Perfluorinated compounds in blood of Caretta caretta from the Mediterranean Sea

Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.     

Fast switch from extensional exhumation to thrusting of the Ronda Peridotites (South Spain)

The Alboran Domain, situated at the western end of the Mediterranean subduction system, is characterized by the Ronda Peridotites, one of the world's largest exposures of sub‐continental mantle. Using U–Pb (LA‐ICP‐MS) and Ar–Ar dating, we precisely dated two tectonic events associated with the Tertiary exhumation of the Ronda Peridotites. First, shearing along the Crust–Mantle Extensional Shear Zone caused, at ca. 22.5 Ma, mantle exhumation, local partial melting in the deep crust and coeval cooling in the upper crust. Second, the Ronda Peridotites Thrust triggered the final emplacement of the peridotites onto the continental crust at c. 21 Ma, as testified by granitic intrusions in the thrust hangingwall. The tectonic evolution of the western Alboran Domain is therefore characterized by a fast switch from continental lithospheric extension in a backarc setting, with sub‐continental mantle exhumation, to a rift inversion by thrusting driven by shortening of the upper plate.     

Origins and energetics of maar volcanoes: examples from the ultrapotassic Sabatini Volcanic District (Roman Province,Central Italy)

Maar volcanoes represent a common volcano type which is produced by the explosive interaction of magma with external water. Here, we provide information on a number of maars in the ultrapotassic Sabatini Volcanic District (SVD, Roman Province) as young as ∼90 ka. The SVD maars are characterised in terms of crater and ejecta ring morphologies, eruptive successions and magma compositions, in light of the local substrate settings, with the aim of assessing magma–water interaction conditions, eruption energetics and genetic mechanisms. Feeder magmas spanned the whole SVD differentiation trend from trachybasalts–shoshonites to phonolites. From the ejected lithic fragments from aquifer rocks, the range of depth of magma–water explosive interaction is estimated to have been mostly at ∼400–600 m below ground level, with a single occurrence of surficial interaction in palustrine–lacustrine environment. In particular, the interaction with external water may have triggered the explosive behaviour of poorly differentiated magmas, whereas it may have acted only as a late controlling factor of the degree of fragmentation and eruption style for the most differentiated magma batches during low-flux ascent in an incipiently fragmented state. Crater sizes, ejecta volumes and ballistic data allow a reconstruction of the energy budget of SVD maar-forming eruptions. Erupted tephra volumes from either monogenetic or polygenetic maars ranged 0.004–0.07 km³ during individual maar-forming eruptions, with corresponding total magma thermal energies of 8 × 10¹⁵–4 × 10¹⁷ J. Based on energy partitioning and volume balance of erupted magmas and lithic fractions vs. crater holes, we consider the different contributions of explosive excavation of the substrate vs. subsidence in forming the SVD maar craters. Following available models based on crater sizes, highly variable fractions (5–50%) of the magma thermal energies would have been required for crater excavation. It appears that subsidence may have played a major role in some SVD maars characterised by low lithic contents, whilst substrate excavation became increasingly significant with increasing degrees of aquifer fragmentation.     

Monitoring Etna volcanic plumes using a scanning LiDAR

In this paper, we use data obtained from LiDAR measurements during an ash emission event on 15 November 2010 at Mt. Etna, in Italy, in order to evaluate the spatial distribution of volcanic ash in the atmosphere. A scanning LiDAR system, located at 7?km distance from the summit craters, was directed toward the volcanic vents and moved in azimuth and elevation to analyse different volcanic plume sections. During the measurements, ash emission from the North East Crater and high degassing from the Bocca Nuova Crater were clearly visible. From our analysis we were able to: (1) evaluate the region affected by the volcanic plume presence; (2) distinguish volcanic plumes containing spherical aerosols from those having non-spherical ones; and (3) estimate the frequency of volcanic ash emissions. Moreover, the spatial distribution of ash mass concentration was evaluated with an uncertainty of about 50?%. We found that, even during ash emission episodes characterised by low intensity like the 15 November 2010 event, the region in proximity of the summit craters should be avoided by air traffic operations, the ash concentration being greater than 4?×?10^?3?g/m³. The use of a scanning permanent LiDAR station may usefully monitor the volcanic activity and help to drastically reduce the risks to aviation operations during the frequent Etna eruptions.     

High-frequency maximum observable shaking map of Italy from fault sources

We present a strategy for obtaining fault-based maximum observable shaking (MOS) maps, which represent an innovative concept for assessing deterministic seismic ground motion at a regional scale. Our approach uses the fault sources supplied for Italy by the Database of Individual Seismogenic Sources, and particularly by its composite seismogenic sources (CSS), a spatially continuous simplified 3-D representation of a fault system. For each CSS, we consider the associated Typical Fault, i.e., the portion of the corresponding CSS that can generate the maximum credible earthquake. We then compute the high-frequency (1–50?Hz) ground shaking for a rupture model derived from its associated maximum credible earthquake. As the Typical Fault floats within its CSS to occupy all possible positions of the rupture, the high-frequency shaking is updated in the area surrounding the fault, and the maximum from that scenario is extracted and displayed on a map. The final high-frequency MOS map of Italy is then obtained by merging 8,859 individual scenario-simulations, from which the ground shaking parameters have been extracted. To explore the internal consistency of our calculations and validate the results of the procedure we compare our results (1) with predictions based on the Next Generation Attenuation ground-motion equations for an earthquake of M_w 7.1, (2) with the predictions of the official Italian seismic hazard map, and (3) with macroseismic intensities included in the DBMI04 Italian database. We then examine the uncertainties and analyse the variability of ground motion for different fault geometries and slip distributions.     

NGC 3147: a 'true' type 2 Seyfert galaxy without the broad-line region

We report on simultaneous optical and X-ray observations of the Seyfert galaxy, NGC 3147. The XMM–Newton spectrum shows that the source is unabsorbed in the X-rays  ( N _H < 5 × 10²⁰ cm⁻²)  . On the other hand, no broad lines are present in the optical spectrum. The origin of this optical/X-rays misclassification (with respect to the Unification Model) cannot be attributed to variability, since the observations in the two bands are simultaneous. Moreover, a Compton-thick nature of the object can be rejected on the basis of the low-equivalent width of the iron Kα line (≃130 eV) and the large ratio between the 2–10 keV and the [O  iii ] fluxes. It seems therefore inescapable to conclude that NGC 3147 intrinsically lacks the Broad-Line Region, making it the first 'true' type 2 Seyfert galaxy.     

Web Geoservices and Ancient Cadastral Maps: The Web C.A.R.T.E. Project

In the State Archive of Como, Northern Italy, about 15,000 historical maps belonging to different national cadastral productions are preserved. The Web C.A.R.T.E. project was started to enhance the accessibility of this valuable cartographic heritage using FOSS (Free and Open Source Software) technologies. The system, which implements specific web geoservices for cataloguing and visualization, should assist the State Archive of Como in the digital management of its cartographic resources and related information. After the high‐resolution digitization step, maps undergo a georeferencing operation. A special statistical procedure for choosing the best mathematical model was developed, verifying also strengths and weaknesses of georeferencing with a common free and Open Source GIS. Next, metadata consistent with current Italian standards were added to the georeferenced maps using an ad hoc localized version of GeoNetwork Opensource (recently provided as the official Italian version of the software). A dedicated WebGIS system was built for publishing the georeferenced cadastral maps. This system is capable of navigating large raster data in a georeferenced framework and easily retrieving their metadata. The WebGIS system for the State Archive of Como is an important contribution for the preservation of the original historical paper maps and also a great modernization and simplification of the end user's access to this archive.     

Hydrogeochemical study in the Main Ethiopian Rift: new insights to the source and enrichment mechanism of fluoride

The central Main Ethiopian Rift suffers a severe water quality problem, characterized by an anomalously high fluoride (F) content that causes an endemic fluorosis disease. The current study, conducted in the Ziway–Shala lakes basin, indicates that the F content exceeds the permissible limit for drinking prescribed by the World Health Organization (WHO; 1.5 mg/l) in many important wells (up to 20 mg/l), with even more extreme F concentration in hot springs and alkaline lakes (up to 97 and 384 mg/l respectively). The groundwater and surface water from the highlands, typically characterized by low total dissolved solids (TDS) and Ca (Mg)–HCO₃ hydrochemical facies, do not show high F content. The subsequent interaction of these waters with the various rocks of the rift valley induces a general increase of the TDS, and a variation of the chemical signature towards Na–HCO₃ compositions, with a parallel enrichment of F. The interacting matrixes are mainly rhyolites consisting of volcanic glass and only rare F-bearing accessory minerals (such as alkali amphibole). Comparing the abundance and the composition of the glassy groundmass with other mineral phases, it appears that the former stores most of the total F budget. This glassy material is extremely reactive, and its weathering products (i.e. fluvio/volcano-lacustrine sediments) further concentrate the fluoride. The interaction of these “weathered/reworked” volcanic products with water and carbon dioxide at high pH causes the release of fluoride into the interacting water. This mainly occurs by a process of base-exchange softening with the neo-formed clay minerals (i.e. Ca–Mg uptake by the aquifer matrix, with release of Na into the groundwater). This is plausibly the main enrichment mechanism that explains the high F content of the local groundwater, as evidenced by positive correlation between F, pH, and Na, and inverse correlation between F and Ca (Mg). Saturation indices (SI) have been calculated (using PHREEQC-2) for the different water groups, highlighting that the studied waters are undersaturated in fluorite. In these conditions, fluoride cannot precipitate as CaF₂, and so mobilizes freely without forming other complexes. These results have important implications for the development of new exploitation strategies and accurate planning of new drilling sites. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Abiotic and Biotic Links Work Two Ways: Effects on the Deposit at the Cliff Foot Induced by Mechanical Action of Date Mussel Harvesting (<Emphasis Type="Italic">Lithophaga lithophaga</Emphasis>)

The existence of linkages between ecological and geomorphological processes and the influence of human activities both on the biota and on geomorphology is well known for terrestrial environments, while it has been seldom reported for submerged ones. A survey in the Noli-Bergeggi area (NW Mediterranean Sea) has been carried out to test the hypothesis that the harvesting of Lithophaga lithophaga has an impact not only on the hammered rock, but also on the sediments at the cliff foot. Size and roundness of pebbles have been measured at different stations and statistical analyses have been used to test the differences between impact and control situations. Results show a dependence of the roundness of pebbles on the date mussel harvesting, indicating a decrease both of the roundness index and of its variability at the cliff foot in impacted sites. Conclusions stress the biogeomorphological nature of this activity, not limited to the present location.