Late Quaternary multiple incised valley systems: An unusually well‐preserved stratigraphic record of two interglacial valley‐fill successions from the Arno Plain (northern Tuscany,Italy)

Un‐fragmented stratigraphic records of late Quaternary multiple incised valley systems are rarely preserved in the subsurface of alluvial‐delta plains due to older valley reoccupation. The identification of a well‐preserved incised valley fill succession beneath the southern interfluve of the Last Glacial Maximum Arno palaeovalley (northern Italy) represents an exceptional opportunity to examine in detail evolutionary trends of a Mediterranean system over multiple glacial–interglacial cycles. Through sedimentological and quantitative meiofauna (benthic foraminifera and ostracods) analyses of two reference cores (80 m and 100 m long) and stratigraphic correlations, a mid‐Pleistocene palaeovalley, 5 km wide and 50 m deep, was reconstructed. Whereas valley filling is chronologically constrained to the penultimate interglacial (Marine Isotope Stage 7) by four electron spin resonance ages on bivalve shells (Cerastoderma glaucum), its incision is tentatively correlated with the Marine Isotope Stage 8 sea‐level fall. Above basal fluvial‐channel gravels, the incised valley fill is formed by a mud‐prone succession, up to 44 m thick, formed by a lower floodplain unit and an upper unit with brackish meiofauna that reflects the development of a wave‐dominated estuary. Subtle meiofauna changes towards less confined conditions record two marine flooding episodes, chronologically linked to the internal Marine Isotope Stage 7 climate‐eustatic variability. After the maximum transgressive phase, recorded by coastal sands, the interfluves were flooded around 200 ka (latest Marine Isotope Stage 7). The subsequent shift in river incision patterns, possibly driven by neotectonic activity, prevented valley reoccupation guiding the northward formation of the Last Glacial Maximum palaeovalley. The applied multivariate approach allowed the sedimentological characterization of the Marine Isotope Stage 7 and Marine Isotope Stage 1 palaeovalley fills, including shape, size and facies architecture, which revealed a consistent river‐coastal system response over two non‐consecutive glacial–interglacial cycles (Marine Isotope Stages 8 to 7 and Marine Isotope Stages 2 to 1). The recurring stacking pattern of facies documents a predominant control exerted on stratigraphy by Milankovitch and sub‐Milankovitch glacio‐eustatic oscillations across the late Quaternary period.     

Topocentric orbit determination: Algorithms for the next generation surveys

The process of calculating a good orbit from astrometric observations of the same object involves three main steps: preliminary orbit determination, least squares orbit fitting, and quality control assessing the orbit's uncertainty and reliability. For the next generation sky surveys, with much larger number density of observations, new algorithms, or at least substantial revisions of the classical ones, are needed. The classical theory of preliminary orbit algorithms was incomplete in that the consequences of the topocentric correction had not been fully studied. We show that it is possible to rigorously account for topocentric observations and that this correction may increase the number of alternate preliminary orbits without impairing the overall performance. We have developed modified least squares algorithms including the capability of fitting the orbit to a reduced number of parameters. The restricted fitting techniques can be used to improve the reliability of the orbit computing procedure when the observed arcs have small curvature. False identification (where observations of different objects are incorrectly linked together) can be discarded with a quality control on the residuals and a ‘normalization’ procedure removing duplications and contradictions. We have tested our algorithms on two simulations based on the expected performance of Pan-STARRS—one of the next generation all-sky surveys. The results confirm that large sets of discoveries can be handled very efficiently resulting in good quality orbits. In these tests we lost only 0.6 to 1.3% of the possible objects, with a false identification rate in the range 0.02 to 0.06%.     

Sericitic alteration at the La Crocetta deposit (Elba Island,Italy): interplay between magmatism,tectonics and hydrothermal activity

The La Crocetta mine near Porto Azzurro (Elba Island, Tuscany, Italy) is an important producer of raw material for the ceramic industry. Exploitation focuses on a pervasively sericitized porphyritic aplite of the Tuscan Magmatic Province, locally known as "eurite", which underwent significant potassium enrichment during sericitic alteration. Eurites are located along the hanging wall of the Elba Centrale Fault, a low-angle extensional lineament of regional significance. A later carbonatization stage, apparently associated with high-angle extensional tectonics, locally overprinted the sericitized facies. It is expressed by carbonate ± pyrite ± quartz veins, with adverse effects on ore quality. Sericitization was accompanied by addition of potassium, and loss of Na (± Ca, Fe). Rubidium was not enriched along with potassium during sericitization, contrary to what would be expected for interaction with late-magmatic fluids. New ⁴⁰Ar–³⁹Ar data from eurites provide an isochron age of about 6.7 Ma for the sericitization, whereas the age of the unaltered protolith is ca. 8.8 Ma. Field evidence indicates the Elba Centrale Fault to be the main channel for the hydrothermal fluids. On the other hand, the involvement of heat and/or fluids contributed by the Porto Azzurro pluton, which crops out in the La Crocetta area, is ruled out by field, geochemical and geochronological data (⁴⁰Ar–³⁹Ar age of Porto Azzurro =5.9 Ma, i.e. significantly younger than the sericitization event). Fluid inclusion studies suggest that sericitization was associated with a low-temperature (<250 °C) hydrothermal system. Fluids were locally boiling, of variable salinity (4–17 wt% NaCl equiv.), and contained some CO₂ (XCO₂≤0.027). Their ultimate source is not unequivocally constrained; meteoric and/or magmatic contributions may be possible. Low-salinity (≤2.6 wt% NaCl equiv.), low-temperature (<250 °C) fluids are associated with the late carbonate veining. They are considered to be of dominantly meteoric nature because of their low salinity. In summary, sericitization at La Crocetta is regarded as the product of a detachment fault-related, low temperature hydrothermal system, resulting from the structurally controlled focusing of meteoric and possibly magmatic fluids. Hence, potential targets for exploration for similar resources are represented by aplitic bodies located in the hanging wall of Elba Centrale Fault. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00126-002-0279-2.     

CH4-consuming microorganisms and the formation of carbonate crusts at cold seeps

To understand the role played by microorganisms in the formation of cold seep carbonates, we conducted an integrated microbial, mineralogical and organic geochemical study of methane-related authigenic carbonate crusts formed on eastern Mediterranean mud volcanoes. We show that supersaturation with respect to carbonate minerals is induced by microbial anaerobic oxidation of methane. Combined lipid biomarker analysis and 16S rRNA gene surveys identified a highly diversified methane-consuming archaeal community possibly comprising novel species, implying that the anaerobic oxidation of methane is phylogenetically widespread and directly implicating these organisms in the process of crust precipitation. Moreover, pore-water sulphate gradients produced by co-occurring methane-based sulphate reduction exert the main control on aragonite versus magnesian calcite precipitation. We propose that this may be the dominant mode of carbonate crust formation at cold seeps world-wide, in agreement with aquatic chemistry predictions and explaining carbonate mineralogy.     

A Systematic Study of the Stability of Symmetric Periodic Orbits in the Planar, Circular, Restricted Three-Body Problem

We investigate symmetric periodic orbits in the framework of the planar, circular, restricted, three-body problem. Having fixed the mass of the primary equal to that of Jupiter, we determine the linear stability of a number of periodic orbits for different values of the eccentricity. A systematic study of internal resonances, with frequency p/q with 2p 9, 1 q 5 and 4/3 p/q 5, offers an overall picture of the stability character of inner orbits. For each resonance we compute the stability of the two possible periodic orbits. A similar analysis is performed for some external periodic orbits.Furthermore, we let the mass of the primary vary and we study the linear stability of the main resonances as a function of the eccentricity and of the mass of the primary. These results lead to interesting conclusions about the stability of exosolar planetary systems. In particular, we study the stability of Earth-like planets in the planetary systems HD168746, GI86, 47UMa,b and HD10697.     

Contents of Volume 53

Volume Contents

Contents of Volume 53     

Anisotropy of magnetic susceptibility studies of depositional processes in the Campanian Ignimbrite,Italy

The late Pleistocene trachytic Campanian Ignimbrite underlies much of the Campanian Plain near Naples, Italy, and occurs in valleys in the mountainous area surrounding the plain out to about 80 km from its source, the Campi Flegrei caldera. At sites within 15 km of the Campi Flegrei, anisotropy of magnetic susceptibility (AMS) principal directions indicate that, in the absence of significant topography, deposition came from a flow moving in a roughly radial direction. AMS studies of the more distal ignimbrite reveal downhill and/or downvalley flow directions prior to deposition, even where these directions are at high angles to a generally radial transport direction from the vent. On the flanks of Roccamonfina Volcano, flow was directly downhill, as if the source of the ignimbrite was the summit of the volcano. In most localities, the ignimbrite consists of a single massive deposit. In a few localities in the Apennine Mountains, however, the confluence of multiple drainage systems off mountains resulted in multiple local flow units that cannot be correlated between valleys. A detailed study of the ignimbrite in the flat Titerno River valley near Massa shows that the AMS fabrics are not due to late-stage creeping during deposition or compaction. Well-defined, but non-parallel AMS fabrics from vertical and lateral sections in the Massa area are best explained by the merging of gravity currents flowing down the valley and steep valley sides to form a single aggradational deposit. Clast compositions and AMS axes at Mondragone indicate that the pyroclastic flow encountered the Monte Massico massif and was partially blocked, so that flow during deposition was toward the Campi Flegrei. Similar AMS data from sites along the edge of the Campanian Plain indicate back-flow off the first ridge of the Apennine Mountains reached at least 5 km from their base. The Campanian Ignimbrite was deposited from a density-stratified pyroclastic flow. The depositional system consisted of the lower, denser portion of the current, and was controlled by topography. The grouping of the AMS axes is interpreted to indicate that deposition occurred under laminar flow conditions.     

Iron local structure in tektites and impact glasses by extended X-ray absorption fine structure and high-resolution X-ray absorption near-edge structure spectroscopy

The local structure of iron in three tektites has been studied by means of Fe K-edge extended X-ray absorption fine structure (EXAFS) and high-resolution X-ray absorption near-edge structure (XANES) spectroscopy in order to provide quantitative data on <Fe-O> distance and Fe coordination number. The samples studied are a moldavite and two australasian tektites. Fe model compounds with known Fe oxidation state and coordination number were used as standards in order to extract structural information from the XANES pre-edge peak. EXAFS-derived grand mean <Fe-O> distances and Fe coordination numbers for the three tektite samples are constant within the estimated error (<Fe-O > =2.00 Å ± 0.02 Å, CN = 4.0 ± 0.4). In contrast to other data from the literature on Fe-bearing silicate glasses, the tektites spectra could not be fitted with a single Fe-O distance, but rather were fit with two independent distances (2 × 1.92 Å and 2 × 2.08 Å). High-resolution XANES spectra of the three tektites display a pre-edge peak whose intensity is intermediate between those of staurolite and grandidierite, thus suggesting a mean coordination number intermediate between 4 and 5. Combining the EXAFS and XANES data for Fe, we infer the mean coordination number to be close to 4.5.Comparison of the tektites XANES spectra with those of a suite of different impact glasses clearly shows that tektites display a relatively narrow range of Fe oxidation state and coordination numbers, whereas impact glasses data span a much wider range of Fe oxidation states (from divalent to trivalent) and coordination numbers (from tetra-coordinated to esa-coordinated). These data suggest that the tektite production process is very similar for all the known strewn fields, whereas impact glasses can experience a wide variety of different temperature-pressure-oxygen fugacity conditions, leading to different Fe local structure in the resulting glasses. These data could be of aid in discriminating between tektite-like impact glasses and impact glasses sensu strictu.     

Tectono-stratigraphic modelling of the North Sicily continental margin (southern Tyrrhenian Sea)

A two-dimensional numerical modelling that simulate the kinematic and thermal response of the lithosphere to thinning was used for the quantitative reconstruction of the late Neogene to Recent times tectonic and stratigraphic evolution of the North Sicily continental margin (southern Tyrrhenian Sea). The numerical study of the evolution of the North Sicily margin builds on the crustal image and kinematic interpretation of the margin obtained by Pepe et al. [Tectonics 19 (2000) 241] on the basis of seismic data and gravity modelling. Tectonic modeling indicate that different segments of the margin were undergoing different vertical movements, which are mainly expression of the rifting and thinning of the lithosphere occurred during tectonic evolution of the southern Tyrrhenian Sea. A prediction of the pre-rift basement topography and the Moho along the margin converges to a value of 6.5 km for the depth of necking and a temperature-dependent EET (500° isotherm). The model fails to reproduce the morphology of the Solunto High confirming its non-extensional origin. A polyphase evolution is required to reproduce the observed syn- and post-rift stratigraphy. During the first rifting stage (between 9 and 5 Ma), crustal thinning factors reach maximum values of 1.27 in the Cefalù basin. A similar value is predicted for the subcrustal thinning around 60 km NNE of the profile margin. Crustal thinning factors increase during the second rifting stage (from 4 to 2 Ma) and reach values of 2 and up to 3.5 in the Cefalù basin and in the continent–oceanic transition zone, respectively. Similarly, subcrustal lithospheric thinning factors reach values up to 2.5 in the distal sector of the margin. An uplift of more than 100 m is predicted for the North Sicily shelf and surrounding onshore areas during the post-rift stage. The evolution of thermal structure with time is very sensitive to the partial thinning factors describing the evolution of the thinning itself during time. The lithosphere preserved part of its strength during extension. The effective elastic thickness (EET) along the margin through time is 24 km at the onset of rifting and reaches values less to 8 km during the second rifting stage in the northeastern end of the margin.