Fumarole/plume and diffuse CO2 emission from Sierra Negra caldera, Galapagos archipelago

Measurements of visible and diffuse gas emission were conducted in 2006 at the summit of Sierra Negra volcano, Galapagos, with the aim to better characterize degassing after the 2005 eruption. A total SO₂ emission of 11?±?2?t day^?1 was derived from miniature differential optical absorption spectrometer (mini-DOAS) ground-based measurements of the plume emanating from the Mini Azufral fumarolic area, the most important site of visible degassing at Sierra Negra volcano. Using a portable multigas system, the H₂S/SO₂, CO₂/SO₂, and H₂O/SO₂ molar ratios in the Mina Azufral plume emissions were found to be 0.41, 52.2, and 867.9, respectively. The corresponding H₂O, CO₂, and H₂S emission rates were 562, 394, and 3?t day^?1, respectively. The total output of diffuse CO₂ emissions from the summit of Sierra Negra volcano was 990?±?85?t day^?1, with 605?t day^?1 being released by a deep source. The diffuse-to-plume CO₂ emission ratio was about 1.5. Mina Azufral fumaroles released gasses containing 73.6?mol% of H₂O; the main noncondensable components amounted to 97.4?mol% CO₂, 1.5?mol% SO₂, 0.6?mol% H₂S, and 0.35?mol%?N₂. The higher H₂S/SO₂ ratio values found in 2006 as compared to those reported before the 2005 eruption reveal a significant hydrothermal contribution to the fumarolic emissions. ³He/⁴He ratios measured at Mina Azufral fumarolic discharges showed values of 17.88?±?0.25?R _A , indicating a mid-ocean ridge basalts (MORB) and a Galapagos plume contribution of 53 and 47?%, respectively.     

Water-Channel Estimation of Eulerian and Lagrangian Time Scales of the Turbulence in Idealized Two-Dimensional Urban Canopies

Lagrangian and Eulerian statistics are obtained from a water-channel experiment of an idealized two-dimensional urban canopy flow in neutral conditions. The objective is to quantify the Eulerian \((T^{\mathrm{E}})\) and Lagrangian \((T^{\mathrm{L}})\) time scales of the turbulence above the canopy layer as well as to investigate their dependence on the aspect ratio of the canopy, AR, as the latter is the ratio of the width (W) to the height (H) of the canyon. Experiments are also conducted for the case of flat terrain, which can be thought of as equivalent to a classical one-directional shear flow. The values found for the Eulerian time scales on flat terrain are in agreement with previous numerical results found in the literature. It is found that both the streamwise and vertical components of the Lagrangian time scale, \(T_\mathrm{u}^\mathrm{L} \) and \(T_\mathrm{w}^\mathrm{L} \), follow Raupach’s linear law within the constant-flux layer. The same holds true for \(T_\mathrm{w}^\mathrm{L} \) in both the canopies analyzed \((AR= 1\) and \(AR= 2\)) and also for \(T_\mathrm{u}^\mathrm{L} \) when \(AR = 1\). In contrast, for \(AR = 2\), \(T_\mathrm{u}^\mathrm{L} \) follows Raupach’s law only above \(z=2H\). Below that level, \(T_\mathrm{u}^\mathrm{L} \) is nearly constant with height, showing at \(z=H\) a value approximately one order of magnitude greater than that found for \(AR = 1\). It is shown that the assumption usually adopted for flat terrain, that \(\beta =T^{\mathrm{L}}/T^{\mathrm{E}}\) is proportional to the inverse of the turbulence intensity, also holds true even for the canopy flow in the constant-flux layer. In particular, \(\gamma /i_\mathrm{u} \) fits well \(\beta _\mathrm{u} =T_\mathrm{u}^\mathrm{L} /T_\mathrm{u}^\mathrm{E} \) in both the configurations by choosing \(\gamma \) to be 0.35 (here, \(i_\mathrm{u} =\sigma _\mathrm{u} / \bar{u} \), where \(\bar{u} \) and \(\sigma _\mathrm{u} \) are the mean and the root-mean-square of the streamwise velocity component, respectively). On the other hand, \(\beta _\mathrm{w} =T_\mathrm{w}^\mathrm{L} /T_\mathrm{w}^\mathrm{E} \) follows approximately \(\gamma /i_\mathrm{w} =0.65/\left( {\sigma _\mathrm{w} /\bar{u} } \right) \) for \(z > 2H\), irrespective of the AR value. The second main objective is to estimate other parameters of interest in dispersion studies, such as the eddy diffusivity of momentum \((K_\mathrm{{T}})\) and the Kolmogorov constant \((C_0)\). It is found that \(C_0\) depends appreciably on the velocity component both for the flat terrain and canopy flow, even though for the latter case it is insensitive to AR values. In all the three experimental configurations analyzed here, \(K_\mathrm{{T}}\) shows an overall linear growth with height in agreement with the linear trend predicted by Prandtl’s theory.     

Modelling the long‐term deformation of the sedimentary substrate of Mt. Etna volcano (Italy)

This study investigates in detail the deformation events that have affected the sedimentary successions forming the substrate of Mt. Etna volcano (Italy). Based on the geometric reconstruction of a buried sedimentary marker, we have been able to identify and quantify the effects of three different mechanisms of deformation that have affected the area in the last 600 ka. Numerical results from Finite Element Method (FEM) applied to model viscoelastic deformation suggest the occurrence of a crustal doming process originating at the mantle‐crust transition (~16 km). We propose that the source of deformation is related to the diapiric uprise of hydrothermal material originating in altered ocean‐like crust and its emplacement at a shallower level in the crust. This process has great relevance in the volcanic system and should be considered for the full assessment of its origin and evolution.     

Transient response of harbours to long waves under resonance conditions

This paper presents the results of a study aimed at quantifying the time–response of harbour basins to long waves under resonance conditions. On the basis of numerical simulations reproducing long waves in the yacht harbour of Rome (Ostia, Italy), it shows that the results valid for periodic forcing waves, acting for an infinitely long time, as those provided by models based on elliptic equations like the Helmoltz and the mild-slope equations, can be misleading with respect to the more realistic ones that can be obtained using time-varying wave equations. Taking advantage of the similarity between the processes studied here and a simple one-dimensional resonator, a method is also proposed to roughly estimate a time–response parameter of each mode of the harbour, using results from steady-state numerical model results, commonly applied for studying harbour resonance in engineering practice. On the basis of further numerical simulations, aimed at reproducing schematic harbour layouts, the effect on resonance of the position of the entrance and of an outer harbour is studied. The results indicate that the effects of design solutions to reduce resonance, by placing the entrance at the middle of the harbour, or using the outer harbour as a resonator, can be correctly evaluated only when considering the time needed for the oscillations to fully develop.     

Bioavailability of different chemical forms of dissolved silica can affect marine diatom growth

In this study, we demonstrate that dissolved silica obtained from mineral (crystalline quartz), biogenic amorphous (diatomaceous earth) and artificial amorphous sources (Aerosil) influence the growth rate of two marine diatoms, Chaetoceros sp. and Skeletonema marinoi. Diatoms were reared in four different experimental conditions in artificial seawater containing either dissolved silica previously obtained through dissolution of the mineral crystalline quartz or two amorphous substrates, biogenic diatomaceous earth or artificial Aerosil silica. Sodium metasilicate was used as control. When the silica in the different media reached concentrations higher than 107 μm , particles were eliminated by filtration and the diatom cells were inoculated. Maximum cell density, growth and silica assimilation rates of both species in the presence of dissolved silica derived from crystalline quartz and metasilicate were higher than those obtained with the other silica sources. These results are discussed against the background of previous geochemical studies that have shown that silica–water interactions are strictly dependent on the silica polymorphs involved and on the ionic composition of the solution. Our results demonstrate that the soluble silicon compounds generated in seawater by crystalline sources are highly bioavailable compared with those generated by biogenic and amorphous materials. These findings are potentially of considerable ecological importance and may contribute to clarifying anomalous spatial and temporal distributions of siliceous organisms with respect to the presence of lithogenic or biogenic silica sources in marine environments.     

On the effectiveness of constant coefficients roll motion equation

As known, the rolling motion characteristics, amplitudes and accelerations, greatly influence the ability of a ship to operate and survive in bad weather. On the other hand, traditional computer codes for seakeeping calculations fail the forecasting of large amplitude rolling. There is a great need of using semi-empirical damping models and coefficients. This stresses the importance of campaigns of measurements as described in the paper, to get a deeper insight into the physical-mathematical modelling of the different contributions to rolling equation.Experimental tests on nonlinear rolling in a regular beam sea of a Ro-Ro ship model have been conducted by varying both the wave steepness and the wave frequency. The use of a parameter estimation technique, based on the least squares fitting of the stationary numerical solution of the nonlinear rolling motion differential equation, allowed to obtain informations on the damping model and on the linear and nonlinear damping coefficients. These exhibit a quite strong dependence on frequency that reduces the efficiency of constant coefficients rolling equation to simulate large amplitude nonlinear rolling. The results indicate that a good quality prediction model of nonlinear rolling cannot be based on constant coefficients time domain simulations. These can infact lead to incorrect estimates of rolling amplitudes even when the parameters have been obtained through high level parameter estimation procedures based on experimental data. The analysis indicates also a marked dependence of the effective wave slope coefficient on wave amplitude. The introduction of both these dependences on the rolling equation allows to reproduce the experimental results with great accuracy even at large amplitudes.     

Recent trends in seasonal and annual precipitation indices in Tuscany (Italy)

Global warming alters the hydrological cycle since a rise in temperature leads to an increase in the moisture-holding capacity of the atmosphere at a rate of about 7 %/°C. This fact can influence the global, but also local characteristics of precipitation, such as total amount and intensity. Therefore, it is important to study changes in rainfall regime in regions with complex orography, like Tuscany, where there are strong spatial gradients in precipitation amounts. The aim of this study is to look for temporal change in precipitation from 1955 to 2007 searching for spatial differences. Daily data of 21 meteorological stations were analyzed to identify trends in seasonal and annual precipitation indices. Cluster analysis applied to principal components was applied to identify homogeneous groups of stations. A decrease in precipitation was observed at annual time scale, during winter and spring, especially in northwestern areas. Wet days highlighted a decrease in all of Tuscany, due to the same seasons. In northern Tuscany, the decrease in rainfall amount was mainly determined by a lower frequency of rainy events which in turn caused a decrease in the occurrence of extreme daily precipitation events (75th, 90th, and 95th percentile). In central-southern Tuscany, no significant changes were observed except for an increase in precipitation fraction, due to extreme events and in mean daily total amount for wet days. These results are consistent with recent findings for the Mediterranean area and confirm the usefulness of cluster analysis for the analysis of the spatial distribution of precipitation.     

Evolution of Eolian arc volcanism (Southern Tyrrhenian Sea)

The Eolian arc is located at the boundary between the converging African and European plates. Its volcanism is characterized by a marked evolution in a restricted time (less than 1 my). A progressive transition is observed from typical calc-alkaline series toward shoshonitic rocks produced by past and present activity (Vulcano and Stromboli). By comparison with circum-Pacific island arcs, the evolution of Eolian volcanism can be related to a rapid deepening of the Benioff zone. The occurrence of shoshonitic rocks and the continental nature of the crust on both sides of the plate boundary suggest that the Eolian arc is in a senile stage of evolution. Petrology and Sr isotopic data indicate a probable mantle source for Eolian volcanism.