Special phase transformation and crystal growth pathways observed in nanoparticles†

Phase transformation and crystal growth in nanoparticles may happen via mechanisms distinct from those in bulk materials. We combine experimental studies of as-synthesized and hydrothermally coarsened titania (TiO₂) and zinc sulfide (ZnS) with thermodynamic analysis, kinetic modeling and molecular dynamics (MD) simulations. The samples were characterized by transmission electron microscopy, X-ray diffraction, synchrotron X-ray absorption and scattering, and UV-vis spectroscopy. At low temperatures, phase transformation in titania nanoparticles occurs predominantly via interface nucleation at particle–particle contacts. Coarsening and crystal growth of titania nanoparticles can be described using the Smoluchowski equation. Oriented attachment-based crystal growth was common in both hydrothermal solutions and under dry conditions. MD simulations predict large structural perturbations within very fine particles, and are consistent with experimental results showing that ligand binding and change in aggregation state can cause phase transformation without particle coarsening. Such phenomena affect surface reactivity, thus may have important roles in geochemical cycling.     

Seismic image of undercrusted serpentinite beneath a rifted margin

During the continental rifting the upper mantle was unroofed, and the mantle rocks were transformed into serpentinite at the ocean-continent transition of the west Galicia margin (Spain). The serpentinite layer, several km thick, extends probably eastwards, beneath the highly thinned continental crust of the margin.
The serpentinite layer was recently imaged by seismic reflection. It is discontinuously and deeply layered. As serpentinized peridotite can have densities and seismic velocities comparable to those of the lower continental crust, we suggest that undercrusting by serpentinite can play a part in building the lower seismic crust in highly stretched continental rifted areas.     

Snow-contact volcanic facies and their use in determining past eruptive environments at Nevados de Chillán volcano, Chile

Studies of the eruptive products from volcanoes with variable ice and snow cover and a long history of activity enable reconstruction of erupted palaeoenvironments, as well as highlighting the hazards associated with meltwater production, such as jökulhlaups and magma-water interaction. Existing difficulties include estimation of ice/snow thicknesses and discrimination between ice- and snow-contact lithofacies. We present field evidence from the Cerro Blanco subcomplex of Nevados de Chillán stratovolcano, central Chile, which has erupted numerous times in glacial and non-glacial periods and most recently produced andesitic lava flows in the 1861–1865 eruption from the Santa Gertrudis cone on the northwest flank of the volcano. The main period of lava effusion occurred during the winter of 1861 when the upper flanks of the volcano were reportedly covered in snow and ice. The bases and margins of the first lava flows produced are cut by arcuate fractures, which are interpreted as snow-contact features formed when steam generated from the melting of snow entered tensional fractures at the flow base. In contrast, the interiors and upper parts of these flows, as well as the overlying flow units, have autobrecciated and blocky textures typical of subaerial conditions, due to insulation by the underlying lava. Similar textures found in a lava flow dated at 90.0±0.6 ka that was emplaced on the northwest flank of Cerro Blanco, are also inferred to be ice and snow-contact features. These textures have been used to infer that a small valley glacier, overlain by snow, existed in the Santa Gertrudis Valley at the time of the eruption. Such reconstructions are important for determining the long-term evolution of the volcano as well as assessing future hazards at seasonally snow-covered volcanoes.     

Rapid changes in the level of Kluane Lake in Yukon Territory over the last millennium

The level of Kluane Lake, the largest lake in Yukon Territory, was lower than at present during most of the Holocene. The lake rose rapidly in the late seventeenth century to a level 12 m above present, drowning forest and stranding driftwood on a conspicuous high-stand beach, remnants of which are preserved at the south end of the lake. Kluane Lake fell back to near its present level by the end of the eighteenth century and has fluctuated within a range of about 3 m over the last 50 yr. The primary control on historic fluctuations in lake level is the discharge of Slims River, the largest source of water to the lake. We use tree ring and radiocarbon ages, stratigraphy and sub-bottom acoustic data to evaluate two explanations for the dramatic changes in the level of Kluane Lake. Our data support the hypothesis of Hugh Bostock, who suggested in 1969 that the maximum Little Ice Age advance of Kaskawulsh Glacier deposited large amounts of sediment in the Slims River valley and established the present course of Slims River into Kluane Lake. Bostock argued that these events caused the lake to rise and eventually overflow to the north. The overflowing waters incised the Duke River fan at the north end of Kluane Lake and lowered the lake to its present level. This study highlights the potentially dramatic impacts of climate change on regional hydrology during the Little Ice Age in glacierised mountains.     

Manifestations précoces du rift de Biscaye au Lias inférieur sur la marge Sud-Armoricaine (Talmont-Saint-Hilaire,Vendée,Ouest France)

To the south of Les Sables-d'Olonne (Vendée, France), the Early Liassic (Hettangian) sedimentation locally begins with continental clastics (including the dinosaur footprint-bearing beds of Le Veillon) prior to the deposition of shallow marine carbonates. Subsurface data (water borehole and geophysical line) indicate frequent variations in thickness of the clastics, related to fault block pattern. Simultaneously, numerous sedimentary dyke swarms developed within the metamorphic basement. These tectonic features resulted from an Early Liassic NNE–SSW-trending extension of the basement. Mineralized zones (silicification and metal-bearing mineralization) are related to hydrothermal circulations, contemporaneous (at least in part) with the Early Liassic extension. These different events may be related to the early stage of evolution (Triassic–Liassic) of the Biscay rift. To cite this article: C. Montenat et al., C. R. Geoscience 338 (2006).     

Products of an effusive subglacial rhyolite eruption: Bláhnúkur, Torfajökull, Iceland

We present field observations from Bláhnúkur, a small volume (<0.1 km³) subglacial rhyolite edifice at the Torfajökull central volcano, south-central Iceland. Bláhnúkur was probably emplaced during the last glacial period (ca. 115–11 ka). The characteristics of the deposits suggest that they were formed by an effusive eruption in an exclusively subglacial environment, beneath a glacier >400 m thick. Lithofacies associations attest to complex patterns of volcano-ice interaction. Erosive channels at the base of the subglacial sequence are filled by both eruption-derived material and subglacial till, which show evidence for deposition by flowing meltwater. This suggests that meltwater was able to drain away from the vent area during the eruption. Much of the subglacial volcanic deposits consist of conical-to-irregularly shaped lava lobes typically 5–10 m long, set in poorly sorted breccias with an ash-grade matrix. A gradational lavabreccia contact at the base of lava lobes represents a fossilised fragmentation interface, driven by magma-water interaction as the lava flowed over poorly consolidated, waterlogged debris. Sets of columnar joints on the upper surfaces of lobes are interpreted as ice-contact features. The morphology of the lobes suggests that they chilled within conically shaped subglacial cavities 2–5 m high. Avalanche deposits mantling the flanks of Bláhnúkur appear to have been generated by the collapse of lava lobes and surrounding breccia. A variety of deposit characteristics suggests that this occurred both prior to and after quenching of the lava lobes. Collapse events may have occurred when the supporting ice walls were melted back from around the cooling lava lobes and breccias. Much larger lava flows were emplaced in the latter stages of the eruption. Columnar joint patterns suggest that these flowed and chilled within subglacial cavities 20 m high and 100–200 m in length. There is little evidence for magma-water interaction at lava flow margins which suggests that these larger cavities were drained of meltwater. As rhyolite magma rose to the base of the glacier, the nature of the subglacial cavity system played an important role in governing the style of eruption and the volcanic facies generated. We present evidence that the cavity system evolved during the eruption, reflecting variations in both melting rate and edifice growth that are best explained by a fluctuating eruption rate.