Contribution of SHRIMP U–Pb zircon geochronology to unravelling the evolution of Brazilian Neoproterozoic fold belts

The South-American continent is constituted of three major geologic–geotectonic entities: the homonym platform (consolidated at the end of the Cambrian), the Andean chain (essentially Meso-Cenozoic) and the Patagonian terrains, affected by tectonism and magmatism through almost all of the Phanerozoic. The platform is constituted by a series of cratonic nuclei (pre-Tonian, fragments of the Rodinia fission) surrounded by a complex fabric of Neoproterozoic structural provinces.     

A new estimate of global methane flux from onshore and shallow submarine mud volcanoes to the atmosphere

A new estimate of global methane emission into the atmosphere from mud volcanoes (MVs) on land and shallow seafloor is presented. The estimate, considered a lower limit, is based on 1) new direct measurements of flux, including both venting of methane and diffuse microseepage around craters and vents, and 2) a classification of MV sizes in terms of area (km²) based on a compilation of data from 120 MVs. The methane flux to the atmosphere is conservatively estimated between 6 and 9 Mt y^–1. This emission from MVs is 3–6% of the natural methane sources and is comparable with ocean and hydrate sources, officially considered in the atmospheric methane budget. The total geologic source, including MVs, seepage from seafloor, microseepage in hydrocarbon-prone areas and geothermal sources, would amount to 35–45 Mt y^–1. The authors believe it is time to add this parameter in the Intergovernmental Panel on Climate Change official tables of atmospheric methane sources.GEM     

A direct scaling analysis for the sea level rise

The estimation of long-term sea level variability is of primary importance for a climate change assessment. Despite the value of the subject, no scientific consensus has yet been reached on the existing acceleration in observed values. The existence of this acceleration is crucial for coastal protection planning purposes. The absence of the acceleration would enhance the debate on the general validity of current future projections. Methodologically, the evaluation of the acceleration is a controversial and still open discussion, reported in a number of review articles, which illustrate the state-of-art in the field of sea level research. In the present paper, the well-proven direct scaling analysis approach is proposed in order to describe the long-term sea level variability at 12 worldwide-selected tide gauge stations. For each of the stations, it has been shown that the long-term sea level variability exhibits a trimodal scaling behaviour, which can be modelled by a power law with three different pairs of shape and scale parameters. Compared to alternative methods in literature, which take into account multiple correlated factors, this simple method allows to reduce the uncertainties on the sea level rise parameters estimation.     

Seismic response of L��Aquila downtown from comparison between 2D synthetics spectral ratios of SH, P-SV and Rayleigh waves and observations of the 2009 earthquake sequence

This is the first part of a study on the seismic response of the L’Aquila city using 2D simulation and experimental data. We have studied two velocity-depth models with the aim of outlining the behavior of a velocity reversal in the top layer, which is associated with the stiff Brecce de L’Aquila unit (BrA). In this setting, the SMTH model is topped by a layer with about 2:1 impedance contrast with the underlying layer while the NORV model has no velocity reversal. We have simulated the propagation of SH and P-SV wavefields in the range 0–10 Hz for incidence 0°–90°. Earthquake spectral ratios of the horizontal and vertical components at six sites in L’Aquila downtown are compared to corresponding synthetics spectral ratios. The vertical component of P-SV synthetics enables us to investigate a remarkable amplification effect seen in the vertical component of the recorded strong motion. Sites AQ04 and AQ05 are best matched by synthetics from the NORV model while FAQ5 and AQ06 have a better match with synthetics spectral ratios from the SMTH model. All simulations show this behavior systematically, with horizontal and near-horizontal incident waves predicting the overall pattern of matches more clearly than vertical and near-vertical incidence. The model inferences are in agreement with new geological data reporting lateral passages in the top layer from the stiff BrA to softer sediments. Matches are good in terms of frequency of the first amplification peak and of spectral amplitude: the horizontal components have spectral ratio peaks predominantly at 0.5 Hz in the simulations and at 0.7 Hz in the data, both with amplitudes of 4, while the vertical component spectral ratios reach values of 6 at frequencies of about 1 Hz in both data and simulations. The vertical component spectral ratios are very well matched using Rayleigh waves with incidence at 90°. The NORV model without the velocity reversal predicts spectral ratio peaks for the horizontal components at frequencies up to 6 Hz. The reversal of velocity acts as a low-pass frequency filter on the horizontal components reducing the amplification effect of the sediment filled valley.     

In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

Hydrocarbon lakes on Titan

The Huygens Probe detected dendritic drainage-like features, methane clouds and a high surface relative humidity (∼50%) on Titan in the vicinity of its landing site [Tomasko, M.G., and 39 colleagues, 2005. Nature 438, 765-778; Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784], suggesting sources of methane that replenish this gas against photo- and charged-particle chemical loss on short (10-100) million year timescales [Atreya, S.K., Adams, E.Y., Niemann, H.B., Demick-Montelara, J.E., Owen, T.C., Fulchignoni, M., Ferri, F., Wilson, E.H., 2006. Planet. Space Sci. In press]. On the other hand, Cassini Orbiter remote sensing shows dry and even desert-like landscapes with dunes [Lorenz, R.D., and 39 colleagues, 2006a. Science 312, 724-727], some areas worked by fluvial erosion, but no large-scale bodies of liquid [Elachi, C., and 34 colleagues, 2005. Science 308, 970-974]. Either the atmospheric methane relative humidity is declining in a steady fashion over time, or the sources that maintain the relative humidity are geographically restricted, small, or hidden within the crust itself. In this paper we explore the hypothesis that the present-day methane relative humidity is maintained entirely by lakes that cover a small part of the surface area of Titan. We calculate the required minimum surface area coverage of such lakes, assess the stabilizing influence of ethane, and the implications for moist convection in the atmosphere. We show that, under Titan's surface conditions, methane evaporates rapidly enough that shorelines of any existing lakes could potentially migrate by several hundred m to tens of km per year, rates that could be detected by the Cassini orbiter. We furthermore show that the high relative humidity of methane in Titan's lower atmosphere could be maintained by evaporation from lakes covering only 0.002-0.02 of the whole surface.     

Thermal convection in ice-I shells of Titan and Enceladus

Cassini-Huygens observations have shown that Titan and Enceladus are geologically active icy satellites. Mitri and Showman [Mitri, G., Showman, A.P., 2005. Icarus 177, 447-460] and McKinnon [McKinnon, W.B., 2006. Icarus 183, 435-450] investigated the dynamics of an ice shell overlying a pure liquid-water ocean and showed that transitions from a conductive state to a convective state have major implications for the surface tectonics. We extend this analysis to the case of ice shells overlying ammonia-water oceans. We explore the thermal state of Titan and Enceladus ice-I shells, and also we investigate the consequences of the ice-I shell conductive-convective switch for the geology. We show that thermal convection can occur, under a range of conditions, in the ice-I shells of Titan and Enceladus. Because the Rayleigh number Ra scales with δ³/ηb, where δ is the thickness of the ice shell and ηb is the viscosity at the base of the ice-I shell, and because ammonia in the liquid layer (if any) strongly depresses the melting temperature of the water ice, Ra equals its critical value for two ice-I shell thicknesses: for relatively thin ice shell with warm, low-viscosity base (Onset I) and for thick ice shell with cold, high-viscosity base (Onset II). At Onset I, for a range of heat fluxes, two equilibrium states—corresponding to a thin, conductive shell and a thick, convective shell—exist for a given heat flux. Switches between these states can cause large, rapid changes in the ice-shell thickness. For Enceladus, we demonstrate that an Onset I transition can produce tectonic stress of ∼500 bars and fractures of several tens of km depth. At Onset II, in contrast, we demonstrate that zero equilibrium states exist for a range of heat fluxes. For a mean heat flux within this range, the satellite experiences oscillations in surface heat flux and satellite volume with periods of ∼50-800 Myr even when the interior heat production is constant or monotonically declining in time; these oscillations in the thermal state of the ice-I shell would cause repeated episodes of extensional and compressional tectonism.     

Constitutive modeling of structured granular materials with anisotropic grain skeleton and cement bonds

Acta Geotechnica - Structured granular materials exhibit strongly anisotropic mechanical behaviours resulting from the directional properties of their microstructural components such as grain...     

人为因素导致的地面沉降

天然气、石油、地下水、地热热水和卤水等流体运移出地下储存地层时,地层耗尽了流体而产生压缩变形,这些变形传递到地表表面就形成了人为的地面沉降。在本文中:(1)列举了世界上主要的地面沉降区域;(2)论述了引发地面沉降的力学机制,这些可以量测的地面沉降发生在地下含水层体系、天然气气田和石油油田之上;(3)描述了目前可以用于地面沉降测量和岩石变形原位测试的技术手段;(4)简要介绍了几个地面沉降预测的数值模型;(5)说明了用于控制地面沉降发展和减轻相关环境影响的几种防治措施。