Selective chemical extraction of carbonate-associated metals from recent lacustrine sediments

Acidic ion-exchanger was applied to the selective extraction of heavy metals in carbonate phases of recent lake sediments. Cr was not detected and Fe and Cu contents were reduced by factors of three to ten, relative to non-carbonate fractions of the sediment samples. Values obtained for Mn and Zn exemplify the effects of dilution was well as enrichment, both originating from increased carbonate percentages. Determinations on grain-sized fractions from Bodensee samples suggest that elevated inputs of dissolved Zn, which partly originate from human activities, may be immobilized by authigenic carbonate precipitation.     

Investigation of spheroidal weathering and twinning

What determines the geometry of spheroidal weathering patterns? Spheroidal weathering rings appear to arise from the leaching of fresh rock, rather than from reprecipitation of dissolved minerals diffusing out of weathered rock. In previous work the authors developed a mathematical model to explain the geometry of spheroidal weathering structures, and showed how some of the features of weathering patterns, otherwise difficult to explain, were natural consequences of the model. In describing the geometrical aspect of these shapes, we hope to understand how natural forces acted upon the unweathered rock and why and under what conditions spheroidal weathering structures were formed. In this paper we review the main features of our model and examine and discuss twinning of spheroidal weathering structures, concluding that the structures were formed during a distinct period in the past. Twinning is an apparent anomaly in that its natural occurrence, as part of the weathering process, cannot be explained by our model without additional ad hoc assumptions. Careful examination of twins reveals an explanation which does not require revision of the model.     

The distribution of megablocks in the Ries crater,Germany: Remote sensing,field investigation,and statistical analyses

The Ries crater is a well‐preserved, complex impact crater that has been extensively used in the study of impact crater formation processes across the solar system. However, its geologic structure, especially the megablock zone, still poses questions regarding crater formation mechanics. The megablock zone, located between the inner crystalline ring and outer, morphologic crater rim, consists of allochthonous crystalline and sedimentary blocks, Bunte Breccia deposits, patches of suevite, and parautochthonous sedimentary blocks that slumped into the crater during crater modification. Our remote sensing detection method in combination with a shallow drilling campaign and geoelectric measurements at two selected megablocks proved successful in finding new megablock structures (>25 m mean diameter) within the upper approximately 1.5 m of the subsurface in the megablock zone. We analyzed 1777 megablocks of the megablock zone, 81 of which are new discoveries. In our statistical analysis, we also included 2318 ejecta blocks >25 m beyond the crater rim. Parautochthonous megablocks show an increase in total area and size toward the final crater rim. The sizes of allochthonous megablocks generally decrease with increasing radial range, but inside the megablock zone, the coverage with postimpact sediments obscures this trend. The size‐frequency distribution of all megablocks obeys a power‐law distribution with an exponent between approximately ?1.7 and ?2.3. We estimated a total volume of 95 km³ of Bunte Breccia and 47 km³ of megablocks. Ejecta volume calculations and a palinspastic restoration of the extension within the megablock zone indicate that the transient cavity diameter was probably 14–15 km.     

Relative timing of last glacial maximum and late-glacial events in the central tropical Andes

Whether or not tropical climate fluctuated in synchrony with global events during the Late Pleistocene is a key problem in climate research. However, the timing of past climate changes in the tropics remains controversial, with a number of recent studies reporting that tropical ice age climate is out of phase with global events. Here, we present geomorphic evidence and an in-situ cosmogenic ³He surface-exposure chronology from Nevado Coropuna, southern Peru, showing that glaciers underwent at least two significant advances during the Late Pleistocene prior to Holocene warming. Comparison of our glacial-geomorphic map at Nevado Coropuna to mid-latitude reconstructions yields a striking similarity between Last Glacial Maximum (LGM) and Late-Glacial sequences in tropical and temperate regions.Exposure ages constraining the maximum and end of the older advance at Nevado Coropuna range between 24.5 and 25.3 ka, and between 16.7 and 21.1 ka, respectively, depending on the cosmogenic production rate scaling model used. Similarly, the mean age of the younger event ranges from 10 to 13 ka. This implies that (1) the LGM and the onset of deglaciation in southern Peru occurred no earlier than at higher latitudes and (2) that a significant Late-Glacial event occurred, most likely prior to the Holocene, coherent with the glacial record from mid and high latitudes. The time elapsed between the end of the LGM and the Late-Glacial event at Nevado Coropuna is independent of scaling model and matches the period between the LGM termination and Late-Glacial reversal in classic mid-latitude records, suggesting that these events in both tropical and temperate regions were in phase.     

Determination of Trace Elements in the Quartz Reference Material UNS-SpS and in Natural Quartz Samples by ICP-MS

A procedure for the digestion and analysis of quartz samples was developed to measure trace element concentrations in natural quartz. The certified glass sand reference material UNS-SpS was chosen to assess the precision, accuracy and detection limit of the analytical method. Quartz was digested with HF/HNO₃ in a closed glassy carbon vessel and analysed by means of quadrupole ICP-MS with external calibration. Analyte concentrations of the sand UNS-SpS were compared with certified and other values from the literature. The abundances of a number of elements (Pr, Gd, Ho and Er) in the reference material are reported here for the first time. The procedure was then applied to three quartz samples from different geological settings to show that trace element data by ICP-MS can distinguish the origin of the sample.     

Weathering profiles in granites, Sierra Norte (Córdoba, Argentina)

Two weathering profiles evolved on peneplain-related granites in Sierra Norte, Córdoba province, were examined. Several weathering levels, of no more than 2 m thickness, were studied in these profiles. They had developed from similar parent rock, which had been exposed to hydrothermal processes of varying intensity. Fracturing is the most notable feature produced by weathering; iron oxides and silica subsequently filled these fractures, conferring a breccia-like character to the rock. The clay minerals are predominantly illitic, reflecting the mineral composition of the protolith. Smaller amounts of interstratified I/S RO type are also present, as well as scarce caolinite+chlorite that originated from the weathering of feldspar and biotite, respectively. The geochemical parameters define the weathering as incipient, in contrast to the geomorphological characteristics of Sierra Norte, which point to a long weathering history. This apparent incompatibility could be due to the probable erosion of the more weathered levels of the ancient peneplains, of which only a few relicts remain. Similar processes have been described at different sites in the Sierras Pampeanas. Reconstruction and dating of the paleosurfaces will make it possible to set time boundaries on the weathering processes studied and adjust the paleographic and paleoclimatic interpretations of this great South American region.