Relative importance of acid coating on ice nuclei in the deposition and contact modes for wintertime Arctic clouds and radiation

Aerosols emitted from volcanic activities and polluted mid-latitudes regions are efficiently transported over the Arctic during winter by the large-scale atmospheric circulation. These aerosols are highly acidic. The acid coating on ice nuclei, which are present among these aerosols, alters their ability to nucleate ice crystals. In this research, the effect of acid coating on deposition and contact ice nuclei on the Arctic cloud and radiation is evaluated for January 2007 using a regional climate model. Results show that the suppression of contact freezing by acid coating on ice nuclei leads to small changes of the cloud microstructure and has no significant effect on the cloud radiative forcing (CRF) at the top of the atmosphere when compared with the effect of the alteration of deposition ice nucleation by acid coating on deposition ice nuclei. There is a negative feedback by which the suppression of contact freezing leads to an increase of the ice crystal nucleation rate by deposition ice nucleation. As a result, the suppression of contact freezing leads to an increase of the cloud ice crystal concentration. Changes in the cloud liquid and ice water contents remain small and the CRF is not significantly modified. The alteration of deposition ice nucleation by acid coating on ice nuclei is dominant over the alteration of contact freezing.     

Challenges of climate change in tropical basins: vulnerability of eco-agrosystems and human populations

Climate change impacts are already happening through the world, and it is now clear that there is the need for an adaptive response from global institutions down to the local level. Reducing vulnerability to cope with climate variability might be more challenging in tropical countries than in North America or Europe. The ten papers of this special issue were presented during the Adaptclim conference that was held by the Sinergia Project, the CLARIS LPB project, and the GeoData Institute in Asunción, Paraguay, in 2010. All papers, except one regarding the Brahmaputra Basin in South Asia, present studies from South America. These studies are first contextualized geographically and then are related one to another by a simplified vulnerability concept linking climate stress to sensitivity and adaptive capacity of natural and human systems. One half of the papers focus on actual or future climate change and the present-day causes of the vulnerability of natural and agrosystems. Droughts are and will be the main source of stress for agriculture in South America. Increasing fragmentation of forest of the center of this continent is aggravating their vulnerability to dry spells. Another half of the studies of this special issue deal with the adaptive capacity human populations to system perturbations produced or enhanced by climate change. The studies point out inclusion of traditional knowledge and involvement of local actors in their own vulnerability assessment to increase adaptive capacity. These elements of climate justice, giving voice to those less responsible for carbon emissions but bearing their most severe consequences, allow the particular needs of a community to be considered and can direct adaptation policy toward preserving or rebuilding their specific capabilities under threat from climate change. The special issue also made clear that a basin analysis of the climate change problem could provide information, results, and methods more readily of use for the local population and decision makers.     

Thermal ion measurements on board Interball Auroral Probe by the Hyperboloid experiment

Hyperboloid is a multi-directional mass spectrometer measuring ion distribution functions in the auroral and polar magnetosphere of the Earth in the thermal and suprathermal energy range. The instrument encompasses two analyzers containing a total of 26 entrance windows, and viewing in two almost mutually perpendicular half-planes. The nominal angular resolution is defined by the field of view of individual windows 13° × 12.5°. Energy analysis is performed using spherical electrostatic analyzers providing differential measurements between 1 and 80 eV. An ion beam emitter (RON experiment) and/or a potential bias applied to Hyperboloid entrance surface are used to counteract adverse effects of spacecraft potential and thus enable ion measurements down to very low energies. A magnetic analyzer focuses ions on one of four micro-channel plate (MCP) detectors, depending on their mass/charge ratio. Normal modes of operation enable to measure H⁺, He⁺, O⁺⁺, and O⁺ simultaneously. An automatic MCP gain control software is used to adapt the instrument to the great flux dynamics encountered between spacecraft perigee (700 km) and apogee (20 000 km). Distribution functions in the main analyzer half-plane are obtained after a complete scan of windows and energies with temporal resolution between one and a few seconds. Three-dimensional (3D) distributions are measured in one spacecraft spin period (120 s). The secondary analyzer has a much smaller geometrical factor, but offers partial access to the 3D dependence of the distributions with a few seconds temporal resolution. Preliminary results are presented. Simultaneous, local heating of both H⁺ and O⁺ ions resulting in conical distributions below 80 eV is observed up to 3 Earths radii altitudes. The thermal ion signatures associated with large-scale nightside magnetospheric boundaries are investigated and a new ion outflow feature is identified associated to the polar edge of the auroral oval. Detailed distribution functions of injected magnetosheath ions and ouflowing cleft fountain ions are measured down to a few eVs in the dayside.     

湖北铜绿山矿床石英闪长岩的矿物学及Sr-Nd-Pb同位素特征

铜绿山是长江中下游鄂东南矿集区最重要的、大型夕卡岩型Cu-Fe(Au)矿床。本文对该矿区中与成矿密切的石英闪长岩进行了详细的矿物成分、地球化学及Sr-Nd-Pb同位素研究。结果表明:岩石中斜长石主要为更长石(An=21～31);角闪石贫Ti(0.2),高Mg/(Mg+Fe)(0.5),属于富镁角闪石;而黑云母为镁质黑云母。岩石的地球化学具有高硅(58.86%～67.71%),富碱(Na2O+K2O=5.67%～9.63%),富集轻稀土元素(LREE)和大离子亲石元素(LILE),并强亏损元素Nb、Ta、Ti等特征。岩石的(87Sr/86Sr)i为0.7055～0.7069,εNd(t)为-7.65～-3.44;(206Pb/204Pb)i=17.66～18.00,(207Pb/204Pb)i=15.49～15.56,(208Pb/204Pb)i=37.73～38.19。矿物成分、地球化学和同位素特征说明,铜绿山岩体与阳新岩体为同源岩浆的产物,源区为深度大于40km的富集地幔,经下地壳的混染及分离结晶作用形成。岩浆熔体形成的温度应大于889℃。角闪石和黑云母的温度计估算岩浆结晶温度分别为650～800℃和500～630℃,黑云母开始结晶温度略低于角闪石结晶结束温度,压力为1.49kbar,对应侵位深度约4.9km。岩浆具有利于Cu、Fe、Au等成矿元素进入熔体的条件,可能与板块俯冲作用相关。     

Oxygen and carbon isotope composition of structural carbonate in weathering apatites from laterites, southern Brazil and western Senegal

The oxygen (δ¹⁸O_c) and carbon (δ¹³C_c) isotope compositions of the structural carbonate group (CO₃) in apatites from lateritic profiles were investigated. The weathering profiles, located in southern Brazil and in western Senegal, are developed on three different types of apatite-rich parent rock: carbonatite, metamorphosed marine phosphorite and sedimentary marine phosphorite. The parent rock apatites are of magmatic, hydrothermal, metamorphic and sedimentary origins. The in situ formation of apatite of weathering origin in the profiles is well documented petrographically and geochemically.The overall range of measured δ¹⁸O_c and δ¹³C_c values of apatites of weathering origin (22 to 27 SMOW for δ¹⁸O_c and −15 to −10 PDB for δ¹³C_c) is much smaller than the range of measured and/or published isotope compositions of parent rock apatites (4–35 for δ¹⁸O_c and −11 to +1 for δ¹³C_c). In any profile, the apatites of weathering origin can exhibit lower, similar or higher δ¹⁸O_c values than parent rock apatites. In contrast, their δ¹³C_c values are systematically and significantly lower than those of the parent rock apatites. Apatites formed as a result of weathering in laterites can therefore be readily distinguished from apatites of other origin on the basis of their isotope composition.Assuming that apatite CO₃ fractionates O in a way similar to calcite CO₃, the structural carbonate group of the apatites of weathering origin appears to form in approximate isotopic equilibrium with the weathering solutions. The very low δ¹³C_c values exhibited by these apatites indicate that the dominant sources of dissolved CO₂ in the soil water are organic. The isotope composition of structural carbonate in apatite of weathering origin in lateritic profiles may provide useful information for paleoenvironmental studies.     

Pigmenting agents in Martian soils: inferences from spectral, Mossbauer, and magnetic properties of nanophase and other iron oxides in Hawaiian palagonitic soil PN-9

We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars.     

Stability functions correct at the free convection limit and consistent for for both the surface and Ekman layers

For the thermal stability function _h used to calculate heat and moisture fluxes in the surface layer, we choose a formulation which has the theoretically correct free convection limit % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaeikaiabgk% HiTGqaciaa-PhacaqGVaGaamitaiaabMcadaahaaWcbeqaaiabgkHi% TiaaigdacaGGVaGaaG4maaaaaaa!3DFE!\[{\rm{(}} - z{\rm{/}}L{\rm{)}}^{ - 1/3} \]. We then use the experimental result that z/L Ri to deduce a formulation with an exponent -1/6 for the momentum stability function _m. This formulation also resolves the matching problem at the interface between the surface and Ekman layers. The proposed functions are found to remain reasonably close to another formulation that is well supported by observations and has exponents -1/2 for _h and -1/4 for _m. The intent of the proposals is mainly to clarify and simplify the parameterization of the convective boundary layer in present day atmospheric models, without significantly altering the results.     

敦煌三危山地区白垩纪OIB型基性岩墙的特征及地质意义

本文首次报道甘肃敦煌三危山地区早白垩世玄武质岩浆活动的记录。在三危山附近,基性岩墙侵入于敦煌群TTG和表壳岩大理岩和片岩中。全岩的K-Ar年龄为136.00±11.56Ma到99.11±6.35Ma,形成时代属于早白垩世。基性岩墙SiO₂含量变化范围较小,集中在47.95%~50.65%之间,以富TiO₂ (2.07%~2.35%,平均为2.21%)、MgO(6.03 %~6.51%,平均为6.32%)、贫K₂O(<1.29%),Na₂O>K₂O, Mg^#值中等且比较稳定(48.9~53.1,平均为51.7)为特征。基性岩相容元素含量相对较低,Ni含量变化相对较小,分布在112.7×10^-6~182.7×10^-6之间。而V含量变化较大,介于184×10^-6~267×10^-6之间,表明岩浆早期可能发生了一定的以橄榄石和单斜辉石为主的分离结晶作用。基性岩富集LREE((La/Yb)_N ＝3.97~4.66)和LILE,无Eu负异常,较高的Fe/Mn比值等,具有与洋岛玄武岩(OIB)相似的特征。微量元素比值等特征表明其来源与富集地幔关系密切,玄武质岩浆的形成可能与岩石圈的减薄和软流圈的上涌有关。     

Chemical and isotopic characterization of hydrocarbon gas traces in porewater of very low permeability rocks: The example of the Callovo-Oxfordian argillites of the eastern part of the Paris Basin

A methodology has been developed to determine chemical and carbon isotopic compositions of trace amounts of hydrocarbon gas compounds (methane, ethane, propane, iso- and normal-butane) present as dissolved compounds in the porewater of the low permeability Callovo-Oxfordian argillites in eastern Paris Basin, France. Results indicate that the studied hydrocarbons contain significant amounts of ethane, butane and propane, in addition to methane. Carbon isotopic compositions reflect primarily thermogenic origin (thermal cracking of organic matter), and lack of any significant biodegradation. Because temperature did not exceed 50 °C in the studied argillites, investigated hydrocarbons must have originated in hotter/deeper organic-bearing formations, possibly Stephanian coals. Data supports the predominance of high maturity thermogenic gas in the upper part of the Callovo-Oxfordian, and low maturity thermogenic gas mixed with minor bacterially produced methane in the lower part of the formation. A mixing between three end-member gases models quite well the data: one thermogenic gas with a low maturity (42% methane, with a δ¹³C of − 53‰), a gas with higher maturity (55% methane, with a δ¹³C of − 47‰) and a bacterial gas (99.45% methane, with a δ¹³C of − 80‰). This study illustrates that migration of hydrocarbon gases can take place in rocks with very low permeability and porosity, such as compacted mudrocks, given enough time. It further suggests that the studied fluid migration and transfer in aquitards would help characterization and understanding of fluid movements in sedimentary basins, as a complement to studies focused on water aquifers and hydrocarbon reservoirs. Chemical and isotopic composition of dissolved hydrocarbons in porewater can be used as natural tracers of fluid circulation in sedimentary basins, in addition to more conventional tracers.     

Tracking the isostatic and eustatic signals in an end Ordovician–early Silurian deglacial sedimentary record (Algeria – Libya border)

To elucidate the signature of isostatic and eustatic signals during a deglaciation period in pre‐Pleistocene times is made difficult because very little dating can be done, and also because glacial erosion surfaces, subaerial unconformities and subsequent regressive or transgressive marine ravinement surfaces tend to amalgamate or erode the deglacial deposits. How and in what way can the rebound be interpreted from the stratigraphic record? This study proposes to examine deglacial deposits from Late‐Ordovician to Silurian outcrops at the Algeria–Libya border, in order to define the glacio–isostatic rebound and relative sea‐level changes during a deglaciation period. The studied succession developed at the edge and over a positive palaeo‐relief inherited from a prograding proglacial delta that forms a depocentre of glaciogenic deposits. The succession is divided into five subzones, which depend on the topography of this depocentre. Six facies associations were determined: restricted marine (Facies Association 1); tidal channels (Facies Association 2); tidal sand dunes (Facies Association 3); foreshore to upper shoreface (Facies Association 4); lower shoreface (Facies Association 5); and offshore shales (Facies Association 6). Stratigraphic correlations over the subzones support the understanding of the depositional chronology and associated sea‐level changes. Deepest marine domains record a forced regression of 40 m of sea‐level fall resulting from an uplift caused by a glacio‐isostatic rebound that outpaces the early transgression. The rebound is interpreted to result in a multi‐type surface, which is interpreted as a regressive surface of marine erosion in initially marine domains and as a subaerial unconformity surface in an initially subaerial domain. The transgressive deposits have developed above this surface, during the progressive flooding of the palaeo‐relief. Sedimentology and high‐resolution sequence stratigraphy allowed the delineation of a deglacial sequence and associated sea‐level changes curve for the studied succession. Estimates suggest a relatively short (<10 kyr) duration for the glacio‐isostatic uplift and a subsequent longer duration transgression (4 to 5 Myr).