Synergistic toxic effects of zinc pyrithione and copper to three marine species: Implications on setting appropriate water quality criteria

Zinc pyrithione (ZnPT) is widely applied in conjunction with copper (Cu) in antifouling paints as a substitute for tributyltin. The combined effects of ZnPT and Cu on marine organisms, however, have not been fully investigated. This study examined the toxicities of ZnPT alone and in combination with Cu to the diatom Thalassiosira pseudonana, polychaete larvae Hydroides elegans and amphipod Elasmopus rapax. Importantly, ZnPT and Cu resulted in a strong synergistic effect with isobologram interaction parameter lambda>1 for all test species. The combined toxicity of ZnPT and Cu was successfully modelled using the non-parametric response surface and its contour. Such synergistic effects may be partly due to the formation of copper pyrithione. It is, therefore, inadequate to assess the ecological risk of ZnPT to marine organisms solely based on the toxicity data generated from the biocide alone. To better protect precious marine resources, it is advocated to develop appropriate water quality criteria for ZnPT with the consideration of its compelling synergistic effects with Cu at environmentally realistic concentrations.     

Nutrient budgets for European seas: a measure of the effectiveness of nutrient reduction policies

Socio-economic development in Europe has exerted increasing pressure on the marine environment. Eutrophication, caused by nutrient enrichment, is evident in regions of all European seas. Its severity varies but has, in places, adversely impacted socio-economic activities. This paper aims to evaluate the effectiveness of recently adopted policies to reduce anthropogenic nutrient inputs to European seas. Nitrogen and phosphorus budgets were constructed for three different periods (prior to severe eutrophication, during severe eutrophication and contemporary) to capture changes in the relative importance of different nutrient sources in four European seas suffering from eutrophication (Baltic Proper, coastal North Sea, Northern Adriatic and North-Western Black Sea Shelf). Policy success is evident for point sources, notably for P in the Baltic and North Seas, but reduction of diffuse sources has been more problematic.     

SEDIMENTATION AND CONSOLIDATION OF A HIGH WATER CONTENT SOIL

I INTRODUCTIONHigh water coment soils are often at the centre of delicate industrial and environmental problems,particularly concerning the behaviour of port or estuary mud, and deposits at sea.In soil mechanics, an understanding of the behaviour of soils is based upon the concept of effectivestress proposed by Terzaghi (1936) and defined by the difference betWeen the total stress and the porepressure. Theoretical studies (Aleds et al., 1992) highlight the effective stress as the main co…     

Observation of Coriolis coupled modes below 1 mHz

We present observations of spectral energy at toroidal mode frequencies in vertical seismic recordings of the 1998 Balleny Islands earthquake. Since toroidal modes on a spherically symmetric, nonrotating Earth have horizontally polarized particle motion these observations call for an explanation. We first rule out local and instrumental effects as being responsible for the verticalcomponent signal of the toroidal modes ₀ T ₃ (0.59 mHz) and ₀ T ₄ (0.77 mHz). The global effects that we consider are general heterogeneous mantle structure, ellipticity of figure and rotation. We find that rotation through Coriolis coupling of loworder spheroidal and toroidal oscillations is the dominant mechanism.     

Modelling of shallow landslides with machine learning algorithms

This paper introduces three machine learning(ML)algorithms,the‘ensemble'Random Forest(RF),the‘ensemble'Gradient Boosted Regression Tree(GBRT)and the Multi Layer Perceptron neural network(MLP)and applies them to the spatial modelling of shallow landslides near Kvam in Norway.In the development of the ML models,a total of 11 significant landslide controlling factors were selected.The controlling factors relate to the geomorphology,geology,geo-environment and anthropogenic effects:slope angle,aspect,plan curvature,profile curvature,flow accumulation,flow direction,distance to rivers,water content,saturation,rainfall and distance to roads.It is observed that slope angle was the most significant controlling factor in the ML analyses.The performance of the three ML models was evaluated quantitatively based on the Receiver Operating Characteristic(ROC)analysis.The results show that the‘ensemble'GBRT machine learning model yielded the most promising results for the spatial prediction of shallow landslides,with a 95%probability of landslide detection and 87%prediction efficiency.     

Comparative biomass structure and estimated carbon flow in food webs in the deep Gulf of Mexico

A budget of the standing stocks and cycling of organic carbon associated with the sea floor has been generated for seven sites across a 3-km depth gradient in the NE Gulf of Mexico, based on a series of reports by co-authors on specific biotic groups or processes. The standing stocks measured at each site were bacteria, Foraminifera, metazoan meiofauna, macrofauna, invertebrate megafauna, and demersal fishes. Sediment community oxygen consumption (SCOC) by the sediment-dwelling organisms was measured at each site using a remotely deployed benthic lander, profiles of oxygen concentration in the sediment pore water of recovered cores and ship-board core incubations. The long-term incorporation and burial of organic carbon into the sediments has been estimated using profiles of a combination of stable and radiocarbon isotopes. The total stock estimates, carbon burial, and the SCOC allowed estimates of living and detrital carbon residence time within the sediments, illustrating that the total biota turns over on time scales of months on the upper continental slope but this is extended to years on the abyssal plain at 3.6 km depth. The detrital carbon turnover is many times longer, however, over the same depths. A composite carbon budget illustrates that total carbon biomass and associated fluxes declined precipitously with increasing depth. Imbalances in the carbon budgets suggest that organic detritus is exported from the upper continental slope to greater depths offshore.The respiration of each individual “size” or functional group within the community has been estimated from allometric models, supplemented by direct measurements in the laboratory. The respiration and standing stocks were incorporated into budgets of carbon flow through and between the different size groups in hypothetical food webs. The decline in stocks and respiration with depth were more abrupt in the larger forms (fishes and megafauna), resulting in an increase in the relative predominance of smaller sizes (bacteria and meiofauna) at depth. Rates and stocks in the deep northern GoM appeared to be comparable to other continental margins where similar comparisons have been made.     

Radiocarbon-derived sedimentation rates in the Gulf of Mexico

Sedimentation rates were determined for the northern Gulf of Mexico margin sediments at water depths ranging from 770 to 3560 m, using radiocarbon determinations of organic matter. Resulting sedimentation rates ranged from 3 to 15 cm/kyr, decreasing with increasing water depth. These rates agree with long-term sedimentation rates estimated previously using stratigraphic methods, and with estimates of sediment delivery rates by the Mississippi River to the northern Gulf of Mexico, but are generally higher by 1–2 orders of magnitude than those estimated by ²¹⁰Pb_xs methods. Near-surface slope sediments from 2737 m water depth in the Mississippi River fan were much older than the rest. They had minimum ¹⁴C ages of 16–27 kyr and δ¹³C values ranging from −24‰ to −26.5‰, indicating a terrestrial origin of organic matter. The sediments from this site were thus likely deposited by episodic mass wasting of slope sediment through the canyon, delineating the previously suggested main pathway of sediment and clay movement to abyssal Gulf sediments.     

The Origin of Sequential Chromospheric Brightenings

Sequential chromospheric brightenings (SCBs) are often observed in the immediate vicinity of erupting flares and are associated with coronal mass ejections. Since their initial discovery in 2005, there have been several subsequent investigations of SCBs. These studies have used differing detection and analysis techniques, making it difficult to compare results between studies. This work employs the automated detection algorithm of Kirk et al. (Solar Phys. 283, 97, 2013) to extract the physical characteristics of SCBs in 11 flares of varying size and intensity. We demonstrate that the magnetic substructure within the SCB appears to have a significantly smaller area than the corresponding \(\mbox{H}\upalpha\) emission. We conclude that SCBs originate in the lower corona around \(0.1~R_{\odot}\) above the photosphere, propagate away from the flare center at speeds of \(35\,\mbox{--}\,85~\mbox{km}\,\mbox{s}^{-1}\), and have peak photosphere magnetic intensities of \(148\pm2.9~\mbox{G}\). In light of these measurements, we infer SCBs to be distinctive chromospheric signatures of erupting coronal mass ejections.     

Formation and Characteristics of Coastal Internal Boundary Layers During Onshore Flows

The development and characteristics of coastal internal boundary layers were investigated in 28 tests. These were made at all seasons and in both gradient and sea-breeze flows but only during mid-day periods. Measurements of turbulence and temperature were taken from a light aircraft which flew traverses across Long Island at successive altitudes parallel to the wind direction. These were used to locate the boundary between modified and unmodified air as a function of height and distance from the coast. The same measurements plus tower measurements of wind, turbulence and temperature, pilot balloon soundings and measurements of land and water surface temperatures by a remote sensing IR thermometer were used to quantify the characteristics of the modified and unmodified air. The boundary layer slope was steep close to the land-water interface and became shallower with downwind distance. Growth of the boundary layer was initially slower with stable lapse rates upwind than with neutral or unstable conditions over the water. An equilibrium height was found in many tests except under conditions of free convection when the internal boundary layer merged into the mixed layer inland and with sea-breeze conditions. The equilibrium height depended on downwind conditions and was greater with low wind speeds and strong land surface heating than with stronger winds and small land-water temperature differences. Current theoretical models are not adequate to predict the height of the boundary layer at the altitudes and distances studied but reasonably good predictions were given by an empirical model developed earlier. Wind speed in the modified air averaged about 70% of that at the coast but turbulence levels were several times higher both near the surface and aloft. These findings have important implications for diffusion from coastal sites.