Interstitial water chemistry of villefranche bay sediments: Trace metal diagenesis

Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO₂, SO₄, TH₂S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO₂/ΔSO₄ was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides.     

Power from the people: a documentation of non-governmental organizations' experience in community-based coastal resource management in the Philippines

Community-based coastal resource management projects facilitated by non-governmental organizations (NGOs) in the Philippines have explored approaches to decrease poverty-driven over-exploitation of coastal resources. There has been little reporting and analysis of such activities until recently. Nine case studies have recently been published and this paper presents a brief summary of these, along with an analysis of the trends and themes identified. Though diverse and covering the Philippines from Mindanao to Luzon, the case studies highlight the value of community commitment and participation in decisions regarding, and in the implementation of, resource management in ways that consider not only the bio-physical aspects of resource management but the social, economic and legal implications. Experience in working with local government has been both successful and limited. Successful projects raise hopes for further progress through education and organization of communities to improve livelihoods and protect coastal resources.     

Numerical modelling of the seasonal variability of the North and Tropical Atlantic currents using an adaptation approach

The paper reports computed data on the seasonal variability of the Atlantic Ocean currents which were obtained through numerical integration (using conservative difference schemes) of non-linear equations of hydrothermodynamics taking into account an upper quasi-homogeneous layer and the bottom topography. The seasonal variability of the meridional heat transfer is discussed. The results were obtained using an adaptation approach.Translated by Vladimir A. Puchkin.     

Concentration du chrome dans deux profils de l'ocean pacifique

Determination of total chromium on two profiles and chromium III on four samples of equatorial Pacific Ocean water have been carried out using coprecipitation of chromium from sea water with hydrous iron oxides, followed by ion-exchange separation and isotope dilution mass spectrometry. Results for two Pacific profiles show increasing total chromium concentration from surface to 250 m. The Cr concentration appears to be different below 1,000 m, with nearly homogeneous concentrations for the first profile and regularly increasing Cr concentrations from 0.330 to 0.550 μg/l at 3,900 m for the second one. Results for Cr(III) show that trivalent species are dominant in these samples.     

Measurement of DNA single-strand breaks in gill and hemolymph cells of mussels, Mytilus sp., collected on the French Atlantic Coast

DNA single-strand breaks were measured by the comet assay in both gill and hemolymph cells of mussels collected in 3 sampling areas of the French coast (Pointe du Castelli, Pen Bron and Saint-Nazaire Harbour). Whole mussel tissue samples were also collected for the chemical determination of PAH, PCB and heavy metal concentrations. In mussel, a higher level of DNA strand breaks was measured in gill than in hemolymph cells (p < 0.01). Despite a factor of contamination from 2 to 3 between sites, no difference in the extent of mussel DNA strand breaks was shown between sampling locations (p > 0.05), questioning the sensitivity of the assays used in biomonitoring studies.     

Hydrocarbons in bivalve mollusks of Port Valdez, Alaska: Consequences of five years' permitted discharge

Petroleum hydrocarbons were investigated in Mytilus edulis and Macoma balthica at six intertidal sites in Port Valdez, Alaska after three to five years of oil terminal operation. Information about the concentrations of total hydrocarbons, unresolved complex mixture, normal alkanes, isoprenoids, olefins, hopanes and polycyclic aromatic hyrocarbons shows that petroleum accumulation in these bivalve mollusks is greatest at the Valdez municipal boat harbor and a crude oil terminal which has been permitted to discharge 170 kg oil day⁻¹. Accumulation two- to ten-fold less were observed at 3 km from the terminal and boat harbor. The temporal trends in petroleum hydrocarbon concentrations in M. edulis and M. balthica reflect the effects of selective retention and depuration of different hydrocarbon classes as well as variation in hydrocarbon sources. It is not clear whether the petroleum concentrations in Port Valdez bivalves had reached steady state by 1982, the final sampling time reported here.