Effect of chelation on toxicity of copper

Metals in the sea may form complexes with organic compounds, a process known as chelation, and this may modify their properties very greatly. Here the effect of chelation on the toxicity of copper to algae has been studied in the laboratory using the powerful chelating agent EDTA. Similar phenomena in the sea have implications both for anti-fouling paints, which usually contain copper, and for metal pollution in waters with a high organic content.     

On the origin of solar metric type II bursts

The vast majority of solar flares are not associated with metric Type II radio bursts. For example, for the period February 1980–July 1982, corresponding to the first two and one-half years of the Solar Maximum Mission, 95% of the 2500 flares with peak >25 keV count rates >100 c s^–1lacked associated Type II emission. Even the 360 largest flares, i.e., those having >25 keV peak count rates >1000 c s^–1, had a Type II association rate of only 24%. The lack of a close correlation between flare size and Type II occurrence implies the need for a 'special condition' that distinguishes flares that are accompanied by metric Type II radio bursts from those of comparable size that are not. The leading candidates for this special condition are: (1) an unusually low Alfvén speed in the flaring region; and (2) fast material motion. We present evidence based on SMM and GOES X-ray data and Solwind coronagraph data that argues against the first of these hypotheses and supports the second. Type II bursts linked to flares within 30° of the solar limb are well associated (64%; 49/76) with fast (>400 km s^–1) coronal mass ejections (CMEs); for Type II flares within 15° of the limb, the association rate is 79% (30/38). An examination of the characteristics of 'non-CME' flares associated with Type IIs does not support the flare-initiated blast wave picture that has been proposed for these events and suggests instead that CMEs may have escaped detection. While the degree of Type II–CME association increases with flare size, there are notable cases of small Type II flares whose outstanding attribute is a fast CME. Thus we argue that metric Type II bursts (as well as the Moreton waves and kilometric Type II bursts that may accompany them) have their root cause in fast coronal mass ejections.     

Infrared photometry of comets Bowell and P/Stephan-Oterma

We report broadband infrared photometry of comets P/Stephan-Oterma and Bowell between 1 and 20 μm. Their JHK colors are similar to P/Meier and P/Tuttle and are compatible with scattering of sunlight by micron-sized grains. The thermal emission from P/Stephan-Oterma showed an effective temperature significantly higher than that expected from a blackbody in equilibrium. The thermal emission can be models be fit by models of the dust coma consisting of micron-sized grains. Most of the flux at all observed wavelengths comes from the dust grains rather than form the nucleus.     

Numerical simulation of the plasma double layer

A one-dimensional particle-in-cell computer simulation is used to model the formation of an electrostatic double layer. The conditions for the onset of the layer formation are explored and a relation between the length of the layer and the electrostatic potential difference across is found.     

The relativistic quasilinear theory of particle acceleration by hydromagnetic turbulence

The quasilinear theory of acceleration of relativistic particles by hydromagnetic turbulence is treated in the adiabatic limit of small gyration radius. The theory is based on the relativistic Vlasov equation; however, a given pitch-angle scattering rate by microturbulence is postulated and is added to this equation. The resulting acceleration is found to be given by a diffusion coefficient in total momentum, which is proportional to the spectrum of turbulence with a rate coefficient . is a frequency that represents the efficiency of each wave component of the turbulence in producing acceleration. It is given as an integral over the solution of a differential equation in pitch angle. is evaluated in various limiting cases and is shown to lead to familiar forms of acceleration, such as Fermi acceleration and magnetic pumping. Thus, a comprehensive theory of these forms of heating is achieved.     

A theoretical investigation of bed-form shapes

The deformation of movable boundaries under the action of an applied turbulent shear stress is well known. The resulting bed forms often are highly organized and nearly two-dimensional, which makes them an intriguing focus of study considering that they are generated in both steady and oscillatory turbulent flows. Many past studies share a common approach in which an infinitesimal perturbation is prescribed and the resulting growth or decay patterns are examined. In this approach, the bed forms are usually sinusoidal and the perturbation analysis does not provide a theoretical prediction of equilibrium bed-form geometry. An alternative approach is suggested here in which the forcing terms (pressure and stress) are prescribed parametrically and the governing equations are solved for the flow velocity and the associated boundary deformation. Using a multilayered approach, in which the bottom boundary layer is divided into a discrete, yet, arbitrary number of finite layers, analytical solutions for the horizontal current and bed profile are derived. The derivations identify two nondimensional parameters, p₀/u₀² and ₀/kh₀u₀², which modulate the amplitude of the velocity fluctuations and boundary deformation. For the case of combined pressure and stress divergence anomalies, the magnitude of the front face and lee slopes exhibit an asymmetry that is consistent with observed bed forms in steady two-dimensional flows.Responsible Editor: Jens Kappenberg     

Natural and artificial connections between atoll islets in the pacific,their process and environmental impact

Three types of natural connection between atoll islets are described. Causeway, as an artificial way of connecting islets, makes a connection to be completed in a few months. In this case shore adjustment becomes more vigorous than that in natural conditions, resulting in lagoon shore erosion. A causeway without short bridges or culverts should be built close to the lagoon shore to reduce lagoon shore erosion. A causeway-crossing channel assemblage is the worst type among all of the connection engineering constructions because the crossing channel traps sediment and further transports it out of the channel, resulting in long period coastal erosion. Reforming Nippon Causeway in Tarawa Atoll, Kiribati by simple means will stop sand loss, reduce shore erosion and greatly upgrade its stability.     

Contaminant concentrations in sport fish from San Francisco Bay, 1997

In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%.     

Short-Period Waves That Heat the Corona Detected at the 1999 Eclipse

As a part of a study of the cause of solar coronal heating, we searched for high-frequency (1 Hz) intensity oscillations in coronal loops in the [Fexiv] coronal green line. We summarize results from observations made at the 11 August 1999 total solar eclipse from Râmnicu-Vâlcea, Romania, through clear skies. We discuss the image reduction and analysis through two simultaneous series of coronal CCD images digitized at 10 Hz for a total time of about 140 s. One series of images was taken through a 3.6 Å filter isolating the 5303 Å[Fexiv] coronal green line and the other through a 100 Å filter in the nearby K-corona continuum. Previous observations, described in Pasachoff et al. (2000), showed no evidence for oscillations in the [Fexiv] green line at a level greater than 2% of coronal intensity. We describe several improvements made over the 1998 eclipse that led to increased image clarity and sensitivity. The corona was brighter in 1999 with the solar maximum, further improving the data. We use Fourier analysis to search in the [Fexiv] channel for intensity oscillations in loops at the base of the corona. Such oscillations in the 1-Hz range are predicted as a result of density fluctuations from the resonant absorption of MHD waves. The dissipation of a significant amount of mechanical energy from the photosphere into the corona through this mechanism could provide sufficient energy to heat the corona. A Monte Carlo model of the data suggests the presence of enhanced power, particularly in the 0.75–1.0 Hz range, and we conclude that MHD waves remain a viable method for coronal heating.