Iron oxidation state in impact glass from the K/T boundary at Beloc,Haiti, by high‐resolution XANES spectroscopy

Abstract— We examined the local iron environment in nine impact glasses from the Cretaceous‐Tertiary (K/T) boundary section at Beloc, Haiti, which formed as the result of impact melting during the Chicxulub impact event. The samples have been analyzed by Fe K‐edge high‐resolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain data on both the Fe oxidation state and the coordination number. The pre‐edge peak of our high‐resolution XANES spectra display noticeable variations indicative of significant changes in the Fe oxidation state spanning a wide range from about 20 to 75 mol% trivalent Fe. All data plot along the same trend, falling between two mixing lines joining a point calculated as the mean of a group of tektites studied so far (consisting of four‐ and five‐coordinated Fe²⁺) to ^[4]Fe³⁺ and ^[5]Fe³⁺, respectively. Thus, the XANES spectra can be interpreted as a mixture of ^[4]Fe²⁺, ^[5]Fe²⁺, ^[4]Fe³⁺, and ^[5]Fe³⁺. There is no evidence for six‐fold coordinated Fe; however, its presence in small amounts cannot be excluded from XANES data alone. Our observations can be explained by two possible scenarios: either these impact glasses formed under very reducing conditions and, because of their small size, were easily oxidized in air while still molten, or they formed under a variety of different oxygen fugacities resulting in different Fe oxidation states. In the first case, the oxidation state and coordination number would imply similar formation conditions as splash‐form tektites, followed by progressive oxidation.     

Growth and population dynamics of the non‐indigenous species Branchiomma luctuosum Grube (Annelida,Sabellidae) in the Ionian Sea (Mediterranean Sea)

The population dynamics and gametogenesis of the non‐indigenous polychaete species Branchiomma luctuosum Grube, 1869 (Annelida, Sabellidae) has been investigated at three sites in the Taranto Seas (Ionian Sea, Mediterranean Sea). The species, probably introduced from the Red Sea, has been reported in the Mediterranean Sea since 1983. The species is hermaphrodite, and the reproductive season is between June and October when the largest mean size of oocytes was recorded together with the presence of mature spermatozoa. Small oocytes are present in specimens reaching about 20–25 mm in length. Therefore oogenesis seems to begin early during the first year of life, but the first reproduction can occur when the worms attain a larger size and are at least 6 months of age. Although most of the individuals reproduce seasonally within a discrete period, some individuals can reproduce in different periods during the year, the oogenesis of individuals not being synchronous. A life span of at least 2 years is highlighted, with a faster growth rate during the first months (about 20 mm per month) decreasing to about 10 mm from the 3rd to the 8th months and slowing down again after the worm reaches 100 mm in size. Some differences in growth performance are discussed, enhanced by comparing the sites located at greater depth (5–7 m) and those located at 0.5 m depth, together with the possible interactions of this alien species with the autochthonous sabellid Sabella spallanzanii.     

Australasian microtektites from Antarctica: XAS determination of the Fe oxidation state

The Fe oxidation state and coordination number of 29 impact glass spherules recently recovered from the Transantarctic Mountains (Antarctica) have been determined by X‐ray absorption near edge structure (XANES) spectroscopy. Based on geochemical, isotopic, and fission track data, these spherules are considered as microtektites from the Australasian tektite/microtektite strewn field. Their find location is the farthest so far discovered from the possible source crater region, and their alkali content is the lowest compared with other published data on Australasian microtektite glasses. The Fe³⁺/(Fe²⁺+Fe³⁺) ratio, determined from the analysis of the pre‐edge peak energy position and integrated intensity, is below 0.1 (±0.04) for all the samples, and is comparable to that of most tektites and microtektites from the Australasian strewn field. Also, the pre‐edge peak integrated intensity, which is sensitive to the average Fe coordination geometry, is comparable to that of other Australasian microtektites reported in the literature. The agreement of the Fe oxidation state and coordination number, between the Transantarctic Mountain microtektites (TAM) and the Australasian tektites and microtektites, further confirms the impact origin of these glass spherules and provides an independent suggestion that they represent a major extension southeastward of the Australasian strewn field. The fact that similar redox conditions are observed in tektites and microtektites within the Australasian strewn field regardless of the distance from the source crater area (up to approximately 11000 km) could be an important constraint for better understanding the different processes affecting microtektite formation and transport. The fact that the Fe oxidation state of microtektites does not increase with distance, as in the case of North American microtektites, means that thermal and redox histories of Australasian and TAM microtektites could differ significantly from those of North American microtektites.     

The Campo Imperatore Near Earth Object Survey (CINEOS)

The Campo Imperatore Near Earth Object Survey (CINEOS) is an Italian survey dedicated to the search and follow-up of Near Earth Objects (NEOs). It is operated with the 90 cm f/3 Schmidt telescope at the Campo Imperatore of the Rome Astronomical Observatory (INAF-OAR) as a joint project with the Istituto di Astrofisica Spaziale and Fisica Cosmica (INAF-IASF) in Rome. Since the end of 2001 CINEOS has covered about 4,250 sq. deg to 20th magnitude in the course of about 160 nights. This effort led to the discovery of 7 Near Earth Asteroids (NEAs), 1 comet (167P/CINEOS; a member of the Centaur group) and a few other unusual objects including 2004 XH₅₀ with a unique comet-like orbit. CINEOS has also contributed almost 2,200 preliminary designations and over 30,000 detections to the Minor Planet Center. About 20% of the survey effort was carried out at low solar elongations (LSE), although no object with an orbit interior (Inner Earth Objects, IEO class) or nearly interior to the Earth (Aten class) was found. The work at LSE was, however, very important to test survey strategies implemented with larger telescopes. We also provide the results of a CINEOS simulation on a reliable NEO population model based on the results of two larger scale surveys, Spacewatch and LINEAR.     

On the definition of the flow width for calculating specific catchment area patterns from gridded elevation data

Specific catchment area (SCA) patterns are commonly computed on grids using flow direction algorithms that treat the flow as coming from a point source at the pixel centre. These algorithms are all ambiguous in the definition of the flow width to be associated with a pixel when computing the SCA. Different methods for computing the flow width have been suggested, without giving an objective reason. In the few cases where this issue has been specifically discussed, the flow width is derived from subjective analysis and incorrect conceptualizations. This paper evaluates alternative approaches for defining the flow width when computing SCA patterns using the D∞ and D8 algorithms, by comparing theoretical and computed SCA patterns on sloping planes, inward and outward cones. Two new methods of defining the flow width are also analysed for both the D∞ and D8 algorithms. The performances of the different methods are discussed in relation to two dimensionless parameters: (1) the global resolution, defined as the ratio of a characteristic length of the study area to the grid size and (2) the upslope area resolution, defined as the ratio of the theoretical SCA to the grid size. The optimal methods are identified by specific threshold values of these dimensionless parameters. We conclude that assuming the flow width invariant and equal to the grid size is generally the best approach in most practical circumstances, both for the D∞ and D8 algorithm. Copyright © 2005 John Wiley & Sons, Ltd.     

Deep Hubble Space Telescope imaging surveys and the formation of spheroidal galaxies

We have extended our previous analysis of morphologically selected elliptical and S0 galaxies in the Hubble Deep Field (HDF) North to include Hubble Space Telescope ( HST ) data in the HDF South and the HDFS–NICMOS areas. Our final sample amounts to 69 E/S0 galaxies with K <20.15 over an area of 11 arcmin². Although a moderately small number over a modest sky area, this sample benefits from the best imaging and photometric data available on high-redshift galaxies. Multi-waveband photometry allows us to estimate with good accuracy the redshifts for the majority of these galaxies, which lack a spectroscopic measure. We confirm our previous findings that massive E/S0s tend to disappear from flux-limited samples at z >1.4. This adds to the evidence that the rest-frame colours and spectral energy distributions (SEDs) of the numerous objects found at 0.8< z <1.2 are inconsistent with a very high redshift of formation for the bulk of stars, while they are more consistent with protracted (either continuous or episodic) star formation down to z ≤1. These results based on high-quality imaging on a small field can be complemented with data from colour-selected extremely red objects (EROs) on much larger sky areas: our claimed demise of E/S0s going from z =1 to z =1.5 is paralleled by a similarly fast decrease in the areal density of EROs when the colour limit is changed from ( R − K )=5 to ( R − K )=6 (corresponding to z ≃1 and z ≃1.3 respectively). Altogether, the redshift interval from 1 to 2 seems to correspond to a very active phase for the assembly of massive E/S0 galaxies in the field, and also probably one where a substantial fraction of their stars are formed.     

Confusion limit resulting from galaxies: using the Infrared Array Camera on board SIRTF

Recent ISO data have allowed, for the first time, observationally based estimates for source confusion in mid-infrared surveys. We use the extragalactic source counts from ISOCAM in conjunction with K -band counts to predict the confusion resulting from galaxies in deep mid-infrared observations. We specifically concentrate on the near-future Space Infrared Telescope Facility ( SIRTF ) mission, and calculate expected confusion for the Infrared Array Camera (IRAC) on board SIRTF . A defining scientific goal of the IRAC instrument will be the study of high-redshift galaxies using a deep, confusion-limited wide-field survey at 3–10 μm . A deep survey can reach 3-μJy sources with reasonable confidence in the shorter wavelength IRAC bands. Truly confusion-limited images with the 8 μm will be difficult to obtain because of practical time constraints, unless infrared galaxies exhibit very strong evolution beyond the deepest current observations. We find L * galaxies to be detectable to z =3–3.5 at 8 μm, which is slightly more pessimistic than found in 1999 by Simpson & Eisenhardt.