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991.
Fiona?V.?FoleyEmail author Simon?Turner Tracy?Rushmer John?T.?Caulfield Nathan?R.?Daczko Paul?Bierman Matthew?Robertson Craig?D.?Barrie Adrian?J.?Boyce 《Contributions to Mineralogy and Petrology》2014,168(3):1048
Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO2) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. 10Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites. 相似文献
992.
Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data. 相似文献
993.
The rare-earth element (REE) concentrations of representative granite samples from the southeast of the Obudu Plateau, Nigeria, were analyzed with an attempt to determine the signatures of their source, evolutionary history and tectonic setting. Results indicated that the granites have high absolute REE concentrations (190×10^-6-1191×10^-6; av.=549×10^-6) with the chondrite-normalized REE patterns characterized by steep negative slopes and prominent to slight or no negative Eu anomalies. All the samples are also characterized by high and variable concentrations of the LREE (151×10^-6-1169×10^-6; av.= 466×10^-6), while the HREE show low abundance (4×10^-6-107×10^-6; av.=28×10^-6). These are consistent with the variable levels of REE fractionation, and differentiation of the granites. This is further supported by the range of REE contents, the chondrite-normalized patterns and the ratios of LaN/YbN (2.30-343.37), CeN/YbN (5.94-716.87), LaN/SmN (3.14-11.68) and TbN/YbN (0.58-1.65). The general parallelism of the REE patterns, suggest that all the granites were comagmatic in origin, while the high Eu/Eu* ratios (0.085-2.807; av.=0.9398) indicate high fo2 at the source. Similarly, irregular variations in LaN/YbN, CeN/YbN and Eu/Eu* ratios and REE abundances among the samples suggest behaviors that are related to mantle and crustal sources. 相似文献
994.
T. Geisler 《Physics and Chemistry of Minerals》2002,29(6):420-429
Raman spectroscopy and the powder diffraction technique have been used to monitor the recovery process of two partially metamict
zircons (2.6 and 4.8 × 1018
α-decays g−1) from Sri Lanka during a series of isothermal annealing experiments in the temperature range from 870 to 1622 K. These experiments
show for the first time that structural recovery in partially metamict zircon proceeds via three distinct recovery stages,
each of which occurs within a distinct time-temperature regime. Whereas the first two stages have previously been recognized
(recovery of damaged crystalline remnants and epitaxial recrystallization), the third stage has not yet been identified as
a single activated process. It is suggested that anisotropic defect annealing during the first stage at low temperatures,
where the structure recovers preferentially along the a(b) plane, produces a geometrical situation where large structural rearrangements are necessary to remove the remaining defects
inside the crystalline material. This situation is approximately reached when the amorphous domains start to recrystallize.
The reason for anisotropic annealing can be found in a different connectivity between polyhedral linkages in both directions
of the zircon lattice. High apparent activation energies, in the range of 6.4 to 7.9 eV, were determined for the third recovery
stage from the Raman data, which are interpreted to reflect large structural rearrangements (i.e. polyhedral tilting) associated
with the final recovery of the c axis. This explains the occurrence of a distinct recrystallization stage without defect annealing. Finally, it should be
mentioned that the first recovery stage is not necessarily expected to occur in less damaged zircon crystals (<∼2 × 1018
α-decays g−1), since less stable defects along the basal plane might have already been self-annealed during radiation damage accumulation
under ambient temperatures.
Received: 6 September 2001 / Accepted: 25 February 2002 相似文献
995.
The Purang ophiolite, which crops out over an area of about 600 km2 in the western Yarlung‐Zangbo suture zone, consists chiefly of mantle peridotite, pyroxenite and gabbro. The mantle peridotites are mostly harzburgite and minor lherzolite that locally host small pods of dunite. Some pyroxenite and gabbro veins of variable size occur in the peridotites, and most of them strike NW. On the basis of their mineral chemistry podiform chromitites are divided into high‐alumina (Cr# = 20‐60) (Cr# = 100*Cr/(Cr+Al)) and high‐chromium (Cr# = 60‐80) varieties (Thayer, 1970). Typically, only one type occurs in a given peridotite massif, although some ophiolites contain several massifs which can have different chromitite compositions. However, the Purang massif contains both high chrome and high alumina chromitites within a single mafic‐ultramafic body. Seven small, lenticular bodies of chromitite ore have been found in the harzburgite, with ore textures ranging from massive to disseminated to sparsely disseminated; no nodular ore has been observed. Individual ore bodies are 2‐6 m long, 0.5‐2 m wide and strike NW, parallel to the main structure of the ophiolite. Ore bodies 1 and 6 consist of Al‐rich chromitite (Cr# = 52‐55), whereas orebodies 2, 3, 4 and 5 are Cr‐rich varieties (Cr # = 63 to 89). In addition to magnesiochromite, all of the orebodies contain minor olivine, amphibole and serpentine. Mineral structures show that the peridotites experienced plastic deformation and partial melting. On the basis of magnesiochromite and olivine/clinopyroxene compositions two stages of partial melting are identified in the Purang peridotites, an early low‐partial melting event (about 8%), and a later high‐partial melting event (about 40%). We interpret the Al‐rich chromitites as the products of early MORB magmas, whereas the Cr‐rich varieties are thought to have been generated by the later SSZ melts.. 相似文献
996.
Margaret A. LeMone Robert L. Grossman Robert T. Mcmillen Kuo-Nan Liou S.C. Ou Stuart Mckeen Wayne Angevine Kyoko Ikeda Fei Chen 《Boundary-Layer Meteorology》2002,104(1):1-52
Aircraft, radiosonde, surface-flux, and boundary-layer windprofiler data from the Cooperative Atmosphere Surface Exchange Study's 1997 field project, CASES-97, are combined with synoptic data to study the evolution of the vertically-averaged mixed-layerpotential temperature []and mixing-ratio [Q] onthree nearly-cloudless days from 1000 CST to 1200CST (local noon is approximately 1230 CST). This was achieved through examination of the terms in the time-tendency (`budget')equations for []and [Q]. We estimate three of the terms –local time rate of change, vertical flux divergence, andhorizontal advection. For the [Q]-budget, vertical flux divergence usually dominates, buthorizontal advection is significant on one of the three days. The [Q]-budget balances for two of the three days to within the large experimental error. For the -budget,vertical flux divergence accounts for most of the morningwarming, with horizontal advection of secondary importance.The residual in the -budget has the same sign for all three days, indicating that not all the heating is accounted for. We can balance the []-budgets to within experimental error on two of the three days by correcting the vertical-flux divergence for apparent low biases in the flux measurements of one of the aircraft and in the surface fluxes, and accounting for direct heating of the mixed layer by radiative flux divergence allowing for the effects of carbonaceous aerosols. The [];-budget with these corrections also balances on the third day if horizontal gradients from synoptic maps are used to estimate the horizontal advection. However, the corrected budget for this day does not balance if the horizontal gradient in the advection term is estimated using CASES-97aircraft and radiosondes; we suggest that persistent mesoscale circulations led to an overestimate of the horizontal gradient andhence horizontal advection. 相似文献
997.
G.K. PLATTNER F. JOOS T. F. STOCKER O. MARCHAL 《Tellus. Series B, Chemical and physical meteorology》2001,53(5):564-592
Global warming simulations are performed with a coupled climate model of reduced complexity to investigate global warming–marine carbon cycle feedbacks. The model is forced by emissions of CO2 and other greenhouse agents from scenarios recently developed by the Intergovernmental Panel on Climate Change and by CO2 stabilization profiles. The uptake of atmospheric CO2 by the ocean is reduced between 7 to 10% by year 2100 compared to simulations without global warming. The reduction is of similar size in the Southern Ocean and in low‐latitude regions (32.5°S‐32.5°N) until 2100, whereas low‐latitude regions dominate on longer time scales. In the North Atlantic the CO2 uptake is enhanced, unless the Atlantic thermohaline circulation completely collapses. At high latitudes, biologically mediated changes enhance ocean CO2 uptake, whereas in low‐latitude regions the situation is reversed. Different implementations of the marine biosphere yield a range of 5 to 16% for the total reduction in oceanic CO2 uptake until year 2100. Modeled oceanic O2 inventories are significantly reduced in global warming simulations. This suggests that the terrestrial carbon sink deduced from atmospheric O2 /N2 observations is potentially overestimated if the oceanic loss of O2 to the atmosphere is not considered. 相似文献
998.
T. Maitani 《Boundary-Layer Meteorology》1989,48(1-2):19-31
Observations of wind velocity and air temperature fluctuations were made in the nocturnal surface inversion layer over a sorghum field. Wave-like fluctuations of temperature and wind velocity with a period of 15–20 min were observed for about 2 hours, 3 to 5 hours before sunrise. Wave-like fluctuations of temperature were observed in the air layer above and within a plant canopy and were most noticeable at the top of the plant canopy. Spectral analysis of temperature and wind velocity fluctuations reveals a separation of energy into wave-like and turbulent fluctuations. Cospectral analysis shows that for both momentum and heat, vertical transports are partitioned almost equally in the frequency ranges characteristic of wave-like and turbulent fluctuations. This suggests wave- turbulence interactions at low frequencies in the air layer near a plant canopy. 相似文献
999.
I.N. Panchishkina G.G. Petrova A.I. Petrov T.V. Kudrinskaja 《Atmospheric Research》2009,91(2-4):238-243
The correlation of mechanical transfer current from the atmosphere to the ground with the process of space charge formation as a result of conductivity current divergence near ground is under discussion in this research. Experimental data of conductivity current and mechanical transfer current acquired at three observation points for different meteorological conditions are analyzed. In particular, the peculiarities of mechanical charge transfer to ground under different stratifications of the surface layer are under discussion. 相似文献
1000.
Summary ?The shallow water equations are formulated on the sphere in a three-dimensional coordinate system with the aid of tangential
velocity components and differential operators. We introduce a modified semi-Lagrangian scheme for the discretization in time.
The discretization in space is solved by linear finite elements. The grids we use are regular refinements of a macro triangulation
which itself is derived from a highly symmetric polyeder also known as a bucky or soccer ball. The good numerical results
show that this combination is a promising approach. The numerical algorithm is stable and its strength is the conservation
of mass and energy.
Received April 13, 2001; Revised December 18, 2001 相似文献