Determination of inorganic sulphur speciation with polarographic techniques: Some preliminary results for recent hypersaline anoxic sediments

Polarographic techniques have been used to determine reduced inorganic sulphur speciation in recent anoxic marine sediments from two hypersaline basins, the Tyro and the Bannock Basins, in the Eastern Mediterranean. The following phases were determined: acid volatile sulphur (AVS), pyritic sulphur and zerovalent sulphur. The determination of AVS and pyrite was based respectively on the acidification and Cr(II) reduction of these sulphur components to H₂S. H₂S was collected in base and the sulphide concentration was measured by polarography. Standard Na₂S and pyrite gave recoveries of 99.6% ± 3.9% and 97% ± 12% respectively. Total zerovalent sulphur in a sediment sample was measured by the reaction of sulphite with thiosulphate. Thiosulphate was measured directly by polarography.

Pyrite is the main phase of inorganic reduced sulphur in the sediments from the Tyro and the Bannock Basins, and it has about the same average level (125 υmoles per gramme dry weight) in the cores recovered from the two areas. However, the distribution of pyrite in the top 100 cm of the two cores differs significantly. In the Bannock Basin a sharp increase is observed with depth, whereas in the Tyro Basin there is a small decrease with depth.

The total amount of reduced inorganic sulphur is less than the total amount of sulphur in the sediments. This indicates that there must be additional sulphur-bearing phases. One of these phases may be gypsum, and indeed, gypsum crystals have been observed in the Bannock Basin.

In neither basin is there a significant correlation between reduced sulphur and organic carbon. The pyrite that occurs in these basins may have been formed syngenetically at the interface of the anoxic brine and oxic seawater. Diagenetic pyrite may have been formed within the sediments of the basins. AVS and total zerovalent sulphur are still observed at depth. We therefore suggest that this may be due to the incomplete transformation of AVS and zerovalent sulphur into pyrite.     

Sensitivity of the Eastern Mediterranean geomorphic system towards environmental change during the Late Holocene: a chronological perspective

Alluvial and colluvial sediment deposition provide a vital record of environmental change during the Holocene. Firm chronological control on these archives is necessary to enable us to relate sediment dynamics to human activity and climate variability. In the Eastern Mediterranean, such relationships are hard to establish due to the lack of spatially well‐distributed sediment archives with good chronological control. This scarcity is problematic with respect to regional‐scale reconstructions of the temporal variation of sediment dynamics. Here, we present a radiocarbon database (n = 178) of geomorphological activity collected from multiple distinct sediment archives within the territory of Sagalassos in south‐western Turkey. The data were grouped according to their sedimentary facies for analysis using cumulative probability distributions (CPDs) and sedimentation rate (SR) modelling. Two small‐scale colluvial valleys, where chronological information was abundant, were investigated in more detail. Results show that sedimentation chronology differs between individual, nearby cores, as it depends strongly on the local geomorphic situation. A generalizing approach combining multiple core results yields more widely valid conclusions. High sedimentation rates coincided with the initial major anthropogenic disturbance of the landscape and decreased afterwards, probably due to hillslope soil depletion. CPD and SR analysis indicates that in general colluvial sedimentation rates did not change much from 2000 BC onwards. River floodplain sedimentation, in contrast, increased markedly during the first millennium BC and during recent times, and a significant time lag in enhanced sediment deposition between the upper and lower reaches of the river valleys was observed. Copyright © 2012 John Wiley & Sons, Ltd.     

Inter‐instrument comparison of particle‐size analysers

This paper presents a methodological framework for inter‐instrument comparison of different particle‐size analysers. The framework consists of: (i) quantifying the difference between complete particle‐size distributions; (ii) identifying the best regression model for homogenizing data sets of particle‐size distributions measured by different instruments; (iii) quantifying the precision of a range of particle‐size analysers; and (iv) identifying the most appropriate instrument for analysing a given set of samples. The log‐ratio transform is applied to particle‐size distributions throughout this study to avoid the pitfalls of analysing percentage‐frequency data in ‘closed‐space’. A Normalized Distance statistic is used to quantify the difference between particle‐size distributions and assess the performance of log‐ratio regression models. Forty‐six different regression models are applied to sediment samples measured by both sieve‐pipette and laser analysis. Interactive quadratic regression models offer the best means of homogenizing data sets of particle‐size distributions measured by different instruments into a comparable format. However, quadratic interactive log‐ratio regression models require a large number of training samples (n > 80) to achieve optimal performance compared to linear regression models (n = 50). The precision of ten particle‐size analysis instruments was assessed using a data set of ten replicate measurements made of four previously published silty sediment samples. Instrument precision is quantified as the median Normalized Difference measured between the ten replicate measurements made for each sediment sample. The Differentiation Power statistic is introduced to assess the ability of each instrument to detect differences between the four sediment samples. Differentiation Power scores show that instruments based on laser diffraction principles are able to differentiate most effectively between the samples of silty sediment at a 95% confidence level. Instruments applying the principles of sedimentation offer the next most precise approach.     

Palaeoecological constraints on late Glacial and Holocene ice retreat in the Southern Andes (53°S)

Late Glacial to Holocene ice retreat was investigated along a 120 km long fjord system, reaching from Gran Campo Nevado (GCN) to Seno Skyring in the southernmost Andes (53°S). The aim was to improve the knowledge on regional and global control on glacier recession with special emphasis on latitudinal shifting of the westerlies. The timing of ice retreat was derived from peat and sediment cores, using mineralogical and chemical characteristics, and pollen as proxies. Stratigraphy was based on ¹⁴C-AMS ages and tephrochronology. The ice retreat of the Seno Skyring Glacier lobe is marked by an ice rafted debris layer which was formed around 18,300 to 17,500 cal. yr B.P. Subsequently, fast glacier retreat occurred until around 15,000 to 14,000 cal. yr B.P. during which around 84% of Skyring Glacier were lost. This fast recession was probably also triggered by an increase of the Equilibrium Line Altitude (ELA) from 200 to 300 m. Subsequently, the ice surface was lowered below the ELA in an area that previously made up more than 50% of the accumulation area. Much slower retreat and glacier fluctuations of limited extent in the fjord channel system northeast of GCN occurred between around 14,000 to 11,000 cal. yr B.P. during both the Antarctic Cold Reversal and the Younger Dryas. This slow down of retreat indicates a decline in the general warming trend and/or increased precipitation, due to a southward migration of the westerlies. After around 11,000 cal. yr B.P. pollen distribution shows evolved Magellanic Rainforest and similar climate as at present, which lasted throughout most of the Holocene. Only Late Neoglacial moraine systems were formed in the period 1220–1460 AD, and subsequently in the 1620s AD, and between 1870 and 1910 AD. The results indicate that the Gran Campo Nevado ice cap has reacted more sensitive and partly distinct to climate change, compared to the Patagonian Ice Field.     

The global energy balance from a surface perspective

In the framework of the global energy balance, the radiative energy exchanges between Sun, Earth and space are now accurately quantified from new satellite missions. Much less is known about the magnitude of the energy flows within the climate system and at the Earth surface, which cannot be directly measured by satellites. In addition to satellite observations, here we make extensive use of the growing number of surface observations to constrain the global energy balance not only from space, but also from the surface. We combine these observations with the latest modeling efforts performed for the 5th IPCC assessment report to infer best estimates for the global mean surface radiative components. Our analyses favor global mean downward surface solar and thermal radiation values near 185 and 342 Wm^?2, respectively, which are most compatible with surface observations. Combined with an estimated surface absorbed solar radiation and thermal emission of 161 and 397 Wm^?2, respectively, this leaves 106 Wm^?2 of surface net radiation available globally for distribution amongst the non-radiative surface energy balance components. The climate models overestimate the downward solar and underestimate the downward thermal radiation, thereby simulating nevertheless an adequate global mean surface net radiation by error compensation. This also suggests that, globally, the simulated surface sensible and latent heat fluxes, around 20 and 85 Wm^?2 on average, state realistic values. The findings of this study are compiled into a new global energy balance diagram, which may be able to reconcile currently disputed inconsistencies between energy and water cycle estimates.     

Long-term response of an arctic fiord system to lead-zinc mining and submarine disposal of mine waste (Maarmorilik, West Greenland)

Contamination by lead (Pb) and zinc (Zn) was studied in seawater, sediments, seaweeds and blue mussels near the former Black Angel Pb-Zn Mine in Maarmorilik, West Greenland. The mine operated during the period 1973-90 when mine waste (tailings and later waste rock) was discharged directly into the sea. Metal concentrations peaked during the mining period and Pb and Zn in seawater within the discharge area were measured up to 440 and 790 μg L?1, respectively. Pb in fiord sediments, seaweeds and blue mussels just outside the discharge area were measured in concentrations up to 190, 84 and 2650 and Zn up to 300, 360 and 1190 μg g?1 dry wt., respectively. Within the discharge area, seawater metal concentrations (especially Pb) decreased abruptly after mine closure. Metals concentrations in sediments and biota, however, decreased more slowly and two decades after mine closure seaweeds and blue mussels were still contaminated 12 km from the mine.     

Conversion Gain and Interpixel Capacitance of Cmos Hybrid Focal Plane Arrays

The conversion gain of optical and infrared focal plane CMOS hybrid arrays is a fundamental parameter, whose value computes into the derivation of other parameters characterizing the performance of a detector. The widespread “noise squared versus signal” method used to obtain the conversion gain can overestimate the nodal capacitance of the detector pixel by more than 20% for infrared arrays and by more than 100% for Si-PIN diode arrays. This is because this method does not take account of the capacitive coupling between neighboring pixels. A simple technique has been developed to measure the nodal capacitance directly by comparing the voltage change of an external calibrated capacitor with the voltage change on the nodal capacitor of the detector pixel. The method is elaborated in detail and has been verified with a Si-PIN diode array hybridized to a Hawaii-2RG multiplexer using an Fe ⁵⁵ X-ray source. It is also in good agreement with a stochastic method based on 2D autocorrelation.     

Theories of practices: Agency, technology, and culture : Exploring the relevance of practice theories for the governance of sustainable consumption practices in the new world-order

Within the environmental social sciences, theories of practices are used by an increasing number of authors to analyze the greening of consumption in the new, global order of reflexive modernity. The use of practices as key methodological units for research and governance is suggested as a way to avoid the pitfalls of the individualist and systemic paradigms that dominated the field of sustainable consumption studies for some decades. With the help of practice theory, environmental governance can be renewed in three particular ways: First, the role and responsibilities (not) to be assigned to individual citizen-consumers in environmental change can be specified. Secondly, objects, technologies and infrastructures can be recognized for their crucial contribution to climate governance without lapsing into technological determinism. Third, the cultural framing of sustainability can be enriched by looking into the forms of excitement generated in shared practices of sustainable consumption. We conclude by discussing the need to investigate the globalization of practices from a post-national perspective in both science and policy.     

What governs macrophyte species richness in kettle hole types? A case study from Northeast Germany

Kettle holes are small, pond-like, depressional wetlands in young moraine landscapes. They mostly undergo a wet-dry cycle and have a high potential for biological species diversity. However, their biodiversity and habitat function is often greatly impacted by surrounding intensive agricultural land use practices.In this study, we used statistical analysis of a large data set from the federal state of Brandenburg (Northeast Germany) to characterise the macrophyte species richness of kettle holes in an interregional context and to determine the factors that influence macrophyte occurrence. We proposed that (1) specific environmental factors, (2) hydrogeomorphic kettle hole types and (3) the regional topography have a major impact on macrophyte species richness. The evaluation of the data was performed using the General Linear Model (GLM) and Canonical Correspondence Analysis (CCA). Each of the analysed factors addresses different parts of the macrophyte species richness, including the target variables overall species richness, plant life and growth forms as well as Red List species.None of the analysis showed effects of the tested environmental factors on overall macrophytes species richness, but on the richness of plant life and growth forms as well as on Red List species. We identified hydroperiod, depth, shore width, kettle hole area, pH, electric conductivity, carbonate hardness and oxygen as key factors for the prediction of species richness of plant life and growth forms. Furthermore, we demonstrate that hydrogeomorphic kettle hole types account for relevant parts of variation in species richness and are useful interregional and integrative indicators to identify kettle holes with protection priority for macrophytes.