Groundwater vulnerability assessment in the Melaka State of Malaysia using DRASTIC and GIS techniques

The present work attempts to interpret the groundwater vulnerability of the Melaka State in peninsular Malaysia. The state of groundwater pollution in Melaka is a critical issue particularly in respect of the increasing population, and tourism industry as well as the agricultural, industrial and commercial development. Focusing on this issue, the study illustrates the groundwater vulnerability map for the Melaka State using the DRASTIC model together with remote sensing and geographic information system (GIS). The data which correspond to the seven parameters of the model were collected and converted into thematic maps by GIS. Seven thematic maps defining the depth to water level, net recharge, aquifer media, soil media, topography, impact of vadose zone and hydraulic conductivity were generated to develop the DRASTIC map. In addition, this map was integrated with a land use map for generating the risk map to assess the effect of land use activities on the groundwater vulnerability. Three types of vulnerability zones were assigned for both DRASTIC map and risk map, namely, high, moderate and low. The DRASTIC map illustrates that an area of 11.02 % is low vulnerability, 61.53 % moderate vulnerability and 23.45 % high vulnerability, whereas the risk map indicates that 14.40 % of the area is low vulnerability, 47.34 % moderate vulnerability and 38.26 % high vulnerability in the study area. The most vulnerability area exists around Melaka, Jasin and Alor Gajah cities of the Melaka State.     

Communicating human health risks associated with disinfection by-products in drinking water supplies: a fuzzy-based approach

Chlorine used for the disinfection of water supplies can react with naturally occurring organic compounds and form potentially harmful disinfection by-products (DBPs). A risk index for two regulated groups of chlorinated DBPs—trihalomethanes (THMs) and haloacetic acids (HAAs), using fuzzy C-means (FCM) clustering algorithm and fuzzy rule-based modeling is proposed for risk communication. The proposed index evaluates the cancer and non-cancer risks individually for THMs and HAAs using the FCM algorithm. Subsequently, two different fuzzy rule-bases were used to evaluate the overall risk-index based on cancer and non-cancer risks. The overall risk-index will provide drinking water utilities with an effective communication tool for communicating aggregated water quality compliance. Simulated DBP occurrence data obtained from the City of Quebec, Canada, is used to demonstrate the application of this methodology.     

Lunar concrete: Prospects and challenges

The possibility of using concrete as a construction material at the Moon surface is considered. Dissimilarities between the Earth and the Moon and their possible effects on concrete are also emphasized. Availability of constituent materials for concrete at lunar surface is addressed. An emphasis is given to two types of materials, namely, hydraulic concrete and sulfur concrete. Hydraulic concrete necessitates the use of water and sulfur concrete makes use of molten sulfur in lieu of cement and water.     

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

Comparison of different phases of bismuth silicate nanofibers for photodegradation of organic dyes

Two different phases of bismuth silicate nanofibers [Bi₂SiO₅ and Bi₄(SiO₄)₃] were synthesized using electrospinning technique. BS nanofibers were tested for the photocatalytic degradation of methyl orange and safranin O dyes. Different phases of BS affect the photodegradation efficiency of nanofibers. Impressive enhancement in photocatalytic efficiency and BET surface area of Bi₄(SiO₄)₃ was observed over Bi₂SiO₅. A speedy reduction in dyes concentration was attributed to the rapid formation of oxygenated radicals by the capture of electrons and holes, generated in the BS nanofiber by UV irradiation. Therefore, the photocatalytic mechanism was elucidated using impedance spectroscopy at room temperature. The lower impedance value of Bi₄(SiO₄)₃ nanofibers had improved high-efficiency charge transfer capability. The cycling efficiency (30 times) and recovery characteristics pointed out that Bi₄(SiO₄)₃ nanofibers photocatalysts had high constancy, resilience, and regeneration ability.     

Sensitivity studies of high-resolution RegCM3 simulations of precipitation over the European Alps: the effect of lateral boundary conditions and domain size

A suite of high-resolution (10 km) simulations were performed with the International Centre for Theoretical Physics (ICTP) Regional Climate Model (RegCM3) to study the effect of various lateral boundary conditions (LBCs), domain size, and intermediate domains on simulated precipitation over the Great Alpine Region. The boundary conditions used were ECMWF ERA-Interim Reanalysis with grid spacing 0.75^°, the ECMWF ERA-40 Reanalysis with grid spacing 1.125 and 2.5^°, and finally the 2.5^° NCEP/DOE AMIP-II Reanalysis. The model was run in one-way nesting mode with direct nesting of the high-resolution RCM (horizontal grid spacing Δx = 10 km) with driving reanalysis, with one intermediate resolution nest (Δx = 30 km) between high-resolution RCM and reanalysis forcings, and also with two intermediate resolution nests (Δx = 90 km and Δx = 30 km) for simulations forced with LBC of resolution 2.5^°. Additionally, the impact of domain size was investigated. The results of multiple simulations were evaluated using different analysis techniques, e.g., Taylor diagram and a newly defined useful statistical parameter, called Skill-Score, for evaluation of daily precipitation simulated by the model. It has been found that domain size has the major impact on the results, while different resolution and versions of LBCs, e.g., 1.125^° ERA40 and 0.7^° ERA-Interim, do not produce significantly different results. It is also noticed that direct nesting with reasonable domain size, seems to be the most adequate method for reproducing precipitation over complex terrain, while introducing intermediate resolution nests seems to deteriorate the results.     

Simulated Heat Content Variability in the Upper Layers of the Tropical Indian Ocean

Ocean General Circulation Model (OGCM) simulations from 1970–2007 are used to study the upper ocean heat content variability in the Tropical Indian Ocean (TIO). Model computed heat contents up to 50 m (denoted by HC50 m hereafter) representing upper ocean heat content and 300 m (HC300 m) representing heat content up to thermocline depth are first compared with heat contents computed from observations of two buoys in the TIO. It is found that there is good agreement between the model and observations. Fourier analysis of heat content is carried out in different regions of TIO. The amplitudes of semi-annual variability for HC50 m and HC300 m are observed to be greater than those for the annual variability in the Bay of Bengal, while in the Arabian Sea there is a mixed result. Heat content tendency is known to be governed by net surface heat flux and horizontal as well as vertical heat transports. For understanding the relative importance of these processes, a detailed analysis of these terms in the tendency equation is carried out. Rossby wave is observed in the annual mode of heat transport while equatorial jet and Kelvin waves are observed in the semi-annual mode of heart transport. Finally, the correlation between heat content and sea surface temperature (SST) and sea level anomaly (SLA), taken one at a time, is computed. It is found that the correlation improves significantly when both these quantities are together taken into account.