了地质环境的人为污染,甚至可能引发全球温室效应。     

大别地区不同类型岩石的超高压结晶实验及其岩石学意义

在３．５ＧＰａ、１２００℃条件下对取自大别地区的不同类型岩石进行了重结晶实验，并采用偏光显微镜、Ｘ射线粉晶衍射和电子探针对实验产物的结晶特点、矿物组成及矿物成分进行了研究。结果表明：①石榴橄缆岩的岩石成因与共生的榴辉岩相同；②榴辉岩的重结晶经历了从单斜辉石岩、石榴辉石岩到榴辉岩的过程；③超高压片麻岩主要由石榴子石、绿辉石、多硅白云母和柯石英组成，不含斜长石、黑云母和绿帘石等常规矿物；④柯石英和文石     

热带土壤发育过程的定量研究—以海南岛北部为例

海南岛北部不同时期喷发的玄武岩上发育的土壤构成一个成土年代系列, 由此可以定量地探讨发育过程中土壤性质随风化成土年龄增加的变化规律.研究表明土体厚度、B层厚度、RR指数、w(REE)、w(Ba)/w(Nb)、w(Fe_d)/w(Fe_t)、w(Fe_d)、w(Fe_o)/w(Fe_d)、土壤硅铝率、土壤硅铁铝率、频率磁化率等土壤性质与风化成土年龄具有确定的相应关系.根据土壤发生学原则, 得出土壤性质与风化成土年龄两者间的统计方程.对于成土环境相同或相近地区可从这些方程由土壤性质推断相对风化成土年龄和发育程度, 也可由风化成土年龄估计土壤特性, 研究成土速率      

应用微机监测系统随钻识别地层与孔内工况

钻探微机监测系统可随钻监测和记录９个钻进参数，绘制４～６条回次过程曲线，提示孔内情况，声光报警。在生产现场，操作者可根据显示的提示和曲线等信息，识别孔底地层变化情况，进行见矿预报，保证好的地质效果，该系统还可辅助操作者识别孔内烧钻，钻杆折断，岩心堵塞等异常工况，从而降低事故率，提高钻探效率。