Soil H<Subscript>2</Subscript> and CO<Subscript>2</Subscript> Surveys at Several Active Faults in Japan

Soil H₂ and CO₂ surveys were carried out along seven active faults and around the aftershock region of the 2000 Tottori-ken Seibu earthquake in Japan. Diffuse CO₂ effluxes were also measured along one fault and around the 2000 aftershock region. The results show highly variable H₂ concentration in space and time and it seems that the maximum H₂ concentration at each active fault correlates with fault activity as exemplified by the time of the latest big earthquakes. Even though observed H₂ concentrations in four faults were markedly lower than those collected previously in the latter half of the 1970s, it is evident that the higher H₂ concentrations in this study are due to the addition of the fault gases. Comparing the chemical composition of trapped gases (H₂: 5–20% and CO₂/H₂: 0.5–12) in fractured rocks of drill cores bored at the Nojima fault, a soil gas sample with the highest H₂ concentration showed large amounts of the trapped fault gas, diluted with atmospheric component. The profile experiment across a fracture zone at the Yamasaki fault showed higher H₂ concentrations and lower CO₂/H₂ ratios as was observed in soil gas from the fracture zone. A few days after the 2000 Tottori-kei Seibu earthquake, no CO₂ effluxes related to the occurrence of earthquakes were observed at the aftershock region. However, only above the epicenter zone, relatively high H₂ concentrations in soil gases were observed.     

Tsunami hazard in the Eastern Mediterranean and its connected seas: Toward a Tsunami warning center in Turkey

Tsunami mitigation, preparedness and early warning initiatives have begun at the global scale only after the tragic event of Sumatra in 2004. Turkey, as a country with a history of devastating earthquakes, has been also affected by tsunamis in its past. In this paper we present the Tsunami Hazard in the Eastern Mediterranean and its connected seas (Aegean, Marmara and Black Sea) by providing detailed information on historically and instrumentally recorded significant tsunamigenic events surrounding Turkey, aiming to a better understanding of the Tsunami threat to the Turkish coasts. In addition to the review of the Tsunami hazard, we have studied a possible Tsunami source area between Rhodes and SW of Turkey using Tsunami numerical model NAMI DANCE-two nested domains. We have computed a maximum positive amplitude of 1.13 m and maximum negative amplitude of −0.5 m at the Tsunami source by this study. The distribution of maximum positive amplitudes of the water surface elevations in the selected Tsunami forecast area and time histories of water level fluctuations near selected locations (Marmaris, Dalaman, Fethiye and Kas towns) indicate that the maximum positive amplitude near the coast in the selected forecast area exceeds 3.5 m. The arrival time of maximum wave to Marmaris, Dalaman, is 10 min, while that of Fethiye and Kas towns is 15–20 min. The maximum positive amplitudes near the shallow region of around 10 m depth are 3 m (Marmaris), 1 m (Dalaman), 2 m (Fethiye) and 1 m (Kas). Maximum positive amplitudes of water elevations in the duration of 4 h simulation of the Santorini-Minoan Tsunami in around 1600 BC in the Aegean Sea are also calculated based on a simulation performed using 900 m grid resolution of Aegean sea bathymetry with a 300 m collapse of 10 km diameter of Thera (Santorini) caldera. We have also presented the results of the Tsunami modeling and simulation for Marmara Sea obtained from a previous study. Last part of this paper provides information on the establishment of a Tsunami Warning Center by KOERI, which is expected to act also as a regional center under the UNESCO Intergovernmental Oceanographic Commission – Intergovernmental Coordination Group for the Tsunami Early Warning and Mitigation System in the North-Eastern Atlantic, the Mediterranean and Connected Seas (ICG/NEAMTWS) initiative, emphasizing on the challenges together with the future work needed to be accomplished.     

An isobaric–isenthalpic magma mixing model for the Hasan Dagi volcano,Central Anatolia,Turkey

Calc-alkaline rocks of the Hasan Dagi volcano (Central Anatolia, Turkey) are products of arc volcanism triggered by continental collision. Volcanic rocks of the Hasan Dagi range in composition from basalt to rhyolite but are dominated by andesite and dacite. Considering only the mass transfer part of the process leads to an incomplete picture of magma chamber processes. The exclusion of simultaneous calculations of heat and mass transfer between mixing magmas, however, has prevented petrologists from gaining new insights into the magma mixing process. Thus, we report our experimental results in conjunction with modeling with MELTS to test the ideas concerning the petrogenesis of Hasan Dagi volcanic rocks and quantitatively model the relevant petrogenetic processes. Our results demonstrate that the chemical diversity of Hasan Dagi volcano is inconsistent with the closed-system crystallization and differentiation. Thus, (1) our experimental modeling, (2) the agreement between the liquid line of descent defined by the natural rock data and the MELTS calculations, and (3) the agreement between the mineralogy of the rocks and calculated mineralogy corroborate the conclusion that the isobaric–isenthalpic magma mixing of basalt and rhyolite is the major controlling process in the petrogenesis of the Hasan Dagi magmas.     

Contemporary Tectonic Movements of the Western Caucasus and the Ciscaucasia Based on Satellite-Geodetic Observations

Geotectonics - The paper presents the velocity field of the Western Caucasus and Ciscaucasia based on GNSS observations. In the ITRF2014 reference frame, this field shows the coordinated movement...     

Speciation and characterization of arsenic in gold ores and cyanidation tailings using X-ray absorption spectroscopy

The knowledge of mineralogy and molecular structure of As is needed to better understand the stability of As in wastes resulting from processing of gold ores. In this study, optical microscopy, scanning electron microscopy, electron microprobe, X-ray diffraction and X-ray absorption fine structure (XAFS) spectroscopy (including both XANES and EXAFS regimes) were employed to determine the mineralogical composition and local coordination environment of As in gold ores and process tailings from bench-scale tests designed to mimic a common plant practice. Arsenic-bearing minerals identified in the ores and tailings include iron (III) oxyhydroxides, scorodite (FeAsO₄·2H₂O), ferric arsenates, arseniosiderite (Ca₂Fe₃(AsO₄)₃O₂·3H₂O), Ca-Fe arsenates, pharmacosiderite (KFe₄(AsO₄)₃(OH)₄·6-7H₂O), jarosite (K₂Fe₆(SO₄)₄(OH)₁₂) and arsenopyrite (FeAsS). Iron (III) oxyhydroxides contain variable levels of As from trace to about 22 wt% and Ca up to approximately 9 wt%.Finely ground ore and tailings samples were examined by bulk XAFS and selected mineral grains were analyzed by microfocused XAFS (micro-EXAFS) spectroscopy to reconcile the ambiguities of multiple As sources in the complex bulk EXAFS spectra. XANES spectra indicated that As occurs as As⁵⁺in all the samples. Micro-EXAFS spectra of individual iron (III) oxyhydroxide grains with varying As concentrations point to inner-sphere bidentate-binuclear arsenate complexes as the predominant form of As. There are indications for the presence of a second Fe shell corresponding to bidentate-mononuclear arrangement. Iron (III) oxyhydroxides with high As concentrations corresponding to maximum adsorption densities probably occur as nanoparticles. The discovery of Ca atoms around As in iron (III) oxyhydroxides at interatomic distances of 4.14-4.17 Å and the coordination numbers suggest the formation of arseniosiderite-like nanoclusters by coprecipitation rather than simple adsorption of Ca onto iron (III) oxyhydroxides. Correlation of Ca with As in iron (III) oxyhydroxides as determined by electron microprobe analysis supports the coprecipitate origin for the presence of Ca in iron (III) oxyhydroxides.The samples containing higher abundances of ferric arsenates released higher As concentrations during the cyanidation tests. The presence of highly soluble ferric arsenates and Ca-Fe arsenates, and relatively unstable iron (III) oxyhydroxides with Fe/As molar ratios of less than 4 in the ore and process tailings suggests that not only the tailings in the impoundment will continue to release As, but also there is the potential for mobilization of As from the natural sources such as the unmined ore.     

Temporal changes of soft-bottom zoobenthic communities in and around Alsancak Harbor (Izmir Bay, Aegean Sea), with special attention to the autecology of exotic species

Temporal and spatial variation in soft‐bottom benthic communities following recovery from a pollution episode were studied between January and September 2004 in and around Alsancak Harbor, located in the polluted part of Izmir Bay (Aegean Sea, eastern Mediterranean). Samples were collected at seven stations by van Veen grab. Three additional stations were sampled by means of a beam trawl to take into account large mobile animals and for a better estimate of the local biodiversity. A total of 231 species belonging to 10 zoobenthic groups were found. Polychaetes contributed 90% of the total faunal populations and mollusks 87% of the total biomass in the area. Community parameters varied significantly among stations and sampling periods; number of species ranged from 2 to 79 per 0.1 m² grab sample; density from 20 to 81,720 ind·m^?2; biomass from 0.1 to 4190 g·m^?2; Shannon–Wiener diversity index (log₂ base) from 0.4 to 4.4; and Pielou's evenness index from 0.11 to 1.0. Collections indicate that a number of species, including those sensitive to pollution, have colonized the area where azoic conditions had been previously reported. A total of six exotic species, Streblospio gynobranchiata, Polydora cornuta, Hydroides dianthus, Hydroides elegans, Anadara demiri and Fulvia fragilis, probably transferred to the area via ballast water or hull fouling, dominated soft or hard substrata in and near Alsancak Harbor. The first two species accounted for more than 70% of the total population in the area, while A. demiri contributed the most to the biomass (93%, at station 7).     

Mineral composite assessment of Kelkit River Basin in Turkey by means of remote sensing

Utilizing remote sensing (RS) and geographic information systems (GIS) tools, mineral composite characteristics (ferrous minerals (FM), iron oxide (IO), and clay minerals (CM)) of the Kelkit River Basin (15913.07 km²) in Turkey were investigated and mapped. Mineral composite (MC) index maps were produced from three LANDSAT-ETM+ satellite images taken in 2000. Resulting MC index maps were summarized in nine classes by using ‘natural breaks’ classification method in GIS. Employing bi-variety correlation analysis, relationships among index maps were investigated. According to the results, FM and IO index maps showed positive correlation, while CM index map is negatively correlated with FM and IO index maps. Negative correlations between iron and clay variables suggested that the dominant clay minerals of the study area might be smectite, illite, kaolinite, and chlorite, which have little or no iron content. Using field data for which their geographic coordinates had been determined by global positioning system (GPS), developed MC maps were verified, and found dependable for environmental and ecological modeling studies.     

Synthesis and phase transformations involving scorodite, ferric arsenate and arsenical ferrihydrite: Implications for arsenic mobility

Scorodite, ferric arsenate and arsenical ferrihydrite are important arsenic carriers occurring in a wide range of environments and are also common precipitates used by metallurgical industries to control arsenic in effluents. Solubility and stability of these compounds are controversial because of the complexities in their identification and characterization in heterogeneous media. To provide insights into the formation of scorodite, ferric arsenate and ferrihydrite, series of synthesis experiments were carried out at 70 °C and pH 1, 2, 3 and 4.5 from 0.2 M Fe(SO₄)_1.5 solutions also containing 0.02-0.2 M Na₂HAsO₄. The precipitates were characterized by transmission electron microscopy, X-ray diffraction and X-ray absorption fine structure techniques. Ferric arsenate, characterized by two broad diffuse peaks on the XRD pattern and having the structural formula of FeAsO₄·4-7H₂O, is a precursor to scorodite formation. As defined by As XAFS and Fe XAFS, the local structure of ferric arsenate is profoundly different than that of scorodite. It is postulated that the ferric arsenate structure is made of single chains of corner-sharing Fe(O,OH)₆ octahedra with bridging arsenate tetrahedra alternating along the chains. Scorodite was precipitated from solutions with Fe/As molar ratios of 1 over the pH range of 1-4.5. The pH strongly controls the kinetics of scorodite formation and its transformation from ferric arsenate. The scorodite crystallite size increased from 7 to 33 nm by ripening and aggregation. Precipitates, resulting from continuous synthesis at pH 4.5 from solutions having Fe/As molar ratios ranging from 1 to 4 and resembling the compounds referred to as ferric arsenate, arsenical ferrihydrite and As-rich hydrous ferric oxide in the literature, represent variable mixtures of ferric arsenate and ferrihydrite. When the Fe/As ratio increases, the proportion of ferrihydrite increases at the expense of ferric arsenate. Arsenate adsorption appears to retard ferrihydrite growth in the precipitates with molar Fe/As ratios of 1-4, whereas increased reaction gradually transforms two-line ferrihydrite to six-line ferrihydrite at Fe/As ratios of 5 and greater.     

Pressure Dependence of Cymbal Transducers

The hydrostatic pressure limit that a receiver can withstand without failure is of major importance in underwater sonar systems. In this paper, the hydrostatic pressure tolerance and sensitivity of cymbal receivers were investigated. The failure mode in cymbal transducers under hydrostatic pressure is described. Effects of cavity geometry and material selection on hydrostatic piezoelectric coefficients and pressure limits were evaluated using both experimental data and finite-element analysis (FEA). It was found that cavity depth has a very strong effect on the stability of underwater sensitivity and pressure tolerance of these devices. Cymbals made with soft piezoelectric transducers (PZTs) possess higher figures of merit and better pressure tolerance than those made with hard PZTs. Alternatively, the cymbal sensitivity and pressure tolerance can be improved by changing the cap material.