Comparison of the structures of humic substances from aquatic and terrestrial sources by pyrolysis gas chromatography-mass spectrometry

Four humic extracts isolated from terrestrial, mahne, plankton and freshwater sources have been investigated by pyrolysis-gas chromatography-mass spectrometry. The results show that substantial quantities of phenols (some not derived from lignin), pyrroles and nitrites (derived from proteins, nucleic acids or porphyrins) are decomposition products. Small amounts of furans (derived from carbohydrates) and unsaturated ketones (derived from polycarboxylic aliphatic acids) are also present. The results illustrate how parent material, transport factors and biological activity affect the composition of humic extracts.     

Announcement Internatioal Society for Diatom Research and Nederlands-Vlaamse Kring van Diatomisten

Announcement Internatioal Society for Diatom Research and Nederlands-Vlaamse Kring van Diatomisten     

Dynamos on stream surfaces of a highly conducting fluid

Abstract

This paper discusses dynamo action in generalisations of the Ponomarenko dynamo at large magnetic Reynolds number. The original Ponomarenko dynamo consists of a spiralling flow in which the stream surfaces are concentric cylinders of circular cross section, and the flow depends only on distance from the axis in cylindrical polar coordinates.

In this study, the stream surfaces are allowed to be cylinders of arbitrary cross section, and the flow is only required to be independent of the coordinate along the cylinder axes. For smooth flows alpha and eddy diffusion effects are identified, in terms of the geometry of the stream surfaces, and asymptotic formulae for growth rates in the limit of large magnetic Reynolds number are obtained. Numerical support for these results is presented using direct simulation of dynamo action in selected flows at high conductivity. Finally the case is considered when in spherical polar coordinates the flow is independent of the azimuthal coordinate and the stream surfaces, which are tori, have arbitrary cross sections.     

Buying environmental insurance: Prospects for trading of global climate-protection services

In order to alleviate the threat of global climate change, coordinated international action is needed. This cooperation should include multilateral agreements and new economic initiatives to help implement measures that will slow the accumulation of carbon dioxide in the Earth's atmosphere due to tropical deforestation and fossil-fuel use. An international market in environmental services can help to safeguard the Earth's climate and foster economic development through a North-South transfer of financial resources.We suggest international carbon-emission offsets (ICEOs) as a means by which international markets, under a policy umbrella such as a multilateral climate-protection treaty, could trade carbon-saving services. Such a market would provide a currency for rewarding actions that reduce global carbon emissions, allowing carbon emitters to seek the least expensive ways to reduce emissions. This currency would transfer cash and/or debt relief from industrialized nations to developing nations, allowing the developing nations to profit from the use of clean energy technologies and the protection, rather than depletion, of tropical forests.     

Effects of hypoxia on benthic macrofauna and bioturbation in the Estuary and Gulf of St. Lawrence,Canada

The bottom water in the >300 m deep Lower St. Lawrence Estuary (LSLE) is persistently hypoxic in contrast to the normoxic bottom waters in the Gulf of St. Lawrence (GSL). We photographed the seabed at 11 stations in the Estuary and Gulf of St. Lawrence (EGSL) during the summers 2006 and 2007 and analysed the images to identify bioturbation traces (lebensspuren) and benthic macrofauna. The objective was to identify the environmental variables that influence the density and diversity of benthic macrofauna and bioturbation traces, and the differences that exist among regions with high, medium and low oxygen levels in the bottom water. The bottom water oxygen concentration is the variable that best explains the densities of total-traces as well as surface-traces. However, the density of these traces was higher in hypoxic regions than in well-oxygenated regions. The higher density of traces in the hypoxic region of the LSLE is mainly due to the activities of the surface deposit feeder Ophiura sp., which occurs in large numbers in this region. Possible explanations explored are stress behaviour of the organisms in response to hypoxia and different benthic macrofauna community structures between the hypoxic regions of the LSLE and the normoxic regions of the GSL. In the former, surface deposit feeders and low-oxygen tolerant species dominate over suspension feeders and low-oxygen intolerant species.     

State of the hydrothermal activity of Soufrière of Guadeloupe volcano inferred by VLF surveys

La Soufrière (1467 m) is the active island arc volcano of Guadeloupe Island in the Lesser Antilles arc. Its historical eruptions are more or less violent phreatic outbursts the last of which, in 1976–1977, led to the evacuation of nearly 70 000 persons. The subsurface structure of the volcano consists of calderas, craters, and avalanche amphitheatres nested within the composite pile of eruptive products. Since the last magmatic eruption, dated ca. 1440 AD, the four phreatic eruptions have developed radial fractures on Soufrière dome favouring the development of a huge active hydrothermal system emphasized by a tropical environment. After the eruptions, the thermal state and the stable ground water flow are completely disorganised during several years during which the slow mineralization of rocks is becoming again preponderant. Sealing of fractures and decay of rocks permeability act as a cap for upward thermal transfers. Therefore Soufrière dome operates as a valve, resealing the hydrothermal system underlying the volcano thus providing over pressurization that could lead to the next phreatic eruption. In 1992 new small seismic swarms have appeared. Several of them are recorded every year while the emission of acid gas slowly increases.In order to recognise the superficial electrical resistive and conductive zones (less than 100 m depth) as well as the cavities on Soufrière volcano, we have made Very Low Frequency (VLF) surveys in 2000. Electrical conductive zones are clearly associated with major radial faults starting from the summit in which the hydrothermal activity takes place. In the continuation of these active hydrothermal fractures hot springs are located down slope. Conversely some of the resistive zones are associated with inactive clayed and sealed or opened faults. The distribution of the conductive zones allows detailing the state of the superficial part of the hydrothermal system of La Soufrière. The distribution of vertical clayed zones associated with major faults supposes Soufrière dome constituted of more or less consolidated blocks joined side by side and lying on the hydrothermally floor of crater Amic.