The effect of metasomatism on the Cr-PGE mineralization in the Finero Complex, Ivrea Zone, Southern Alps

The magmatic metasomatism that was responsible for producing chromitite–dunite bodies in the unusual phlogopite peridotite of the Finero Complex in Permian to Triassic times also influenced the Cr-platinum group elements (PGE) mineralization. At least the end stages of this metasomatism are recorded in compositional zoning of chromite grains in the podiform chromitite. Metasomatic melt, with or without vapor, reacted with chromite to produce core-to-rim Cr enrichment of extant chromite grains and was concurrent with pyroxene crystallization. Under conditions of lower melt/rock ratio, metasomatism resulted in core-to-rim Al enrichment in chromite and crystallization of amphibole between chromite and clinopyroxene. This early, high-temperature metasomatism is unrelated to the later and pervasive K-metasomatism that crystallized phlogopite and was associated with the intrusion of clinopyroxenite dikes that cut the peridotite. Much later, serpentinization of olivine locally depleted chromite in Al and enriched it in Fe and formed minor amounts of magnetite.The PGE, which are present mainly as laurite inclusions in chromite, were remobilized by the early metasomatism. This resulted in substantial variation in the PGE contents of chromitites and imposed a characteristic PGE pattern in which chondrite-normalized Os, Ir, Ru and Rh contents are high but Pt and Pd contents are low. The slopes of PGE chondrite-normalized concentration patterns are systematically related to absolute PGE abundance and to rock mode. Chromitites with low modal orthopyroxene, clinopyroxene, and amphibole exhibit negative PGE slopes and contain relatively high PGE concentrations, whereas chromitites rich in these silicate minerals have positive slopes and low PGE contents.     

Dissolution of nanocrystalline fluorite powders: An investigation by XRD and solution chemistry

The effect of lattice disorder and mineral surface area on the reactivity of finely ground fluorite was studied on ball-milled powders. Structural information was provided by X-ray whole powder pattern modeling (WPPM). The mean size of coherent scattering domains decreases with milling time from 70 nm to ∼20 nm, whereas the density of lattice defects increases with both time and intensity of milling treatment, from 4 × 10¹⁵ m^-2 to 24 × 10¹⁵ m^-2. High resolution transmission electron microscopy (HRTEM) of ground fluorite grains shows several line defects and a general tendency of nanometric crystalline domains to agglomerate in larger grains.Solution chemistry was investigated using batch reactors with free drift of solution saturation state with respect to fluorite. Total surface area was measured by the Brunaver, Emmet and Teller (BET) method, and dissolution rates were measured at pH = 2 (HCl) and T = 295 K. In far from equilibrium conditions, dissolution rates normalized by BET area do not increase with the dislocation density. In near-equilibrium condition, however, measured stationary ionic product clearly increases with both time and intensity of milling treatment. Thermodynamic predictions of the solubility constant indicate negligible or little effect of total surface area. Consequently, the observed increase in the stationary ionic product can be related to the increasing lattice defect content. This confirms the significant role of dislocation outcrops on mineral dissolution in close to equilibrium conditions.     

New real‐value modal combination rules for non‐classically damped structures

A procedure is presented to determine new modal combination rules (both CQC and SRSS) for non‐classically damped structures. The procedure presented in this paper does not need the solution of any complex eigenvalue problem, in contrast to other methods found in the literature. Thus, the modal combination rules presented here are easily applicable, even by those engineers who are unaccustomed to using complex algebra. Moreover, these formulations show the further advantage of requiring the response spectra only for the target damping ratio value. So the use of approximated formulae, necessary for passing from the response spectrum with the target damping ratio value to other ones, is avoided. Copyright © 2004 John Wiley & Sons, Ltd.     

57Fe Mössbauer study of the asbestiform silicates balangeroite and carlosturanite

⁵⁷FeMössbauer spectra of the two silicate minerals balangeroite (BAL) and carlosturanite (CST) have been collected at 80 and 295 K under normal and magic angle geometry. For both minerals the spectra have been fitted with two ferrous and two ferric doublets; Fe²⁺ accounts for 80 and 62% of Fe_tot in Bal and CST, respectively. The number of doublets used to fit the spectra supports the hypotheses that: (i) in the serpentine-like structure of CST iron occupies only octahedra which lie between the tetrahedral silicate strips; (ii) the octahedral framework of BAL (actually monoclinic) is satisfactorily described with an orthorhombic sub-cell.     

Using GB-SAR technique to monitor slow moving landslide

A Ground-Based SAR (GB-SAR) interferometer was employed to measure the surface displacements of a landslide occurring in the Carnian Alps, north-eastern Italy, which has affected a national road and seriously damaged a road tunnel still under construction. Moreover, since the landslide is located on the left bank of the Tagliamento River Valley, it is feared that this mass movement might dam the river, creating a basin that would increase natural hazard for the valley inhabitants. The data collected from December 2002 to July 2005 by a conventional monitoring system, consisting of a GPS network and boreholes equipped with inclinometric tubes, showed that the landslide was moving at a quasi-constant rate of about 3 cm per year. Due to the slow deformation rate of the landslide, a recently developed GB-SAR technique based on the analysis of a restricted ensemble of coherent points was used. Two surveys, each lasting two days, were planned in December 2004 and July 2005, in order to map and measure the surface displacements that occurred over time. The results from the radar were compared with the ones derived from the GPS monitoring network. An agreement was achieved among the data collected, showing the capability of the GB-SAR technique to measure displacements even within a time span of several months between the surveys.     

Evidence of a two-fold glacial advance during the last glacial maximum in the Tagliamento end moraine system (eastern Alps)

The glacial history of the Tagliamento morainic amphitheater (southeastern Alpine foreland, Italy) during the last glacial maximum (LGM) has been reconstructed by means of a geological survey and drillings, radiocarbon dating and pollen analysis in the amphitheater and in the sandur. Two phases of glacial culmination, separated by a distinct recession, are responsible for glacial landforms and related sediments in the outer part of the amphitheater. The age of the younger advance fits the chronology of the culmination of the last glaciation in the Alps, well established between 24 and 21 cal ka BP (20 to 17.5 ¹⁴C ka BP), whereas the first pulse between 26.5 and 23 cal ka BP (22 to 21 ¹⁴C ka BP), previously undated, was usually related to older (pre-LGM) glaciations by previous authors. Here, the first pulse is the most extensive LGM culmination, but is often buried by the subsequent pulse. The onset and final recession of the late Würm Alpine glaciation in the Tagliamento amphitheater are synchronous with the established global glacial maximum between 30 and 19 cal ka BP. The two-fold LGM glacial oscillation is interpreted as a millennial-scale modulation within the late Würm glaciation, caused by oscillations in inputs of southerly atmospheric airflows related to Dansgaard-Oeschger cycles. Phases of enhanced southerly circulation promoted increased rainfall and ice accumulation in the southern Alps.     

A simple and efficient procedure for the numerical simulation of wind fields in complex terrain

In spite of recent progress in the prognostic numerical simulation of the atmospheric boundary layer, the explicit simulation of turbulent flows in actual complex terrain is generally still very complicated and time consuming for many environmental applications. In an attempt to develop simpler and more efficient application oriented techniques, although less refined, we propose a multi-step procedure for simulating wind fields. Once obtained the necessary meteorological input, the mass-consistent modelling technique is used to perform high-resolution mean wind flow simulations taking into account recent developments in the atmospheric boundary-layer theory. Besides, a procedure based on a generalisation of the local logarithmic law-of-the-wall over complex terrain is used to estimate the effective parameters characterising the simulated wind profiles. Turbulence intensities and spectral properties are then calculated through the estimated effective parameters, in particular through the effective friction velocity parameter. Finally, time series of the instantaneous velocity field are simulated by the Monte Carlo technique. Two applications of the proposed approach are discussed briefly: the first one is related to a coastal area in southern Italy (the Messina Straits), where the construction of the world’s longest central span bridge is being planned; the second one corresponds to the flow in a mountainous area in northern Italy (the Albenga Airport).     

Wetland Plant Diversity in a Coastal Nature Reserve in Italy: Relationships with Salinization and Eutrophication and Implications for Nature Conservation

Wetlands are important centers of biodiversity. Coastal wetlands are subject to anthropogenic threats that can lead to biodiversity loss and consequent negative effects on nature conservation. We investigated relationships between wetland vegetation and habitat conditions in a coastal Nature Reserve in Northern Italy that has undergone seawater intrusion and eutrophication for several decades. The wetland vegetation in the Nature Reserve consisted of nine communities of hygrophytic and helophytic vegetation and five communities of waterplant vegetation. The hygrophytic and helophytic communities were arranged according to a salinity gradient, from salt-free habitats to strongly saline habitats. The saline habitats had high nutrient levels, due to the influx of nitrate-rich saltwater from an adjacent lagoon. The waterplant communities were all typical of freshwater habitats. Water-table depth and concentration of dissolved nutrients in the water were the main factors structuring waterplant vegetation. The main driver of future changes in the wetland vegetation of the Nature Reserve is the ongoing increase in salinity levels which may enhance expansion of halophilic species and communities, thus outcompeting locally rare freshwater species. If nutrient, especially nitrate, load further increases in the next future, this may exert negative effects on wetland species and communities preferring nutrient-poor habitats.